• Journal of the Korean Crystal Growth and Crystal Technology
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• v.17 no.3
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• pp.133-137
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• 2007

Ecological lightweight aggregates were made in order to recycle the dredged soils from the seaside construction area and the bottom ashes from the power plant. Various physical and chemical analysis were performed on them to identify their possibility for applying lightweight concrete fields. Lightweight aggregates were made of bottom ashes and dredged soils from Yongheung Island which is located 20km west away from Seoul, and all the raw materials were milled before mixing. The physical and chemical properties such as density, absorption rate, stability, alkali latency reaction, heavy metal leaching of the lightweight aggregates were tested and analysed by following the KS standard procedures. From the size analysis, the coarse aggregates showed a suitable fit on standard particle ranges; however, the fine aggregates showed a large deviation from the standard. The absorption rates were increased with decreasing weight of the aggregates. All the aggregates were turned out to be safe by the stability and heavy metal leaching test; however, some of the aggregates were confirmed on the border of harmless and possibly harmful region through the alkali latency reactivity test.

• 한국신재생에너지학회:학술대회논문집
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• 2009.11a
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• pp.619-619
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• 2009

Recently, silica nanostructures are widely used in various applicationary areas such as chemical sensors, biosensors, nano-fillers, markers, catalysts, and as a substrate for quantum dots etc, because of their excellent physical, chemical and optical properties. Additionally, these days, semiconductor silica and silicon with high purity is a key challenge because of their metallurgical grade silicon (MG-Si) exhibit purity of about 99% produced by an arc discharge method with high cast. Tremendous efforts are being paid towards this direction to reduce the cast of high purity silicon for generation of photovoltaic power as a solar cell. In this direction, which contains a small amount of impurities, which can be further purified by acid leaching process. In this regard, initially the low cast rice-husk was cultivated from local rice field and washed well with high purity distilled water and were treated with acid leaching process (1:10 HCl and $H_2O$) to remove the atmospheric dirt and impurity. The acid treated rice-husk was again washed with distilled water and dried in an oven at $60^{\circ}C$. The dried rice-husk was further annealed at different temperatures (620 and $900^{\circ}C$) for the formation of silica nanospheres. The confirmation of silica was observed by the X-ray diffraction pattern and X-ray photoelectron spectroscopy. The morphology of obtained nanostructures were analyzed via Field-emission scanning electron microscope(FE-SEM) and Transmission electron microscopy(TEM) and it reveals that the size of each nanosphares is about 50-60nm. Using the Inductively coupled plasma mass spectrometry(ICP-MS), Silica was analyzed for the amount of impurities.

• Nuclear Engineering and Technology
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• v.20 no.2
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• pp.120-131
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• 1988

A souce term model describes mathematically the source of radionuclides as they begin slow migration and decay in deep groundwater. Various source term models based on mass-transfer analysis and measurement-based source term models are reviewed. Ganerally, two processes are involved in leaching or dissolution: (1) chemical reactions and (2) mass transfer by diffusion. The chemical reaction controls the dissolution rates only during the early stage of exposure to groundwater. The exterior-field mass transfer may control the long term dissolution rates from the waste solid in a geologic repository. Mass-transfer analyses re3y on detailed and careful application of the governing equations that describe the mechanistic processes of transport of material between and within phases. If used correctly, source term models based on mass-transfer theory are valuable and necessary tools for developing reliable predictions.

• Journal of The Korean Society of Agricultural Engineers
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• v.63 no.4
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• pp.13-21
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• 2021

The feasibility of HWS for agricultural use was analyzed through a crop cultivation test to utilize the hydroponic waste solution (HWS) generated from the nutriculture greenhouse. The fertilizing effect of HWS was assessed on the basis of the inorganic nitrogen (N) mostly existed in HWSs, and nitrogen (urea) fertilizer. Lettuce was selected as the target crop influenced by the soil treatment and also for the crop cultivation test. Thus, the change in growth characteristics of lettuce and that in chemical characteristics of the soil were investigated. In terms of the growth of lettuce, the C control group with 70% nitrogen (urea) fertilizer and 30% HWS and the D control group with 50% nitrogen (urea) fertilizer and 50% HWS were more effective than the practice control group (B) with 100% nitrogen (urea) fertilizer. The results of this study confirmed the combined applicability of the chemical fertilizer and HWS for crop cultivation. Because NO₃-N present in HWS has a high possibility of leaching into the soil, its applicability as a fertilizer has been considered to be relatively low in Korea. However, if an appropriate mixing ratio of urea fertilizer and HWS could be applied, the problems associated with leaching of nitrate nitrogen could be reduced with beneficial effects on crop cultivation. Thus, future studies are required on the treatment effect of HWS with repeated cultivation, impact assessment on the surrounding environment, and appropriate fertilization methods using nitrogen (urea) fertilizer and HWS. These studies would facilitate the sustainable recycling of HWS.

• Journal of Korean Society of Environmental Engineers
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• v.22 no.11
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• pp.2085-2095
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• 2000

Red mud is generated as a by-product during the production of aluminum hydroxide from bauxite ore. In this study inorganic coagulants were prepared by leaching aluminum and iron from red mud with acids under various operating conditions. The optimum leaching efficiency of Al and Fe was obtained by contacting red mud with acids of 5M $H_2SO_4$ and 9M HCI with the ratio of 1/10(g/mL) at $85^{\circ}C$ and $25^{\circ}C$, respectively. In addition. the removal experiments of heavy metal ions($Pb^{2+}$, $Cd^{2+}$, $Cu^{2+}$, $Zn^{2+}$, $Cr^{3+}$), turbidity and phosphate phosphorus($PO_4{^{3-}}-P$) in aqueous solutions were also studied in various experimental conditions. As a result, the developed coagulants are found to show a good removal performance of heavy metal ions. turbidity and phosphate phosphorus in aqueous solutions.

• Bulletin of the Korean Chemical Society
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• v.26 no.9
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• pp.1381-1384
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• 2005

Surface modification of tridimensional cubic mesoporous silica, SBA-16, was investigated with pendant arm functionalized cobalt diaminosarcophagine (diAMsar) cage complex which covalently grafted onto the silica surface through the silication with sylanol group. The spectroscopic results showed that the mesoporous structure was preserved under the $[Co(diAMsar)]^{3+}$ grafting reaction condition. Successful grafting prevented the cobalt diAMsar cage from leaching out from the SBA-16 support.

• Proceedings of the Korea Concrete Institute Conference
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• 2005.05b
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• pp.477-480
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• 2005

The discharge of sewage sludge is rapidly increasing in Korea. But the most common sewage sludge disposal alternative is to incinerate and to deposit it in controlled landfills. However, space limitations on existing landfill sites, and increasing environmental concerns have prompted the investigation of alternative ash disposal routes. The utilization of sewage sludge ash would contribute to the elimination of an environmental problem and to the development of new high-performance materials. The purpose of this study is to apply to Alkali Activation into solidification of sewage sludge ash. It achieves leaching test, chemical composition and compressive strength test. As a result of tests, the sewage sludge ash has sufficient potential for use of pozzolanic raw material. However, it is judge to be available to construction material if research is continuously gone.

• The Korean Journal of Ecology
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• v.21 no.1
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• pp.1-6
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• 1998

Effects of air pollutants on the chemical properties of soil in Yoch'on inductrial complex were investigated. Soil pH showed severe acidity with average value of 4.3$\pm$0.13. Soil pH decreaed along the increase in altitute of Mt. Jeseok. Soil organic matter and total N was 19.2$\pm$3.6% and 4.7$\pm$0.25mg/g, respectively, which were higher than those of unpolluted area, Kongju. Available P was 41.2$\pm$3.7 $\mu$g/g, which was 4 times greater than that of unpolluted area, Kongju. Average content of total-S was 283.5$\pm$14.1 $\mu$g/g, which was 10 times greater than that of unpolluted area. Content of available Al was o.43$\pm$0.03 mg/g, which was 2 times greater than that of unpolluted area. Available Al increased as the soil pH decrease. Contents of exchangeable K, Ca and Mg were significantly lower than those in unpolluted area, because of severe leaching in acid soil.

• Bulletin of the Korean Chemical Society
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• v.26 no.6
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• pp.887-891
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• 2005

Novel nickel catalyst deposited on nanoporous carbon was found to be an efficient catalyst for the epoxidation of simple alkenes with $O_2$ and isobutyraldehyde under mild conditions. Alkenes exhibited different reactivities towards Ni-catalyst and epoxidation with stilbene proceeds stereospecifically. This may be rationalized with the mechanism involving coordinated acylperoxy radical intermediate. Nickel contents depend on the preparative methods and the KNI-3 catalyst, which was synthesized by wet impregnation of $Ni(NO_3)_2$ into nanoporous carbon, shows the highest activity. The activity of the catalyst is well correlated with contents of nickel. Recycled catalysts suffer considerable loss of activity due to leaching of catalytic active species, nickel.

• Journal of the Korean earth science society
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• v.28 no.1
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• pp.112-122
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• 2007

It is known that coal-derived fly ashes have the unique chemical composition and mineralogical characteristics. Since iron oxides in coal fly ash are enriched with heavy metals, the subsurface media including soils, underground water, and sea water are highly likely contaminated with heavy metals when the heavy metals are leached from fly ashes by water-fly ash interactions. The purpose of this study was to investigate how indigenous bacteria affect heavy metal leaching and mineralogy in fly ash slurry during the fly ash-seawater interactions in the ash pond located in Dangjin seashore, Korea. The average pH of ash pond seawater was 8.97 in nature. Geochemical data showed that microbial activity sharply increased after the 7th day of the 60-day course batch experiments. Compared with other samples including autoclaved and natural samples, ${SO_4}^{2-}$ was likely to decrease considerably in the fly ash slurry samples when glucose was added to stimulate the microbial activity. Geochemical data including Eh/pH, alkalinity, and major and trace elements showed that the bacteria not only immobilize metals from the ash pond by facilitating the chemical reaction with Mn, Fe, and Zn but may also be able to play an important role in sequestration of carbon dioxide by carbonate mineral precipitation.