Browse > Article
http://dx.doi.org/10.5012/bkcs.2005.26.9.1381

Fuctionalization of SBA-16 Mesoporous Materials with Cobalt(III) Cage Amine Complex  

Han, Sang-Cheol (Nano Center Fine Chemicals Fusion Technology and Laboratory of Nano-Green Catalysis, Department of Chemistry, Inha University)
Sujandi, Sujandi (Nano Center Fine Chemicals Fusion Technology and Laboratory of Nano-Green Catalysis, Department of Chemistry, Inha University)
Park, Sang-Eon (Nano Center Fine Chemicals Fusion Technology and Laboratory of Nano-Green Catalysis, Department of Chemistry, Inha University)
Publication Information
Bulletin of the Korean Chemical Society / v.26, no.9, 2005 , pp. 1381-1384 More about this Journal
Abstract
Surface modification of tridimensional cubic mesoporous silica, SBA-16, was investigated with pendant arm functionalized cobalt diaminosarcophagine (diAMsar) cage complex which covalently grafted onto the silica surface through the silication with sylanol group. The spectroscopic results showed that the mesoporous structure was preserved under the $[Co(diAMsar)]^{3+}$ grafting reaction condition. Successful grafting prevented the cobalt diAMsar cage from leaching out from the SBA-16 support.
Keywords
SBA-16; Grafting; Cobalt; Diaminosarcophagine; Confinement effect;
Citations & Related Records

Times Cited By Web Of Science : 8  (Related Records In Web of Science)
Times Cited By SCOPUS : 8
연도 인용수 순위
1 Kresge, C. T.; Leonowiez, M. E.; Roth, W. J.; Vartuli, J. C.; Beck, J. S. Nature 1992, 359, 710   DOI
2 Zhao, D.; Huo, Q.; Feng, J.; Chemlka, B. F.; Stucky, G. D. J. Am. Chem. Soc. 1998, 120, 6024   DOI   ScienceOn
3 Sakamto, Y.; Kaneda, M.; Terasaki, O.; Zhao, D.; Kim, J. M.; Stucky, G. D.; Shin, H. Y.; Ryoo, R. Nature 2000, 408, 449   DOI   ScienceOn
4 Hwang, Y. K.; Chang, J.-S.; Kwon, Y.-U.; Park, S.-E. Micropor. Mesopor. Mater. 2004, 68, 21   DOI   ScienceOn
5 Konigstein, C.; Mau, A. W. H.; Osvath, P.; Sargeson, A. M. Chem. Commun. 1997, 423
6 Donnelly, P. S.; Harrowfield, J. M.; Skelton, B. W.; White, A. H. Inorg. Chem. 2000, 39, 5817   DOI   ScienceOn
7 Donnelly, P. S.; Harrowfield, J. M.; Skelton, B. W.; White, A. H. Inorg. Chem. 2001, 40, 5645   DOI   ScienceOn
8 Burnet, S.; Choi, M.-H.; Donnelly, P. S.; Harrowfield, J. M.; Ivanova, I.; Jeong, S.-H.; Kim, Y.; Mocerino, M.; Skelton, B. W.; White, A. H.; Williams, C. C.; Zeng, Z.-L. Eur. J. Inorg. Chem. 2001, 1869
9 Sargeson, A. M. Coordin. Chem. Rev. 1996, 151, 89   DOI   ScienceOn
10 Wainwright, K. P. Coordin. Chem. Rev. 1997, 166, 35   DOI   ScienceOn
11 Bernhardt, P. V.; Lawrance, G. A. Coordin. Chem. Rev. 1990, 104, 297   DOI   ScienceOn
12 Geue, R. J.; Hambley, T. W.; Harrowfield, J. M.; Sargeson, A. M.; Snow, M. R. J. Am. Chem. Soc. 1984, 106, 5478   DOI
13 Stein, A.; Melde, B. J.; Schroden, R. C. Adv. Mater. 2000, 12, 1403   DOI   ScienceOn