• Title/Summary/Keyword: Chemical flow control

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Effects of Flow on the Chemical Vapor Deposition of Si in System SiH$_4$-H$_2$ (SiH$_4$-H$_2$계에서 유체유동이 Si의 화학증착에 미치는 영향)

  • 조성욱;이경우;조영환;윤종규
    • Journal of Surface Science and Engineering
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    • v.23 no.3
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    • pp.160-166
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    • 1990
  • The effects of the variation of proedd varibles on the flow patterns and effects of the flow patterns on the deposition rate and uniformity in the Si-epitaxy CVD with SiH4 as the source of Si were studied through the calculation by use of control volume method. The reslts showed that the natural convection was undesirable to the uniformity of deposition rate, whose effects were decreased with the dercrese with the decrese of the pressure in the reactoor and with the increase of the flow rate. However. the excessive increase of flow rate caused the movement of the unreacted gas to the substrate. Therefore it resulted in the non-uniform depositions. The rotation of substrate was apperared to improve the uniformity. The resulte of this study could used in CVD process to design the reator and to find the optimum conditions of the process variables.

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Process Optimization for Life Extension of Electropolishing Solution using Half Round Bus Bar (반구형 부스바를 이용한 전해연마액 수명연장을 위한 공정 최적화)

  • Kim, Soo Han;Lee, Seung Heon;Cho, Jaehoon;Lim, Dong-Ha;Choi, Joongso;Park, Chulhwan
    • Journal of Surface Science and Engineering
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    • v.49 no.5
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    • pp.447-453
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    • 2016
  • In this study, we intended to extend the life of electropolishing solution through the reduction of electric resistance by improving the electrolysis efficiency. The optimum conditions were obtained by half round bus bar and Taguchi method. As the main control factors in the electropolishing process, current density, polishing time, electrolyte temperature and flow rate were selected. The electrolyte temperature was the most significant to the electrolysis efficiency. The optimum conditions for the life extension of electropolishing solution were as follows: current density, $45A/dm^2$; polishing time, 6 min; electrolyte temperature, $70^{\circ}C$; flow rate, 11 L/min. As a results of ANOVA of SN ratios, it was found that the electrolyte temperature was significant factor at the 90% confidence level.

DSMC Calculation of the Hypersonic Free Stream and the Side Jet Flow Using Unstructured Meshes (비정렬 격자 직접모사법을 이용한 희박 유동과 측면 제트의 상호 작용에 관한 연구)

  • Kim M. G.;Kwon O. J.;Ahn C. S.
    • 한국전산유체공학회:학술대회논문집
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    • 2004.03a
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    • pp.126-131
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    • 2004
  • The interaction between the hypersonic free stream and the side jet flow at high altitudes is investigated by direct simulation Monte Carlo(DSMC) method. Since there is a great difference in density between the free stream and the side jet flow, the weighting factor technique which could control the number of simulation particles, is applied to calculate these two flows simultaneously. Chemical reactions are not considered in the calculation. For validation, the corner flow passing between a pair of plates that are perpendicularly attached is solved. The side jet flow is then injected into this comer flow and solution is found for the merged flow. Results are compared with the experiments. For a more realistic rocket model, the flow past a blunted cone cylinder shape is solved. The leeward or windward jet injection is merged with this flow. The effect on the rocket surface is observed at various flow angles. The lambda effect and the wake structure are found like low attitudes. High interaction between the free stream and the side jet flow is observed when the side jet is injected in the windward direction.

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The Effect of Process Oriented Guided Inquiry Learning Using Mobile Augmented Reality on Science Achievement, Science Learning Motivation, and Learning Flow in Chemical bond (화학 결합에서 모바일 증강현실을 이용한 과정기반 안내탐구학습이 과학 학업 성취도, 과학 학습 동기, 학습 몰입감에 미치는 영향)

  • Jeon, Young-Eun;Ji, Joon-Yong;Hong, Hun-Gi
    • Journal of The Korean Association For Science Education
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    • v.42 no.3
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    • pp.357-370
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    • 2022
  • In this paper, we developed an augmented reality learning tool suitable for chemical bond learning and proposed a process-oriented guided inquiry learning using mobile augmented reality (POGIL-MAR) to find out how it affects science achievement, science learning motivation and learning flow. Participants were 139 10th-grade students from a coeducational high school in Gyeonggi-do, and they were randomly assigned to the control group (TL), the treatment group 1 (POGIL), and the treatment group 2 (POGIL-MAR). They learned the concept of the chemical bond from the Integrated Science subject for four class periods. Results of two-way ANCOVA revealed that the POGIL-MAR group scored significantly higher than the other groups in a science achievement test, science learning motivation test, and learning flow test, regardless of their prior science achievement. In addition, in the case of the low-level group, the POGIL-MAR group showed a statistically significant improvement in achievement compared to the TL and POGIL groups. The MANCOVA analysis for sub-factors of science learning motivation show that the POGIL-MAR group had significantly higher scores in intrinsic motivation, career motivation, self-determination, self-efficacy, and grade motivation. In particular, the interaction effect between the teaching and learning method and the level of prior achievement was significant in the intrinsic motivation. Meanwhile, the MANCOVA analysis for sub-factors of learning flow show that the POGIL-MAR group had significantly higher scores in clear goals, unambiguous feedback, action-awareness merging, sense of control, and autotelic experience. Based on the results, educational implications for effective teaching and learning strategy using mobile augmented reality are discussed.

Experimental Evaluation Method of Mass Transfer Coefficient on Biotrickling Filtration for Air Pollution Control (대기오염제어를 위한 생물살수여과법에서 물질전달계수 실험평가방법에 관한 연구)

  • Won, Yang-Soo;Jo, Wan-Keun
    • Korean Chemical Engineering Research
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    • v.53 no.4
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    • pp.482-488
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    • 2015
  • Biological treatment is promising alternative to conventional air pollution control method. Bioreactors for air pollution control have found most of their success in the treatment of dilute and high flow waste air streams containing volatile organic compounds and odor. The studies of mass transfer in biotrickling filters for air pollution control were of importance in order to control and optimize the purification process. The objectives of this study were to develop the experimental methodologies to evaluate the mass transfer coefficients of gas/liquid(trickling liquid), gas/solid(biomass) and liquid/solid in three phase biotrickling filtration. Also, this study characterized the influence factors on mass transfer such as dynamic holdup volume, gas/liquid flow rate ratio, biomass weight in reactor and recirculation rate of trickling medium for each phase of biotrickling filter.

Development of CCD(Corrosion Control Document) in Refinery Process (정유공정의 CCD(Corrosion Control Document) 개발)

  • Kim, Jung-Hwan;Kim, Ji-Yong;Lee, Young-Hee;Park, Sang-Rok;Suh, Sun-Kyu;Lee, Yoon-Hwa;Moon, Il
    • Journal of the Korean Society of Safety
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    • v.24 no.1
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    • pp.31-36
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    • 2009
  • This paper focuses on techniques of improving refinery reliability, availability, and profitability. Our team developed a corrosion control document(CCD) for processing of the crude distillation unit(CDU). Recent study shows the loss due to corrosion in US is around $276 billion. It's a big concern for both managers and engineers of refinery industry. The CCD consists of numerous parts namely damage mechanism(DM), design data, critical reliability variable(CRV), guidelines, etc. The first step in the development of CCD is to build material selection diagram(MSD). Damage mechanisms affecting equipments and process need to be chosen carefully based on API 571. The selected nine DM from API 571 are (1) creep/stress rupture, (2) fuel ash corrosion, (3) oxidation, (4) high temperature sulfidation, (5) naphthenic acid corrosion, (6) hydrochloric acid(HCL) corrosion, (7) ammonium chloride(salt) corrosion, (8) wet $H_2S$ corrosion, and (9) ammonia stress corrosion cracking. Each DM related to corrosion of CDU process was selected by design data, P&ID, PFD, corrosion loop, flow of process, equipment's history, and experience. Operating variables affecting severity of DM are selected in initial stage of CRV. We propose the guidelines for reliability of equipments based on CRV. The CCD has been developed on the basis of the corrosion control in refinery industry. It also improves the safety of refinery process and reduces the cost of corrosion greatly.

Temperature-controlled Restrictor for UV Detection in Capillary Supercritical Fluid Chromatography

  • Pyo, Dong-Jin
    • Bulletin of the Korean Chemical Society
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    • v.27 no.9
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    • pp.1429-1432
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    • 2006
  • Polyaromatic hydrocarbons were separated by a capillary supercritical fluid chromatographic (SFC) column and detected by a UV detector at the wavelength of 280 $\mu$m. The temperature-controlled restrictor was designed for UV detection. The temperature-controlled restrictor is a 20 cm length of deactivated fused silica of 7 mm i.d. which is held right after UV detector of the capillary SFC. The temperature of the restrictor will control the flow rate of the supercritical carbon dioxide mobile phase through the capillary column in SFC. Thus as the pressure in the column is increased from 1500 psi to 4000 psi during a pressure program, the temperature of 7 $\mu$m fused-silica tube can be varied from 100 to 350 ${^{\circ}C}$ to maintain a constant flow rate.

Optimal shape design of a polymer extrusion die by inverse formulation

  • Na, Su-Yeon;Lee, Tai-Yong
    • 제어로봇시스템학회:학술대회논문집
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    • 1995.10a
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    • pp.315-318
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    • 1995
  • The optimum design problem of a coat-hanger die is solved by the inverse formulation. The flow in the die is analyzed using three-dimensional model. The new model for the manifold geometry is developed for the inverse formulation. The inverse problem for the optimum die geometry is formed as the optimization problem whose objective function is the linear combination of the square sum of pressure gradient deviation at die exit and the penalty function relating to the measure of non-smoothness of solution. From the several iterative solutions of the optimization problem, the optimum solution can be obtained automatically while producing the uniform flow rate distribution at die exit.

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Experimental Study for the Identification of the Nascent Product of OH Heterogeneous Reaction with NaCl using Chemical Ionization Mass Spectrometry

  • Park, Jong-Ho;Ivanov, Andrey V.;Molina, Mario J.
    • Mass Spectrometry Letters
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    • v.3 no.4
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    • pp.108-111
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    • 2012
  • An experimental study on the nascent product of the OH heterogeneous reaction with NaCl was performed under dry and wet conditions using a bead-filled flow tube system coupled to a high-pressure chemical ionization mass spectrometer. The ozone concentration in the flow tube for the atomic hydrogen removal was varied in order to control the conversion reaction of molecular chlorine into HCl for the identification of the nascent product. The mass spectrometric observation was that the $O_3$ introduction reduced the concentration HCl, while it increased the concentration of $Cl_2$ and ClO. Based on the experimental results, we suggest that the nascent product of the titled reaction is gaseous $Cl_2$, which is followed by fast conversion into HCl in presence of H. No significant difference in the concentration profile between under dry and wet (RH = 2%) conditions was observed.

Morphology Control of Single Crystalline Rutile TiO2 Nanowires

  • Park, Yi-Seul;Lee, Jin-Seok
    • Bulletin of the Korean Chemical Society
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    • v.32 no.10
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    • pp.3571-3574
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    • 2011
  • Nano-scaled metal oxides have been attractive materials for sensors, photocatalysis, and dye-sensitization for solar cells. We report the controlled synthesis and characterization of single crystalline $TiO_2$ nanowires via a catalyst-assisted vapor-liquid-solid (VLS) and vapor-solid (VS) growth mechanism during TiO powder evaporation. Scanning electron microscope (SEM) and transmission electron microscope (TEM) studies show that as grown $TiO_2$ materials are one-dimensional (1D) nano-structures with a single crystalline rutile phase. Also, energy-dispersive X-ray (EDX) spectroscopy indicates the presence of both Ti and O with a Ti/O atomic ratio of 1 to 2. Various morphologies of single crystalline $TiO_2$ nano-structures are realized by controlling the growth temperature and flow rate of carrier gas. Large amount of reactant evaporated at high temperature and high flow rate is crucial to the morphology change of $TiO_2$ nanowire.