• Proceedings of the Korea Concrete Institute Conference
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• 2006.05b
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• pp.169-172
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• 2006

The IIA structures exposed to marine environment is subject to many different types of potential attack. The physical attack due to drying and wetting would increase the internal stress of concrete. The chemical attack resulting from the diffusion of ions$(Cl^-,SO_4^{2-},Mg^+)$ from seawater through the pores in concrete. Therefore the sea water resistance of concrete must be considered when it is used for structure in the ocean. The objective of this study is to evaluate chloride diffusion and corrosion characteristics of concrete when using the various concrete materials under marine environment. After 5 years of exposure, concrete incorporating 40% blast-furnace slag as replacement for type I cement with low w/c ratio of 0.42 and using the inhibitor shows excellent performance.

• Proceedings of the Korea Concrete Institute Conference
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• 1998.04b
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• pp.683-686
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• 1998

In this paper, we carried out the fundamental experiments on the resistance of chemical attack of mortar using the electric are furnace slag as fine aggregate. The mortar specimens made from the EAF slag as fine aggregate were immersed in four sorts of chemical solutions, and measured to investigate the change of compressive strength and weight. As the results of this study, it was found that compressive strength and weight were increased with incresing replacement ratio of the EAF slag.

• Journal of the Korea institute for structural maintenance and inspection
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• v.9 no.2
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• pp.173-180
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• 2005

Metakaolin is a cementitious material for producing high-strength concrete. This material is now used as substitute for silica-fume. In this paper, we did the mechanical and durability test such as compressive/tensile/flexural strength test, chloride ion diffusion, chemical attack and repeated freezing and thawing, carbonation test. In the mechanical tests, 10~15% for binder is optimum substitute rate. And, in the chloride ion diffusion test, according to the increase of substitute of metakaolin & silica-fume for binder, the diffusion coefficient was more reduced. In the chemical attack test, by the filler effect of fine powder such metakaolin and silica-fume, the resistance is more excellent than normal concrete. In the other durability test, the concrete using metakaolin also compared with those of silica-fume substitute concrete. Through these tests, we recognized that metakaolin can be used as a substitute for silica-fume.

• Proceedings of the Korea Concrete Institute Conference
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• 2008.11a
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• pp.733-736
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• 2008

In this study, we developed durability promoting chemical agent(HD) that simultaneously improved resistance for chloride attack and shrinkage of concrete. This agent as typed aqueous solution containing organic and inorganic compounds applied to concrete mix(Bx0.6%, 1.2%) of seaside construction using SLG and then evaluated the effect on the shrinkage and chloride attack of concrete. By the addition of HD, it was elucidated that resistance for chloride attack and shrinkage were improved above 50% and 33% respectively than non-added concrete(Plain). This performance was confirmed through the Field-test applied HD(Bx0.6%) such as RCD construction.

• Journal of the Korea institute for structural maintenance and inspection
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• v.15 no.1
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• pp.129-137
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• 2011

This study aims to evaluate the resistance to seawater attack of mortars and concretes incorporating limestone powder (0, 10, 20 and 30% of cement by mass). In order to achieve this goal, both chemical resistance by seawater and chloride ions penetration resistance of mortars or concretes were regularly monitored. From the test results, it was observed that the durability of cement matrix was greatly dependent on the replacement ratios of limestone powder. In other words, performance of cement matrix with 10% limestone powder was similar to that of OPC matrix. However, it was found that a high replacement ratio of limestone powder was ineffective to resist seawater attack.

• Bulletin of the Korean Chemical Society
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• v.24 no.5
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• pp.583-592
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• 2003

The gas phase identity nucleophilic substitution reactions of halide anions (X = F, Cl, Br) with cyclopentadienyl halides (1) are investigated at the B3LYP/6-311+G**, MP2/6-311+G** and G2(+)MP2 levels involving five reaction pathways: σ-attack $S_N2$, β-$S_N$2'-syn, β-$S_N$2'-anti, γ-$S_N$2'-syn and γ-$S_N$2'-anti paths. In addition, the halide exchange reactions at the saturated analogue, cyclopentyl halides (2), and the monohapto circumambulatory halide rearrangements in 1 are also studied at the same three levels of theory. In the σ-attack $S_N2$ transition state for 1 weak positive charge develops in the ring with X = F while negative charge develops with X = Cl and Br leading to a higher energy barrier with X = F but to lower energy barriers with X = Cl and Br than for the corresponding reactions of 2. The π-attack β-$S_N$2' transition states are stabilized by the strong $n_C-{\pi}^{*}_{C=C}$ charge transfer interactions, whereas the π-attack γ-$S_N$2' transition states are stabilized by the strong $n_C-{\sigma}^{*}_{C-X}$ interactions. For all types of reaction paths, the energy barriers are lower with X = F than Cl and Br due to the greater bond energy gain in the partial C-X bond formation with X = F. The β-$S_N$2' paths are favored over the γ-$S_N$2' paths only with X = F and the reverse holds with X = Cl and Br. The σ-attack $S_N2$ reaction provides the lowest energy barrier with X = Cl and Br, but that with X = F is the highest energy barrier path. Activation energies for the circumambulatory rearrangement processes are much higher (by more than 18 kcal $mol^{-1}$) than those for the corresponding $S_N2$ reaction path. Overall the gas-phase halide exchanges are predicted to proceed by the σ-attack $S_N2$ path with X = Cl and Br but by the β-$S_N$2'-anti path with X = F. The barriers to the gas-phase halide exchanges increase in the order X = F < Br < Cl, which is the same as that found for the gas-phase identity methyl transfer reactions.

• Journal of the Korea Concrete Institute
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• v.14 no.3
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• pp.409-419
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• 2002

Nowadays, antiwashout underwater concrete is widely used for constructing underwater concrete structures but they, especially placed in marine environment, can be easily attacked by chemical ions such as SO$\^$2-/$\_$4/ Cl$\^$-/ and Mg$\^$2＋/, so the quality and capability of concrete structures go down. In this paper, to solve and improve those matters, flyash and GGBFS(ground granulated blast furnace slag) were used as partial replacements for ordinary portland cement. As results of experiments for fundamental properties of antiwashout underwater concrete containing 10, 20, 30％ of flyash and 40, 50, 60 ％ of GGBFS respectively, setting time, air contents, suspended solids and pH value were satisfied with the "Standard Specification of Antiwashout Admixtures for Concrete" prescribed by KSCE, and also slump flow, efflux time and elevation of head were more improved than that of control concrete. From the compressive strength test, it was revealed that the antiwashout underwater concrete containing mineral admixtures(flyash and GGBFS) is more effective for long term compressive strength than control concrete. An attempt to know how durable when they are under chemical attack has also been done by immersing in chemical solutions that were x2 artificial seawater, 5 ％ sulphuric acid solution, 10％, sodium sulfate solution and 10％ calcium chloride solution. After immersion test for 91days, XRD analysis was carried out to investigate the reactants between cement hydrates and chemical ions and some crystalline such as gypsum ettringite and Fridel′s salt were confirmed.

• Journal of the Korea Concrete Institute
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• v.11 no.4
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• pp.13-20
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• 1999

Recently, the study for practical construction application no recycled aggregate concrete is actively being proceeded, on the purpose of technical development for recycling on the construction waste concrete occurred at the time of destruction of building construction by the rapid increase of building wastes and exhaustion of natural aggregates. But, the durability of investigation with all sorts of fluidity and engineering property for application recycled aggregate concrete to practical construction must be done at the same time. Especially, because of the real condition for chemical attack of concrete construction by the acid rain, acidification of soil, deepening of air pollution and dirty water etc. being come to the fore a serious problem, the study on the chemical soundness of concrete durability must be accompanied. This study is composed as: I series: Analysis for chemical soundness of aggregates. II series: Analysis for chemical soundness of natural and recycled aggregate concrete against $Na_2$$SO_4$ solution in drying and wet curing condition ($at20~80^{\circ}C$).

• Bulletin of the Korean Chemical Society
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• v.13 no.2
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• pp.135-139
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• 1992

The mono(aryl)cyanoplatinum(II) complex $[Pt(CN)(C_6H_3{CH_2NMe_2}_2-26)]$, reacts with the dihalogens to yield the mono(aryl)cyanoplatinum complexes $[PtX_2(CN)(C_6H_3{CH_2NMe_2}_2-26)]$, (X = Cl, Br, I). The structural configuration of the two halogen atoms for a square planar platinum complex was studied by 1H-NMR spectroscopy and led to a mixture of trans and cis orientation. The trans orientation was found to be more stable in energy (1.33 kcal/mol) than the cis orientation by means of Extended H ckel calculations. On the base of a combination of the analysis of $^1H-NMR$, $^{13}C-NMR spectra and computational calculations it is assumed that the intermediate consists of an initial attack in the linear transition state, leading to the $S_{N}2$ type mechanism.

• Bulletin of the Korean Chemical Society
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• v.35 no.3
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• pp.753-757
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• 2014

The nucleophilic substitution reactions of Y-aryl N,N-dimethyl phosphoroamidochloridates with substituted anilines and deuterated anilines are kinetically investigated in acetonitrile at $65.0^{\circ}C$. A stepwise mechanism with a rate-limiting leaving group departure from the intermediate is proposed based on the positive ${\rho}_{XY}$ value. The deuterium kinetic isotope effects involving deuterated anilines show secondary inverse with all the nucleophiles, rationalized by a dominant backside nucleophilic attack.