• Title/Summary/Keyword: Chemical attack

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The characteristics of compressive strength resistance of concrete combined with corrosion inhibitors and mineral admixtures under simulated tidal condition (인공 해수 간헐 조건에서의 방청제 및 혼화재를 사용한 콘크리트 압축강도 및 저항의 특성)

  • 이용은;장태순;양우석
    • Proceedings of the Korea Concrete Institute Conference
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    • 1998.04b
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    • pp.641-646
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    • 1998
  • The structures exposed to marine environment do not show long-term durability due to corrosion of steel and deterioration of concrete by the attack of various salts dissolved in sea water. In this study, Partial substitution of cement with fly ash(20%) or blast furnace slag(40%) was made together with the addition of 4 different corrosion-inhibitors, as a protective measure of concrete structures against chemical attack of salts. Combined effects of mineral and corrosion-inhibiting admixtures were tested by measuring the resistance and compressive strength of concretes under the simulated tidal condition, which consists of alternating 12 hour periods of immersion in artificial sea water and drying in air. Both the strength and concrete resistance were found to decrease in following order, regardless of the corrosion inhibitors the concretes with blast furnace slag, those with fly ash and those without any mineral admixtures. The interrelation between compressive strength of concrete and resistance was investigated.

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$SiH_4$ Soak Effects for Optimization of Tungsten Plug Deposition on TiN Barrier Metal

  • Kim, Sang-Yang;Seo, Yong-Jin;Lee, Woo-Sun;Chung, Hun-Sang;Kim, Chang-Il;Chang, Eui-Goo;Chung, Yong-Ho
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2001.05b
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    • pp.54-56
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    • 2001
  • The $SiH_4$ soak step is widely used during the CVD Tungsten(W) plug deposition process on the Ti/TiN barrier metal to prevent the $WF_6$ attack to the underlayer metal. We tried to reduce or skip the time of $SiH_4$ soak process to optimize W-plug deposition process on Via. The electrical characteristics including Via resistance and the structure of W film are affected according to $SiH_4$ soak time. The elimination possibility of $SiH_4$ soak process was confirmed in the case of that the CVD W film grows on the stable Ti/TiN underlayer.

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Terrorism using biological weapons and Countermeasures (생물무기에 의한 테러와 대응책)

  • Jo, Sung-Ho
    • Korean Security Journal
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    • no.7
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    • pp.287-307
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    • 2004
  • Mass killing and injuring by purpose, the countries that is hurrying countermeasure preparation of investigators who enforce that necessity to compare to intimidation of doing creature weapon is common concerns of the several countries including advanced nation such as the United States of America. Development and use of biological weapon have increased too recently to private citizens unlike development of military purpose in country dimension. The latest WHO is preparing proposal of standard stroke model who each department solidifies preparedness for chemical biological and electronic weapon revising report about biological weapon. But in case of korea, confrontation plan that bamboo broom about possibility of attack to the common people and attack comparing actual state in case of attained nothing but is readying remedy about biological warfare partially in military dimension was not readied. The purpose of this article is a study on threat of bio-weapons and the countermeasure.

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An Experimental Study on the Engineering Properties of Concrete Spread with Liquefied Antibiotics (액상 항균제를 도포한 하수시설용 콘크리트의 공학적 특성에 관한 실험적 연구)

  • Lee Eui-Bae;Kim Yong-Duk;Cho Bong-Suk;Kim Jae-Hwan;Khil Bae-Su;Kim Moo-Han
    • Proceedings of the Korea Concrete Institute Conference
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    • 2005.05b
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    • pp.233-236
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    • 2005
  • Sewage facilities are positively necessary for environment improvement such as rainwater removal, sewage disposal, preservation of the quality of water and health of the citizens in present-day. Meanwhile, a deterioration of the concrete sewer facilities is increasing rapidly due to the chemical and physical attack and especially biochemical attack that is to say biodeterioration. In this study, to prevent biochemical corrosion of the sewer concrete, surface of the concrete was spread with liquefied organic and inorganic complex antibiotics and then its engineering properties were experimentally investigated

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The Evaluation of Durability and Bond of Resin Concrete (레진 콘크리트의 부착성 및 내구성 평가)

  • Yoo Sung Won;Suh Jeong In;Jeon Sung Hwan;Hwang Sun Bok
    • Proceedings of the Korea Concrete Institute Conference
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    • 2004.11a
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    • pp.715-718
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    • 2004
  • The evaluation of durability of resin concrete was examined through various tests, i.e., compressive strength, absorption, abrasion, chemical attack resistance and bond between general and resin concrete. 2 types of concrete were used such as 40 MPa of general concrete and 90 MPa of resin concrete. The characteristics of resin concrete was more improved than that of general concrete, and especially, resin concrete was most effective on compressive strength, the resistance to $H_2SO_4$ solution attack and absorption. However, abrasion. is almost same between general concrete and resin concrete.

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An Experimental Study on Measurement of Corrosion Initiation in Reinforced Concrete Exposed to Chloride Using EIS Method (EIS를 이용한 염해에 노출된 철근콘크리트의 부식개시 측정에 관한 실험적 연구)

  • Park, Dong-Jin;Park, Jang-Hyun;Lee, Kwang-Soo;Lee, Han-Seung
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2017.11a
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    • pp.61-62
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    • 2017
  • In this study, the initiation of steel corrosion was monitored due to chloride attack using embedded sensor. In general, Steel bars embedded in concrete are protected from corrosion by being forming a passive film on the surface. However, the passive film is destroyed by chemical erosion such as concrete carbonation and chloride penetration, and the rebar is exposed to the deteriorating factor and corrosion proceeds. In order to realize the initiation of steel corrosion, OCP and change of Impedance parameter were observed by using Half-cell and EIS method depending on cover depth. As result, 10mm cover showed the impedence increased in 6weeks.

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Magnesium Sulfate Resistance of Concrete Containing Waste Glass (폐유리를 혼입한 콘크리트의 황산마그네슘 저항성에 관한 연구)

  • Kim, Young-Su;Jeong, Yoo-Jin;Lee, Dong-Un
    • Journal of the Korea Institute of Building Construction
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    • v.9 no.3
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    • pp.109-116
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    • 2009
  • The magnesium sulfate solution digestion test carried out for resistance of concrete containing waste glass powder on magnesium sulfate attack. Moreover, it yielded S.D.F index was used for the criteria of quantitative assessment to the resistance of magnesium sulfate for the purpose of evaluation of chemical deterioration on concrete. Furthermore, to evaluate for micro-cracks within concrete and external corrosion, the weight variation of specimens and the dynamic elasticity were compared and analyzed and also the applicability was examined using the analysis of product of hydration through out observing external deformation and micro-structural deformation.

Effect of Adding Scoria as Cement Replacement on Durability-Related Properties

  • al-Swaidani, Aref Mohamad;Aliyan, Samira Dib
    • International Journal of Concrete Structures and Materials
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    • v.9 no.2
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    • pp.241-254
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    • 2015
  • A lot of reinforced concrete (RC) structures in Syria went out of service after a few years of construction. This was mainly due to reinforcement corrosion or chemical attack on concrete. The use of blended cements is growing rapidly in the construction industry due to economical, ecological and technical benefits. Syria is relatively rich in scoria. In the study, mortar/concrete specimens were produced with seven types of cement: one plain Portland cement (control) and six blended cements with replacement levels ranging from 10 to 35 %. Rapid chloride penetration test was carried in accordance with ASTM C 1202 after two curing times of 28 and 90 days. The effect on the resistance of concrete against damage caused by corrosion of the embedded steel has been investigated using an accelerated corrosion test by impressing a constant anodic potential. The variation of current with time and time to failure of RC specimens were determined at 28 and 90 days curing. In addition, effects of aggressive acidic environments on mortars were investigated through 100 days of exposure to 5 % $H_2SO_4$, 10 % HCl, 5 % $HNO_3$ and 10 % $CH_3COOH$ solutions. Evaluation of sulfate resistance of mortars was also performed by immersing in 5 % $Na_2SO_4$ solution for 52 weeks. Test results reveal that the resistance to chloride penetration of concrete improves substantially with the increase of replacement level, and the concretes containing scoria based-blended cements, especially CEM II/B-P, exhibited corrosion initiation periods several times longer than the control mix. Further, an increase in scoria addition improves the acid resistance of mortar, especially in the early days of exposure, whereas after a long period of continuous exposure all specimens show the same behavior against the acid attack. According to results of sulfate resistance, CEM II/B-P can be used instead of SRPC in sulfate-bearing environments.

Assessment of strength and durability of bagasse ash and Silica fume concrete

  • Singaram, Jayanthi;Kowsik, Radhika
    • Computers and Concrete
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    • v.17 no.6
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    • pp.801-814
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    • 2016
  • An alternative type of building system with masonry units is extensively used nowadays to reduce the emission of CO2 and embodied energy. Long-term performance of such structures has become essential for sustaining the building technology. This study aims to assess the strength and durability properties of concrete prepared with unprocessed bagasse ash (BA) and silica fume (SF). A mix proportion of 1:3:3 was used to cast concrete cubes of size $100mm{\times}100mm{\times}100mm$ with various replacement levels of cement and tested. The cubes were cast with zero slump normally adopted in the manufacturing of hollow blocks. The cubes were exposed to acid attack, alkaline attack and sulphate attack to evaluate their durability. The mass loss and damages to concrete for all cases of exposures were determined at 30, 60, and 90 days, respectively. Then, the residual compressive strength for all cases was determined at the end of 90 days of durability test. The results showed that there was slight difference in mass loss before and after exposure to chemical attack in all the cases. Though the appearance was slightly different than the normal concrete the residual weight was not affected. The compressive strength of 10% bagasse ash (BA) as a replacement for cement, with 10% SF as admixture resulted in better strength than the normal concrete. Hence concrete with 10% replacement with BA along with 10% SF as admixture was considered to be durable. Besides solid concrete cubes, hollow blocks using the same concrete were casted and tested simultaneously to explore the possibility of production of masonry units.

Surface Preparation of III-V Semiconductors

  • Im, Sang-U
    • Proceedings of the Korean Vacuum Society Conference
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    • 2015.08a
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    • pp.86.1-86.1
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    • 2015
  • As the feature size of Si-based semiconductor shrinks to nanometer scale, we are facing to the problems such as short channel effect and leakage current. One of the solutions to cope with those issues is to bring III-V compound semiconductors to the semiconductor structures, because III-V compound semiconductors have much higher carrier mobility than Si. However, introduction of III-V semiconductors to the current Si-based manufacturing process requires great challenge in the development of process integration, since they exhibit totally different physical and chemical properties from Si. For example, epitaxial growth, surface preparation and wet etching of III-V semiconductors have to be optimized for production. In addition, oxidation mechanisms of III-V semiconductors should be elucidated and re-growth of native oxide should be controlled. In this study, surface preparation methods of various III-V compound semiconductors such as GaAs, InAs, and GaSb are introduced in terms of i) how their surfaces are modified after different chemical treatments, ii) how they will be re-oxidized after chemical treatments, and iii) is there any effect of surface orientation on the surface preparation and re-growth of oxide. Surface termination and behaviors on those semiconductors were observed by MIR-FTIR, XPS, ellipsometer, and contact angle measurements. In addition, photoresist stripping process on III-V semiconductor is also studied, because there is a chance that a conventional photoresist stripping process can attack III-V semiconductor surfaces. Based on the Hansen theory various organic solvents such as 1-methyl-2-pyrrolydone, dimethyl sulfoxide, benzyl alcohol, and propylene carbonate, were selected to remove photoresists with and without ion implantation. Although SPM and DIO3 caused etching and/or surface roughening of III-V semiconductor surface, organic solvents could remove I-line photoresist without attack of III-V semiconductor surface. The behavior of photoresist removal depends on the solvent temperature and ion implantation dose.

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