• Title/Summary/Keyword: Chemical and physical characteristics

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Effects of Ultrasonic Cleaning and Chemical Pre-treatment on the Characteristics of Fast-stabilized Rayon Fabrics (빠르게 안정화된 레이온직물의 특성에 미치는 초음파세척 및 화학전처리 영향)

  • Cho, Chae Wook;Cho, Donghwan
    • Journal of Adhesion and Interface
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    • v.14 no.3
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    • pp.146-159
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    • 2013
  • In the present study, stabilized rayon fabrics were prepared from fast isothermal stabilization processes, which were carried out within four minutes at $350^{\circ}C$. The effects of ultrasonic cleaning and chemical pre-treatment on the chemical composition, physical characteristics, X-ray diffraction pattern, thermal stability and shape of the stabilized rayon fabrics were investigated extensively. In order to reduce the weight loss and thermal shrinkage of rayon fabrics occurring during the stabilization process, ultrasonic cleaning was first conducted and then chemical pre-treatments using $NH_4Cl$, $Na_3PO_4$, $H_3PO_4$, and $ZnCl_2$ were performed, respectively. The results indicated that both ultrasonic cleaning and chemical pre-treatment influenced the weight loss, thermal shrinkage, microstructure, carbon content, thermal stability and fabric shape of stabilized rayon fabrics. Also the results depended on the fast-stabilization time and the type of chemical pre-treatment agents used.

Durability Characteristics of Blended Cement Mortars (혼합 시멘트 모르타르의 내구특성)

  • 원종필;이찬민;박찬기
    • Magazine of the Korean Society of Agricultural Engineers
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    • v.45 no.3
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    • pp.41-49
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    • 2003
  • In this study, durability performance of blended cement mortars is evaluated when various mineral admixtures are used with the cement. A comprehensive evaluation of the effects of mineral admixtures on the mortar performance was made. The properties of fresh and hardened blended mortars investigated include slump flow and compressive strength. The durability characteristics of cement materials incorporating the mineral admixtures under various physical and chemical causes of deterioration was investigated. The laboratory test results indicate that mechanical and durability properties of blended cement mortars have superior performance rather than ordinary cement mortars.

Preparation ann their Characteristics of Microcapsules for Fragrant Fiber

  • Kijeong Hong;Park, Soomin
    • Proceedings of the Korean Fiber Society Conference
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    • 1998.10a
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    • pp.162-165
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    • 1998
  • Characteristics of microcapsule wall depend on chemical and physical condition in procedure such as type and concentration of constituent and microencapsulation methods, thus, if the other process conditions are same, they depend on mainly types of wall-forming materials. Isocyanates used in this study are very important constituent as hard segments preparing urethane or urea by reaction with alcohol or amine. (omitted)

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Wood Properties of Quercus acuta Thunb. (붉가시나무의 목재성질)

  • Chong, Song-Ho;Park, Byung-Su;Chung, Doo-Jin;Lee, Do-Sick;Cho, Sung-Taek;Chun, Su-Kyoung
    • Journal of the Korea Furniture Society
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    • v.18 no.1
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    • pp.39-46
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    • 2007
  • This study was carried out to investigate the wood properties for efficient utilization of warm temperate tree species of Quercus acuta Thunb. grown in Korea. Fundamental wood properties in the anatomical, physical, mechanical and chemical characteristics were examined. Quercus acuta Thunb. is a radial-porous, straight grained and fine textured wood. The heartwood is not clearly distinguished from the sapwood. In physical properties, it has a high oven-dry specific gravity of $0.85{\pm}0.02$, and high shrinkage from green to air-dried condition of $7.05{\pm}0.52%$ in radial and $11.13{\pm}0.48%$ in tangential direction. Mechanical properties determined are strong with the MOR of $1,065{\pm}90kgf/cm^2$, and tensile strength parallel to grain of $1,490{\pm}258kgf/cm^2$ and shear strength of $175{\pm}13kgf/cm^2$. Also, this wood has high extractive contents: 11.11% for cold and 13.51% for hot water.

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Activated Carbon-Nickel (II) Oxide Electrodes for Capacitive Deionization Process

  • Gandionco, Karl Adrian;Kim, Jin Won;Ocon, Joey D.;Lee, Jaeyoung
    • Applied Chemistry for Engineering
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    • v.31 no.5
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    • pp.552-559
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    • 2020
  • Activated carbon-nickel (II) oxide (AC-NiO) electrodes were studied as materials for the capacitive deionization (CDI) of aqueous sodium chloride solution. AC-NiO electrodes were fabricated through physical mixing and low-temperature heating of precursor materials. The amount of NiO in the electrodes was varied and its effect on the deionization performance was investigated using a single-pass mode CDI setup. The pure activated carbon electrode showed the highest specific surface area among the electrodes. However, the AC-NiO electrode with approximately 10 and 20% of NiO displayed better deionization performance. The addition of a dielectric material like NiO to the carbon material resulted in the enhancement of the electric field, which eventually led to an improved deionization performance. Among all as-prepared electrodes, the AC-NiO electrode with approximately 10% of NiO gave the highest salt adsorption capacity and charge efficiency, which are equal to 7.46 mg/g and 90.1%, respectively. This finding can be attributed to the optimum enhancement of the physical and chemical characteristics of the electrode brought by the addition of the appropriate amount of NiO.

Direct Growth of Graphene at Low Temperature for Future Device Applications

  • Kim, Bum Jun;Nasir, Tuqeer;Choi, Jae-Young
    • Journal of the Korean Ceramic Society
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    • v.55 no.3
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    • pp.203-223
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    • 2018
  • The development of two-dimensional graphene layers has recently attracted considerable attention because of its tremendous application in various research fields. Semi-metal materials have received significant attention because of their excellent biocompatibility as well as distinct physical, chemical, and mechanical properties. Taking into account the technical importance of graphene in various fields, such as complementary metal-oxide-semiconductor technology, energy-harvesting and -storage devices, biotechnology, electronics, light-emitting diodes, and wearable and flexible applications, it is considered to be a multifunctional component. In this regard, material scientists and researchers have primarily focused on two typical problems: i) direct growth and ii) low-temperature growth of graphene. In this review, we have considered only cold growth of graphene. The review is divided into five sections. Sections 1 and 2 explain the typical characteristics of graphene with a short history and the growth methods adopted, respectively. Graphene's direct growth at low temperatures on a required substrate with a well-established application is then precisely discussed in Sections 3 and 4. Finally, a summary of the review along with future challenges is described in Section 5.

A Study on Durability Improvement of Concrete Using Glycol Ether Chemical Admixture (글리콜에테르계 혼화제가 콘크리트의 내구성 향상에 미치는 영향에 관한 연구)

  • Kim, Kwang-Ki;Song, In-Myung;Jung, Sang-Jin
    • Journal of the Korea Institute of Building Construction
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    • v.7 no.4
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    • pp.117-124
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    • 2007
  • Focused on the material-related aspect for enhancing the durability of concrete, the present study analyzed the effect of glycol ether admixture, which is a chemical admixture that can compact the structure of concrete by entraining air inside the concrete, on the basic physical properties and durability characteristic of the concrete. In analyzing the results of experiment, we examined the basic physical properties and durability characteristic of concrete according to addition rate based on OPC and selected the optimal addition rate. In addition, with the optimal addition rate, we added glycol ether admixture to concrete, which contained fly ash used as binder and high-performance water reducing agent for reducing the unit quantity, and examined changes in the characteristics of the concrete. According to the result, the optimal addition rate of glycol ether admixture was 3% of the unit quantity of cement, and the addition of binder and chemical admixture did not have a significant effect on unhardened concrete but reduced the air content. In addition, concrete showed resistance performance of around 30% to carbonation and around 40% to drying shrinkage. In addition, as for resistance to freezing and thawing, the relative dynamic modulus of elasticity was over around 85% through atmospheric curing. These performances prove the effect.

Adsorption Equilibrium of Bovine Serum Albumin Protein on Porous Polymer Microgels (다공성 고분자 마이크로겔의 Bovine Serum Albumin 단백질의 흡착평형)

  • Kim, Kong-Soo;Kang, Seog-Ho
    • Applied Chemistry for Engineering
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    • v.9 no.2
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    • pp.311-316
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    • 1998
  • The adsorption equilibrium properties of bovine serum albumin(BSA-protein) for three kinds of porous microgels with different physical and chemical features were investigated. The adsorption amount of BSA-protein on poly(butyl methacrylate)(PBMA) microgels was higher than those on poly(vinyl pyridine)(PVP) and poly(acrylonitrile) (PAN) microgels due to the hydrophobic interaction between polymer and protein in an aqueous solution. And PBMA microgels had more irreversible adsorption equilibrium properties the PVP and PAN microgels. It implies that hydrophobic interaction plays a more important role in adsorption properties of BAS-protein than physical properties of polymer and electrostatic attraction between protein and polymer microgels. Characteristics of the microgels used in this study followed Langmuir equation better than the Freundlich equation.

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Effect of H2O2 modification of H3PW12O40@carbon for m-xylene oxidation to isophthalic acid

  • Fang, Zhou-wen;Wen, Di;Wang, Zhi-hao;Long, Xiang-li
    • Korean Journal of Chemical Engineering
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    • v.35 no.11
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    • pp.2172-2184
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    • 2018
  • The production of isophthalic acid (IPA) from the oxidation of m-xylene (MX) by air is catalyzed by $H_3PW_{12}O_{40}$ (HPW) loaded on carbon and cobalt. We used $H_2O_2$ solution to oxidize the carbon to improve the catalytic activity of HPW@C catalyst. Experiments reveal that the best carbon sample is obtained by calcining the carbon at $700^{\circ}C$ for 4 h after being impregnated in the 3.75% $H_2O_2$ solution at $40^{\circ}C$ for 7 h. The surface characterization displays that the $H_2O_2$ modification leads to an increase in the acidic groups and a reduction in the basic groups on the carbon surface. The catalytic capability of the HPW@C catalyst depends on its surface chemical characteristics and physical property. The acidic groups play a more important part than the physical property. The MX conversion after 180 min reaction acquired by the HPW@C catalysts prepared from the activated carbon modified in the best condition is 3.81% over that obtained by the HPW@C catalysts prepared from the original carbon. The IPA produced by the former is 46.2% over that produced by the latter.

A Study on the Properties and Fabrication of Bulk Forming GeSe Based Chalcogenide Glass for Infrared Optical Lens (적외선 광학렌즈 제작을 위한 GeSe의 벌크 제작 및 특성 연구)

  • Bae, Dong-Sik;Yeo, Jong-Bin;Park, Jung-Hoo;Lee, Hyun-Yong
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.26 no.9
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    • pp.641-645
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    • 2013
  • Chalcogenide glass has superior property of optical transmittance in the infrared region. Glass made using Ge-Se how many important optical applications. We have determined the composite formular of $Ge_{0.25}Se_{0.75}$ to be the GeSe chalcogenide glass composition appropriate for IR lenses. Also, the optical, thermal and physical characteristics of chalcogenide glass depended on the composition ratio. GeSe bulk sample is produced using the traditional melt-quenching method. The optical, structural, thermal and physical properties of the compound were measured by using Fourier transform infrared spectroscopy (FT-IR), X-ray diffraction (XRD), Differential scanning calorimeter (DSC), and Scanning electron microscope (SEM) respectively.