• Title/Summary/Keyword: Chemical accident prevention

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Effect of Proof Test of Protective System on Securing Safety of Off-site Risk Assessment (보호시스템 보증시험 적용이 장외영향평가 안전성 확보에 미치는 영향)

  • Kim, Min-Su;Kim, Jae-Young;Lee, Eun-Byeol;Yoon, Junheon;Park, Jai Hak
    • Journal of the Korean Society of Safety
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    • v.32 no.6
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    • pp.46-53
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    • 2017
  • The risk is expressed as consequence of damage multiplied by likelihood of failure. The installation of a protective system reduces the risk by reducing the likelihood of failure at the facility. Also, the protective system has different effects on the likelihood of failure according to the proof test cycle. However, when assessing risks in the Off-site Risk Assessment (ORA) system, the variation in risk was not reflected according to the proof test cycle of protective system. This study was conducted to examine the need for proof test and the importance of cycle setting by applying periodic proof test of the protective system to ORA. The results showed that the likelihood of failure and the risk increased with longer proof test cycle. The risk of a two-yearly proof test was eight times greater than that of a three-month cycle. From the results, the protective system needs periodic proof test. Untested protective system for a long term cannot be reliable because it is more likely to be failed state when it is called upon to operate. In order to reduce the risk to an acceptable level, it is effective to differently set the proof test cycle according to the priority. This study suggested a more systematic and accurate risk analysis standard than ORA. This standard is expected to enable an acceptable level of risk management by systematically setting the priority and proof test cycle of the protective system. It is also expected to contribute to securing the safety of chemical facilities and at the same time, will lead to the development of the ORA system.

Estimation of Temporal Acute Exposure Guideline Levels for Emergency Response - A Brief Case using Formaldehyde - (화학사고 대응을 위한 시간별 급성노출기준 참고치 산정 - 폼알데하이드 사례 -)

  • Kim, Eunchae;Cho, Yong-Sung;Lee, Chung-Soo;Yang, Wonho;Hwang, Seung-Ryul;Park, Jihoon
    • Journal of Environmental Health Sciences
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    • v.47 no.2
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    • pp.166-174
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    • 2021
  • Objectives: This study aimed to provide temporal Acute Exposure Guideline Levels (AEGL) for a hazardous substance as a pilot study. Methods: As one of the substances designated by the Korea Ministry of Environment as requiring preparations for potential accidents, formaldehyde was selected to estimate the AEGLs. The calculation was based on Haber's formula (Cn×t=k) using valid toxicity data (for humans/animals). A total of 96 points of AEGL levels were provided using an interval of five minutes over eight hours. Results: The AEGL-1 and 2 values were constant for the entire exposure duration at 0.9 ppm and 14 ppm, respectively. The values were obtained from clinical/animal tests, and the adaptation effect after a given exposure duration was also considered. AEGL-3 was based on animal toxicity data, and it was estimated from 127 ppm for the initial five minutes to 35 ppm for eight hours. Conclusions: More specific AEGL levels for formaldehyde could be obtained in this study using toxicity data with Haber's formula. Based on this methodology, it would be also possible to estimate AEGL levels that can be used at the scene of a chemical accident for other substances requiring preparation for potential accidents.

Risk Analysis of Off-site Risk Assessment using Vulnerability by Environmental Medium (환경매체별 취약성을 반영한 장외영향평가 위험도 분석)

  • Choi, Woo Soo;Back, Jong Bae
    • Journal of the Korean Society of Safety
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    • v.33 no.5
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    • pp.150-156
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    • 2018
  • As the types and usage of chemical increase, modern countries should protect their health and environment from the risk of hazardous chemical. Chemical accidents not only affect humans but also cause huge losses to the environment. Moreover, since its effects do not end in a short period of time, it is necessary to identify the extent of the damage and establish a prevention and response system in advance. In 2015, the Chemical Substances Management Act provided a system for assessing the impact on the people and the environment around the workplace. However, it is difficult to quantitatively evaluate the impact on environmental factors such as vegetation and aquatic, with the current hazard assessment methods. The purpose of this study is to analyze the quantitative risk of environmental receptors. This study improved the existing risk assessment formula by using the environmental vulnerability index and established the end point concentration criterion which can estimate the damage range to environmental media. To verify the results of the study, a virtual accident scenario was selected and a case study was conducted. As a result, the extent of impact on the environmental medium can be calculated, and the degree of environmental risk of the zone can be quantified through the risk analysis considering the environmental vulnerability. This study is expected to increase the reliability of the reliability of the existing risk anaylsis method beacause it is a risk analysis method that can be applied when the environmental factors are absolutely necessary and when the residents and environment are complex.

Development of a Supporting Program for the Emergency Preparedness Plan (사고대비물질 취급자의 비상대응계획 작성 프로그램 연구)

  • Kim, Sung-Bum;Noh, Hye-Ran;Seok, Gwang-Seol;Park, Jae-Deuk
    • Journal of the Korean Society of Safety
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    • v.26 no.5
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    • pp.54-58
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    • 2011
  • Emergency preparedness plan(EPP) is the systematic management of activities that involve a material degree of risk of loss or other damage to the surroundings(people, property and environment), and the boundary of accident recovery plan(ARP). The main purpose of the program is to provide a safety management system to each facility in order to enable to prevent accident and to control accident immediately. The EPP includes not only typical safety-related documentations such as material safety data sheet(MSDS), standard operation procedure(SOP), emergency response plan(ERP). EPP is established basis of the preliminary safety analysis involving risk identification, assessment and prevention plans. The program is also helpful for government or related agencies to control a number of accidents in small-scale companies in the whole country.

Safety Program in Chemical Industry (국내 화학업종의 안전실태)

  • 고흥화;전종한
    • Journal of the Korean Society of Safety
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    • v.5 no.1
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    • pp.67-76
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    • 1990
  • This research was to describe the organizational safety climate, to examine its implication, and to improve the strategies of industrial accident prevention in chemical industry in Korea. The subjects were 207 directors of department of safety in chemical industry, asked to respond questionnaire sent by mailing. The data in this research were analyzed by SPSS PC+. The results were as follows : 1) 24.2% of surveyed chemical industry had department of safety. 2) 53.6% of suueyed chemical industry had safety education program. 3) 53% of employees in surveyed chemical industry were satisfied with supply of personal protective equipments.

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Discussions on the Disaster Management for NaTech based on the Foreign Case Studies (국외 NaTech 사례연구를 통한 재난관리 방안 고찰)

  • Yoo, Byungtae;Baek, Jong-bae;Ko, Jae-wook
    • Journal of the Korean Society of Safety
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    • v.31 no.1
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    • pp.111-117
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    • 2016
  • Natural disasters can cause major accidents in chemical facilities where they can lead to the release of hazardous materials which in turn can result in fires, explosions or toxic dispersion. Technological disasters triggered by natural disasters are referred to as NaTech(Natural Disaster Triggered Technological Disaster). These trends increase the probability of catastrophic future disasters and the potential for mass human exposure to hazardous materials released during disasters. In the present study, we proposed some methods for effective disaster management by conducting case study of major NaTech. First, establishing information sharing system of chemical accident for stakeholders and improving disaster manuals and standards of central and local government and co-operation support system. Second, activating information service of emergency planning and community right to know. Third, improving the integrated chemical accident database including NaTech accidents.

Toxic Concentration(T-LOC) Endpoint Distance Study for Fire Brigade Protection in Response to Chemical Accidents (화학사고 초기대응 소방대 보호를 위한 독성농도(T-LOC) 끝점거리 연구)

  • Jong Chan Yun;Chul Hee Cho;Jeong Hun Won
    • Journal of the Korean Society of Safety
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    • v.38 no.6
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    • pp.60-71
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    • 2023
  • The purpose of this study is to propose a quantitative toxicity endpoint distance suitable for the initial response of firefighters by comparing and analyzing the commonly applied toxic level of concern (T-LOC), specifically emergency response planning guidelines (ERPG), acute exposure guideline levels (AEGL), and immediately dangerous to life or health (IDLH). This is to protect the fire brigade, which responds to toxic chemical accidents first during the golden time. Using areal locations of hazardous atmospheres, a damage prediction program, the amount of leakage for both acidic and basic substances, along with the endpoint distance, were analyzed for alternative accident and worst-case accident scenarios. The results showed that the toxicity endpoint distance, serving as a compromise between Level-3 and Level-2 of T-LOC, was longer than ERPG-3 and shorter than ERPG-2 with IDLH, while its values were analyzed in the order of ERPG-2, AEGL-2, IDLH, AEGL-3, and ERPG-3. It is suggested that the application of IDLH in an emergency (red card) and ERPG-2 endpoint distance in a non-emergency (non-red card) can be utilized for the initial response of the fire brigade.

Development on AR-Based Operator Training Simulator(OTS) for Chemical Process Capable of Multi-Collaboration (다중협업이 가능한 AR 기반 화학공정 운전원 교육 시뮬레이터(OTS-Simulator) 개발)

  • Lee, Jun-Seo;Ma, Byung-Chol;An, Su-Bin
    • Journal of Convergence for Information Technology
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    • v.12 no.1
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    • pp.22-30
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    • 2022
  • In order to prevent chemical accidents caused by human error, a chemical accident prevention and response training program using advanced technology was developed. After designing a virtual process based on the previously built pilot plant, chemical accident response contents were developed. A part of the pilot facility was remodeled for content realization and a remote control function was given. In addition, a DCS program that can control facilities in a virtual environment was developed, and chemical process operator training (OTS) that can finally respond to virtual chemical accidents was developed in conjunction with AR. Through this, trainees can build driving skills by directly operating the device, and by responding to virtual chemical accidents, they can develop emergency response capabilities. If the next-generation OTS like this study is widely distributed in the chemical industry, it is expected to greatly contribute to the prevention of chemical accidents caused by human error.

A Study on the Response Technique for Toxic Chemicals Release Accidents - Hydrogen Fluoride and Ammonia - (독성 화학물질 누출사고 대응 기술연구 - 불산 및 암모니아 누출을 중심으로 -)

  • Yoon, Young Sam;Cho, Mun Sik;Kim, Ki Joon;Park, Yeon Shin;Hwang, Dong Gun;Yoon, Jun heon;Choi, Kyung Hee
    • Korean Journal of Hazardous Materials
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    • v.2 no.1
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    • pp.31-37
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    • 2014
  • Since the unprecedented hydrogen fluoride leak accident in 2012, there has been growing demand for customized technical information for rapid response and chemical accident management agencies including the Ministry of Environment, the National Emergency Management Agency, and the National Police Agency need more information on chemicals and accident management. In this regard, this study aims to provide reliable technical data and guidelines to initial response agencies, similar to accident management technical reports of the US and Canada. In this study, we conducted a questionnaire survey and interviews on initial response agencies like fire stations, police stations, and local governments to identify new information items for appropriate initial response and improvements of current guidelines. We also collected and reviewed the Canada's TIPS, US EPA's hydrogen fluoride documents, domestic and foreign literature on applicability tests of control chemicals, and interview data, and then produced items to be listed in the technical guidelines. In addition, to establish database of on-site technical information, we carried out applicability tests for accident control data including ① emergency shut down devide, safety guard, shut down valve, ground connection, dyke, transfer pipe, scrubber, and sensor; ② literature and field survey on distribution type and transportation/storage characteristics (container identification, valve, ground connection, etc.); ③ classification and identification of storage/transportation facilities and emergency management methodslike leak prevention, chemicals control, and cutoff or bypass of rain drainage; ④ domestic/foreign analysis methods and environmental standards including portable detection methods, test standards, and exposure limits; and ⑤ comparison/evaluation of neutralization efficiency of control chemicals on toxic substances.

Consideration on Design and Management of Flexible Hose through the Case Study of Chlorine Leak (염소 누출 사고사례연구를 통한 Flexible hose 설계 및 관리 방안 고찰)

  • Park, Suyoul;Yim, Ji-pyo
    • Korean Chemical Engineering Research
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    • v.57 no.3
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    • pp.351-357
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    • 2019
  • This research was performed to propose domestic standard for design and management of flexible hose by analyzing chlorine leak caused by breakage of the hose in Ulsan, 2018. The leak had multiple causes but this paper focuses on analyzing the cause of breakage of flexible hose, the direct cause. According to the analysis, flexible hose that the company of the accident used for chlorine transfer was inappropriate in several aspects including material and wall thickness. And even pressure test had been conducted below operating pressure. Upon investigation on five companies that handle chlorine in Ulsan, four companies were using inappropriate flexible hose for chlorine transfer. Since there is no domestic standard for the design of flexible hose for chlorine transfer at present, it is hard to examine its design adequacy. Design standard of flexible hose used in chlorine transfer that is applicable domestically is proposed based on this research. It will contribute to the reduction in risk of breakage of the hose if the proposed standard could be applied in design and examination of flexible hose.