• 제어로봇시스템학회:학술대회논문집
• /
• 제어로봇시스템학회 1992년도 한국자동제어학술회의논문집(국내학술편); KOEX, Seoul; 19-21 Oct. 1992
• /
• pp.490-495
• /
• 1992

A neural model predictive control strategy combining a neural network for plant identification and a nonlinear programming algorithm for solving nonlinear control problems is proposed. A constrained nonlinear optimization approach using successive quadratic programming cooperates with neural identification network is used to generate the optimum control law for the complicate continuous/batch chemical reactor systems that have inherent nonlinear dynamics. Based on our approach, we developed a neural model predictive controller(NMPC) which shows excellent performances on nonlinear, model-plant mismatch cases of chemical reactor systems.

• 대한기계학회논문집B
• /
• 제34권4호
• /
• pp.365-373
• /
• 2010

제트 혼합 반응기(JSR) 내의 NOx와 같은 배출물질을 예측하기 위해서 화학반응기 모델을 개발했다. 본 연구에서는 JSR에 대한 화학반응기 모델로서 two-PSR 모델이 채택되었다. CHEMKIN 코드와 4가지 NO 생성 메커니즘을 포함한 GRI 3.0 메탄-공기 연소 메커니즘을 이용해서 JSR내의 희박 예혼합 메탄-공기 연소의 NO 생성예측을 실시하였다. 모델의 검증을 위해서 계산된 결과를 Rutar의 실험 데이터와 비교하였다. NO 생성의 중요 파라미터와 4 가지 NO 경로의 기여도를 조사하였다. 화염 영역에서는 prompt 메커니즘이 주된 경로이고, 화염후영역에서는 Zeldovich 메커니즘이 주된 경로이다. 희박 예혼합 조건에서는 N2O 메카니즘이가 화염 및 화염후 영역 모두에서 중요한 경로이다.

• Journal of Microbiology
• /
• 제43권3호
• /
• pp.301-307
• /
• 2005

The feasibility of laccase production by immobilization of Pleurotus ostreatus 1804 on polyurethane foam (PUF) cubes with respect to media composition was studied in both batch and reactor systems. Enhanced laccase yield was evidenced due to immobilization. A relatively high maximum laccase activity of 312.6 U was observed with immobilized mycelia in shake flasks compared to the maximum laccase activity of free mycelia (272.2 U). It is evident from this study that the culture conditions studied, i.e. biomass level, pH, substrate concentration, yeast extract concentration, $Cu^{2+}$ concentration, and alcohol nature, showed significant influence on the laccase yield. Gel electrophoretic analysis showed the molecular weight of the laccase produced by immobilized P. ostreatus to be 66 kDa. The laccase yield was significantly higher and more rapid in the packed bed reactor than in the shake flask experiments. A maximum laccase yield of 392.9 U was observed within 144 h of the fermentation period with complete glucose depletion.

• Korean Chemical Engineering Research
• /
• 제57권2호
• /
• pp.259-266
• /
• 2019

Tuning of electro-optical properties of nano-structured $SnO_2:Ga$ powders in a micro drop fluidized reactor (MDFR) was highly effective to enhance the activities of powders to be used as sensor materials. The tuning was conducted continuously in a facile one-step process during the formation of powders. The microscopic hydrodynamic forces affected the band gap structure and charge transfer of $SnO_2:Ga$ powders through the oxygen and interfacial tin vacancies by providing plausible pyro-hydraulic conditions, which resulted in the decrease in the electrical resistance of the materials. The analyses of room-temperature photoluminescence (PL) spectra and FT-IR exhibited that the tuning could improve the surface activities of $SnO_2:Ga$ powders by adjusting the excitation as well as separation of electrons and holes, thus maximizing the oxygen vacancies at the surface of the powders. The scheme of photocatalytic mechanism of $SnO_2:Ga$ powders was also discussed.

• 공업화학
• /
• 제9권6호
• /
• pp.901-906
• /
• 1998

기체분산기로 단일노즐을 사용한 내부순환 공기리프트 반응기에서 기체 및 액체의 유동특성을 해석하였다. 실험은 공기-물계에서 하강관의 직경과 상승관의 높이가 다른 세 가지 반응기를 사용하여 기체속도와 반응기의 높이를 변화시키면서 각 유동지역의 기체체류량과 추적자의 충격-응답곡선을 측정하였다. 실험결과, 기포의 유동양상은 상승관에서 강한 기포합체를 일으키는 슬러그흐름을, 그리고 하강관에서는 직경의 크기에 따라 전이흐름 또는 균일상 기포흐름을 나타내었다. 그리고 동일한 반응기 상부지역의 높이비에서 각 유동지역과 반응기 전체의 평균 기체체류량은 하강관의 직경이 작을수록 상당히 증가하였다. 또한 혼합시간은 기체속도보다 반응기 상부지역의 높이에 크게 영향을 받으며 동일한 반응기 상부지역의 높이비에서는 하강관의 직경과 상승관의 길이가 클수록 상당히 큰 값을 나타내었다. 액체의 유동특성은 하강관에서 기포의 유동양상과 반응기 상부지역의 크기에 따라 크게 변화하였으며 상승관에서 액체의 순환속도는 기체속도와 반응기 상부지역의 크기가 증가할수록 증가하였고 동일한 반응기 상부지역의 높이비에서는 하강관의 직경과 상승관의 길이가 증가할수록 증가하였다.

• Environmental Engineering Research
• /
• 제23권2호
• /
• pp.195-204
• /
• 2018

A pilot scale study was conducted on a down-flow hanging sponge (DHS) reactor installed at a sewage treatment plant in Banda Aceh, Indonesia for treatment of desludging septic tank wastewater. Raw wastewater with an average biochemical oxygen demand (BOD) and total suspended solids of 139 mg/L and 191 mg/L, respectively, was pumped into the reactor. Two different hydraulic retention times (HRTs, 3 h and 4 h) were investigated, equivalent to organic loadings of 1.11 and $0.78kg\;BOD/m^3/d$, respectively. The average BOD concentration in the final effluent was 46 and 26 mg/L at HRTs of 3 and 4 h, respectively. The concentration of retained sludge along the reactor height was 10.2-18.7 g VSS/L-sponge, and the sludge activities were 0.24-0.32 and 0.04-0.40 mg/g VSS/h for heterotrophs and nitrification, respectively. Values of water hold-up volume, dispersion coefficient, and number of tank in-series found from tracer studies of clean sponge and biomass-loaded sponge confirmed that growth of retained sludge on the sponge module improved hydraulic performance of the reactor. Adoption of the DHS reactor by this Indonesian sewage treatment plant would enhance the role of the current desludging septic tank wastewater treatment system.

• 한국가스학회지
• /
• 제20권6호
• /
• pp.95-101
• /
• 2016

본 연구에서는 다양한 수소 생산 방법 중 하나인 천연가스 수증기 개질반응(natural gas steam reforming reaction)에 대해 일반적인 충전층반응기와 반응기와 수소분리기가 결합된 새로운 형태의 분리막 반응기에서의 성능에 대한 비교분석을 수행하였다. Xu 와 Froment에 의해 기존에 발표된 실험결과를 바탕으로 상업용 화학공정모사기인 Aspen $HYSYS^{(R)}$ 모델이 개발되었으며, 반응온도, $H_2$ 투과량, Ar 유량 등이 분리막 반응기에서의 반응물의 전환율 및 $H_2$ 수율 향상도에 미치는 영향에 대해 분석한 결과 분리막 반응기에서 보다 많은 양의 수소수율 및 메탄전환율이 확인되었다. 더 나아가, 전체 시스템에서 필요로 하는 열량을 공급하기 위해 요구되는 천연가스의 양에 초점을 맞춰 분리막 반응기에서의 원가절감 가능성을 평가한 결과, 분리막 반응기에서 10.94%의 원가절감이 관찰되었다.

• 제어로봇시스템학회:학술대회논문집
• /
• 제어로봇시스템학회 1996년도 Proceedings of the Korea Automatic Control Conference, 11th (KACC); Pohang, Korea; 24-26 Oct. 1996
• /
• pp.263-266
• /
• 1996

A method to determine an optimal temperature trajectory that guarantees polymer products having controlled molecular weight distribution and desired values of molecular weight is presented. The coordinate transformation method and the optimal control theory are applied to a batch PMMA polymerization system to calculate the optimal temperature trajectory. Coordinate transformation method converts the original fixed-end-point, free-end-time problem to a free-end-point, fixed-end-time problem. The idea is that by making the reactor temperature track the optimal temperature trajectory one may be able to produce polymer products having the prespecified physical property in a minimum time. The on-line control experiments with the PID control algorithm have been conducted to establish the validity of the scheme proposed in this study. The experimental results show that prespecified polymer product could be obtained with tracking the calculated optimal temperature trajectory.

• 제어로봇시스템학회:학술대회논문집
• /
• 제어로봇시스템학회 2001년도 ICCAS
• /
• pp.26.2-26
• /
• 2001

It is known that Volterra kernel model can represent a wide variety of nonlinear chemical processes. But almost all Volterra kernel models which appeared in the literature are up to second order, because it was difficult to measure higher order Volterra kernels. Kashiwagi has recently shown a method for measuring Volterra kernels up to third order using pseudorandom M-sequence signals. In this paper, the authors verified the applicability of this method for chemical processes using polymerization reactor simulation. Also, the authors have recently proposed a practical Identification method for chemical processes, which is based on the combination of off-line nonlinear identification and on-line linear identification. This method is also applied to the identification of polymerization reactor, and we obtained ...

• 대한기계학회논문집B
• /
• 제26권3호
• /
• pp.410-416
• /
• 2002

The fluid flow, heat transfer and the local mass fraction of chemical species in the chemical vapor deposition(CVD) manufacturing process are studied numerically. Flow with a dilute precursor concentration of silane in hydrogen as the carrier gas enters to the reactor and deposits silicon onto the heated surface. The silicon deposition rate using silane is calculated in the horizontal or vertical, axisymmetric reactor. The effects of inlet carrier gas velocity, mass fraction of silane, susceptor angle and rotation of surface on the deposition rate are described.