• Title/Summary/Keyword: Chemical Propulsion

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An Experimental Study on Measurement of the Reaction Order of a Liquid Fuel with Various Components (혼합 액체연료의 화학반응차수 계측에 관한 실험적 연구)

  • Choi, Hyo-Hyun;Lim, Jun-Seok;Kim, Chul-Jin;Sohn, Chae-Hoon
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 2011.04a
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    • pp.421-424
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    • 2011
  • Thermal Analyses are conducted to measure various factors of a liquid fuel required for numerical analysis. Thermal Analyses are divided into two different methods of TGA (Thermo Gravimetric Analysis) and DSC (Differential Scanning Calorimetry). Non-isothermal experimental results are analyzed using by TGA. The results are filtered by a Freeman Carroll method. At the same time, chemical parameters of unknown liquid fuel, activation temperature and reaction order are measured to 6128.2 K and 1.4, respectively. Furthermore, the parameters can be obtained by various mathematical methods. It is found that tha parameters depend on the processing method.

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Numerical Study of High Resolution Schemes for GH2/GO2 Rocket Combustor using Single Shear Coaxial Injector (단일 전단 동축 분사기를 가지는 GH2/GO2 로켓 연소기의 고해상도 수치해석)

  • Jeong, Seung-Min;Um, Jae-Ryeong;Choi, Jeong-Yeol
    • Journal of the Korean Society of Propulsion Engineers
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    • v.22 no.6
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    • pp.72-83
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    • 2018
  • In this study, a series of CFD analyses were carried out for a hydrogen rocket combustor with a single shear coaxial injector. A hybrid RANS/LES approach was used for the turbulent combustion analysis with a two-dimensional axisymmetric configuration. Three reaction mechanisms, three spatial discretization methods, and three levels of grid resolution were compared to determine an appropriate CFD approach. The performance of the CFD prediction were investigated by comparing the wall heat flux with experimental data. Investigation of the flow field results provides an insight into the characteristics of the turbulent reacting flow of a rocket combustor with a shear coaxial injector.

Review on Kerosene Fuel and Coking (케로신 연료 및 코킹에 대한 검토)

  • Lee, Junseo;Ahn, Kyubok
    • Journal of the Korean Society of Propulsion Engineers
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    • v.24 no.3
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    • pp.81-124
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    • 2020
  • In liquid oxygen/kerosene liquid rocket engines, kerosene is not only a propellant but also plays a role as a coolant to protect the combustion chamber wall from 3,000 K or more combustion gas. Since kerosene is exposed to high temperature passing through cooling channels, it may undergo heat-related chemical reactions leading to precipitation of carbon-rich solids. Such kerosene's thermal and fluidic characteristic test data are essential for the regeneratively cooled combustion chamber design. In this paper, we investigated foreign studies related to regenerative cooling channel and kerosene. Starting with general information on hydrocarbon fuels including kerosene, we attempted to systematically organize sedimentary phenomena on cooling channel walls, their causes/research results, coking test equipments/prevention methods, etc.

Development of Lyocell-Based Graphite Fabric for Aerospace (항공우주용 리오셀계 흑연화 직물 개발)

  • Park, Gil-Young;Kim, Nam-Kyu;Kim, Yun-Chul;Seo, Sang-Kyu;Chung, Yong-Sik
    • Journal of the Korean Society of Propulsion Engineers
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    • v.25 no.4
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    • pp.36-42
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    • 2021
  • In this study, the impregnation of Lyocell fabrics was performed using phosphoric acid, ammonium phosphate, diammonium hydrogen, triammonium phosphate as phosphorus flame retardant, to fabricate continuous graphite fabrics using lyocell fiber. The physical and chemical structure changes were investigated by thermogravimetric, Fourier-transform infrared spectroscopy, C-nuclear magnetic resonance, X-ray diffraction, and weight analyses, By analyzing the thermal behavior of phosphorus flame retardant, conditions for the temperature, gas, and residual time of the pyrolysis process were set. Graphite fabrics with a tensile strength of 1,007.19±11.47 N/5 cm and yield of 25.3% were fabricated using continuous pyrolysis, carbonization and graphitization process.

Prediction Method for Thermal Destruction of Internal Insulator in Solid Rocket Motor (고체추진기관 연소관단열재의 열파괴 예측기법)

  • Ji-Yeul Bae;In Sik Hwang;Yoongoo Kang
    • Journal of the Korean Society of Propulsion Engineers
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    • v.27 no.1
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    • pp.9-16
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    • 2023
  • This paper investigated the method to predict a thermal response of internal insulation in a solid rocket motor considering both thermal decomposition and ablation. Changes in properties due to the thermal decomposition, swelling of char layer and movement of decomposition gases inside the material were considered during a modeling. And radiative/convective heat flux from the exhaust gas were applied as boundary conditions, while the chemical ablation of the material surface is modeled with algebraic equations. Test SRM with thermocouples was solved for a validation purpose. The results showed that predicted temperatures have identical trends and values compared to the experimental values. And an error of predicted thermal destruction depth was around 0.1 mm.

Fuel cell system for SUAV using chemical hydride - II. Lightweight fuel cell propulsion system (화학수소화합물을 이용한 소형 무인항공기용 연료전지 시스템 연구 - II. 경량 연료전지 추진 시스템)

  • Hong, Ji-Seok;Park, Jin-Gu;Sung, Myeong-Hun;Jeon, Chang-Soo;Sung, Hong-Gye;Shin, Seock-Jae;Nam, Suk-Woo
    • Journal of the Korean Society for Aeronautical & Space Sciences
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    • v.41 no.3
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    • pp.233-239
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    • 2013
  • A 100 W fuel cell system using chemical storage method has been applied for a propulsion system of the SUAV(Small Unmanned Aerial Vehicle). A fuel cell and battery have been combined for both the small/light hydrogen generation control system and the hybrid power supply system. A small hydrogen generation device was implemented to utilize NaBH4 aqueous solution and dead-end type PEMFC system, which were evaluated on the ground and by the flight tests. The system pressurized at a 45kpa stably operates and get higher fuel efficiency. The pressure inside of the hydrogen generation control system was maintained at between 45 kPa and 55 kPa. The 100W fuel cell system satisfies the required weight and power consumption rate as well as the propulsion system, and the fuel cell system performance was demonstrated through flight test.

Characterization of aluminized RDX for chemical propulsion

  • Yoh, Jai-ick;Kim, Yoocheon;Kim, Bohoon;Kim, Minsung;Lee, Kyung-Cheol;Park, Jungsu;Yang, Seungho;Park, Honglae
    • International Journal of Aeronautical and Space Sciences
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    • v.16 no.3
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    • pp.418-424
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    • 2015
  • The chemical response of energetic materials is analyzed in terms of 1) the thermal decomposition under the thermal stimulus and 2) the reactive flow upon the mechanical impact, both of which give rise to an exothermic thermal runaway or an explosion. The present study aims at building a set of chemical kinetics that can precisely model both thermal and impact initiation of a heavily aluminized cyclotrimethylene-trinitramine (RDX) which contains 35% of aluminum. For a thermal decomposition model, the differential scanning calorimetry (DSC) measurement is used together with the Friedman isoconversional method for defining the frequency factor and activation energy in the form of Arrhenius rate law that are extracted from the evolution of product mass fraction. As for modelling the impact response, a series of unconfined rate stick data are used to construct the size effect curve which represents the relationship between detonation velocity and inverse radius of the sample. For validation of the modeled results, a cook-off test and a pressure chamber test are used to compare the predicted chemical response of the aluminized RDX that is either thermally or mechanically loaded.

Papers : Analysis of Supersonic Rocket Plume Flowfield with Finite - Rate Chemical Reactions (논문 : 유한속도 화학반응을 고려한 초음속 로켓의 플룸 유동장 해석)

  • Choe,Hwan-Seok;Mun,Yun-Wan;Choe,Jeong-Yeol
    • Journal of the Korean Society for Aeronautical & Space Sciences
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    • v.30 no.1
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    • pp.114-123
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    • 2002
  • A supersonic rocket plum flowfield of kerosene/liquid-oxygen based propulsion system has been analysed using the Reynolds-averaged Navier-Stokes equations coupled with a 9-species 14-reaction finite-chemistry model. The result were compared with chemically frozen flow solution to investigate the effect of finite-rate chemistry on the plume flowfield. The computations were performed using a commercial CFD software, FLUENT 5. The finite-rate chemistry solution exhibited higher temperature caused by the reactions within the nozzle. All the chemical reactions within the plum were dominated only in the shear layer and behind the barrel shock reflection region where the temperatures are high and the effect of finite-rate chemical reactions on the flowfield was found to be insignificant. However, the present plume computation including the finite-rate chemical reaction within the plume has revealed major reactions occurring in the plum and their reaction mechanisms.

Thermal Conductivity and Thermal Expansion Behavior of Pseudo-Unidirectional and 2-Directional Quasi-Carbon Fiber/Phenolic Composites

  • Cho, Donghwan;Choi, Yusong;Park, Jong Kyoo;Lee, Jinyong;Yoon, Byung Il;Lim, Yun Soo
    • Fibers and Polymers
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    • v.5 no.1
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    • pp.31-38
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    • 2004
  • In the present paper, a variety of fiber reinforcements, for instance, stabilized OXI-PAN fibers, quasi-carbon fibers, commercial carbon fibers, and their woven fabric forms, have been utilized to fabricate pseudo-unidirectional (pseudo-UD) and 2-directional (2D) phenolic matrix composites using a compression molding method. Prior to fabricating quasi-carbon fiber/phenolic (QC/P) composites, stabilized OXI-PAN fibers and fabrics were heat-treated under low temperature carbonization processes to prepare quasi-carbon fibers and fabrics. The thermal conductivity and thermal expansion/contraction behavior of QC/P composites have been investigated and compared with those of carbon fiber/phenolic (C/P) and stabilized fiber/phenolic composites. Also, the chemical compositions of the fibers used have been characterized. The results suggest that use of proper quasi-carbonization process may control effectively not only the chemical compositions of resulting quasi-carbon fibers but also the thermal conductivity and thermal expansion behavior of quasi-carbon fibers/phenolic composites in the intermediate range between stabilized PAN fiber- and carbon fiber-reinforced phenolic composites.

Design and Operation Characteristics of 2.4MJ Pulse Power System for Electrothermal-Chemical (ETC) Propulsion (II) (전열화학추진용 2.4MJ 펄스파워전원의 설계와 동작특성(II))

  • Jin, Y.S.;Lee, H.S.;Kim, J.S.;Whang, D.W.;Kim, J.S.;Chu, J.H.;Jung, J.W.;Moon, H.J.
    • Proceedings of the KIEE Conference
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    • 2001.07c
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    • pp.1603-1605
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    • 2001
  • Eight 300kJ modularized capacitor-banks have been constructed. These modules have been installed and assembled to make a 2.4MJ pulse power system (PPS). This 2.4MJ PPS was developed to be used as a driver of an electrothermal-chemical (ETC) gun. Each capacitor bank has six 22kV, 50kJ capacitors connected in parallel. A triggered vacuum switch (TVS-43) was adopted as a main pulse power-closing switch in each module. The module also contains a crowbar circuit made of three high-voltage diode-stacks, a multi-tap inductor and an energy-dumping resistor. Various current shapes have been formed by a sequential firing of multiple capacitor banks. Resistive dummy load has been used and various combinations of experimental parameters, such as charging voltage, trigger time and inductance, were tested to make flexible current shapes.

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