• 제어로봇시스템학회:학술대회논문집
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• 1999.10a
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• pp.145-148
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• 1999

It is known that Volterra kernel models can represent a wide variety of nonlinear chemical processes. Also, it is necessary for Volterra model identification to excite the process to be identified with a signal having wide range of frequency spectrum and high enough amplitude of input signals. Kashiwagi[4 ∼ 7] has recently shown a method for measuring Volterra kernels up to third order using pseudorandom M-sequence signals. However, in practice, since it is not always possible to apply such input sequences to the actual chemical plants. Even when we can apply such a pseudorandom signal to the process, it takes much time to obtain higher order Volterra kernels. Considering these problems, the authors propose here a new method for practical identification of Volterra kernels by use of approximate open differential equation (ODE) model and simple plant test. Simulation results are shown for verifying the usefulness of our method of identification of nonlinear chemical processes.

• Bulletin of the Korean Chemical Society
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• v.10 no.3
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• pp.282-288
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• 1989

Theoretical analysis of DF-$CO_2$ transfer chemical laser is performed through simple kinetic model consisting of 30 chemical reactions. In this model, we calculate the power theoretically by solving the rate equations, which are related to the $D_2\;+\;F_2$ chain reaction and the DF-$CO_2$ resonance energy transfer, combined with both the gain processes and the stimulated emission processes. The calculated powers are verified with previously reported results in good agreements. The output energy rises linearly with the increase in pressure, and the duration time of output pulse show the inverse dependence on pressure. Through the detailed calculation of temperature and concentrations of reactants as a function of time, it is found that the deactivation processes of DF(v) can be neglected in low pressure, but they have to be considered in high pressure. From the parametric study for the variation on [$D_2]/[F_2$] and [$CO_2]/[D_2\;+\;F_2$] at several constant total pressure, the optimum lasing conditions are found to be in a range of 1/3 to 1 and 2 to 4, respectively.

• Korean Chemical Engineering Research
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• v.46 no.2
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• pp.383-388
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• 2008

The safe and efficient operation of the chemical processes has become one of the primary concerns of chemical companies, and a variety of fault diagnosis methods have been developed to diagnose faults when abnormal situations arise. Recently, many research efforts have focused on fault diagnosis methods based on quantitative history data-based methods such as statistical models. However, when the history data-based models trained with the data obtained on an operation mode are applied to another operating condition, the models can make continuous wrong diagnosis, and have limits to be applied to real chemical processes with various operation modes. In order to classify operation modes of chemical processes, this study considers three multivariate models of Euclidean distance, FDA (Fisher's Discriminant Analysis), and PCA (principal component analysis), and integrates them with process dynamics to lead dynamic Euclidean distance, dynamic FDA, and dynamic PCA. A case study of the TE (Tennessee Eastman) process having six operation modes illustrates the conclusion that dynamic PCA model shows the best classification performance.

• Korean Chemical Engineering Research
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• v.53 no.1
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• pp.22-30
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• 2015

So far, most of research activities on modeling of membrane separation processes have been focused on binary feed mixture. But, in actual separation operations, binary feed is hard to find and most separation processes involve multicomponent feed mixture. In this work models for membrane separation processes treating multicomponent feed mixture are developed. Various model types are investigated and validity of proposed models are analysed based on experimental data obtained using hollowfiber membranes. The proposed separation models show quick convergence and exhibit good tracking performance.

• Proceedings of the Korean Environmental Sciences Society Conference
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• 1998.10a
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• pp.1-1
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• 1998

Advanced (Chemical) oxidation processes (AOP) differ from most conventional ones in that hydroxyl radical(OH.) is considered to be the primary oxidant. Hydroxyl radicalcan react non-selectively with a great number of organic and inorganic chemicals. The typical rate constants of true hydroxyl radical reactions are in the range of between 109 to 1012 sec-1. Many processes are possible to generate hydroxyl radical. These include physical and chemical methods and their combinations. Physical means involves the use of high energy radiation such as gamma ray, electron beam, and acoustic wave. Under an applied high energy radiation, water molecules can be decomposed to yield hydroxyl radicals or aqueous electrons. Chemical means include the use of conventional oxidants such as hydrogen peroxide and ozone, two of the most efficient oxidants in the presence of promoter or catalyst. Hydrogen peroxide in the presence of a catalyst such as divalent iron ions can readily produce hydroxyl radicals. Ozone in the presence of specific chemical species such as OH- or hydrogen peroxide, can also generate hydroxyl radicals. Finally the combination of chemical and physical means can also yield hydroxyl radicals. Hydrogen peroxide in the presence of acoustic wave or ultra violet beam can generate hydroxyl radicals. The principles for hydroxyl radical generation will be discussed. Recent case studied of AOP for water treatment and other environmental of applications will be presented. These include the treatment of contaminated soils using electro-Fenton, lechate treatment with conventional Ponton, treatment of coal for sulfur removal using sonochemical and the treatment of groundwater with enhanced sonochemical processes.

• Macromolecular Research
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• v.13 no.2
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• pp.162-166
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• 2005

• Proceedings of the Membrane Society of Korea Conference
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• 2002.11a
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• pp.69-72
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• 2002

No Abstract, See Full Text

• Proceedings of the Membrane Society of Korea Conference
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• 2003.11a
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• pp.64-67
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• 2003

• Journal of the Korean Chemical Society
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• v.57 no.1
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• pp.25-34
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• 2013

The efficiency of three complex surfactants based on sunflower oil and nitrogen containing compounds as corrosion inhibitors for mild steel in $CO_2$-saturated 1% NaCl solution, has been determined by weight loss and LPR corrosion rate measurements. These compounds inhibit corrosion even at very low concentrations. The inhibition process was attributed to the formation of an adsorbed film on the metal surface that protects the metal against corrosive media. The inhibition efficiency increases with increasing the concentration of the studied inhibitors. Maximum inhibition efficiency of the surfactants is observed at concentrations around its critical micellar concentration (CMC). Adsorption of complex surfactants on the mild steel surface is in agreement with the Langmuir adsorption isotherm model, and the calculated Gibbs free energy values confirm the chemical nature of the adsorption. Energy dispersive X-ray fluorescence microscopy (EDRF) observations of the electrode surface confirmed the existence of such an adsorbed film.

• Journal of Environmental Science International
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• v.24 no.9
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• pp.1181-1188
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• 2015

In this study, we discussed about the application of the single physical and chemical treatment processes and the physical-chemical complex treatment processes on the inactivation of Artemia sp. in order to satisfy the USCG Phase II (United States Coast Guard). The results showed that initial disinfection rate of ultrasonic process in single batch process is higher than that of electrolysis. However, the inactivation rate showed slower than electrolysis. The inactivation rate of Artemia sp. on the single continuous treatment process ranked in the following order: homogenizer > electrolysis > ultrasonic process. Inactivation rate of Artemia sp. in continuous homogenizer-electrolysis complex process was reached at 100% immediately. A synergistic effect of ultrasonic-electrolytic complex process was found to be a small. The order of processes in a complex process did not affect the disinfection performance.