• Title/Summary/Keyword: Chemical Processes

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Distribution and Inter-annual Variation of Nutrients (N, P, Si) and Organic Carbon (DOC, POC) in the Equatorial Thermocline Ridge, Northeast Pacific (북동태평양 적도 Thermocline Ridge 해역에서 영양염(질소, 인, 규소)과 유기탄소(용존 및 입자)의 분포 특성 및 연간 변화)

  • Son, Ju-Won;Kim, Kyeong-Hong;Kim, Mi-Jin;Son, Seung-Kyu;Chi, Sang-Bum
    • Ocean and Polar Research
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    • v.33 no.1
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    • pp.55-68
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    • 2011
  • The distribution and inter-annual variation of nutrients (N, P, Si) and dissolved/particulate organic carbon were investigated in the equatorial thermocline ridge ($7^{\circ}{\sim}11.5^{\circ}N$, $131.5^{\circ}W$) of the northeast Pacific. From the Oceanic Nino Index and Multivariate ENSO Index provided by NOAA, normal condition was observed in July 2003 and August 2005 on the aspect of global climate/ocean change. However, La Ni$\~{n}$a and El Ni$\~{n}$o episodes occurred in July 2007 and August 2009, respectively. Thermocline ridge in the study area was located at $9^{\circ}N$ in July 2003, $8^{\circ}N$ in August 2005, $10^{\circ}N$ in July 2007, and $10.5^{\circ}N$ in August 2009 under the influence of global climate/ocean change and surface current system (North Equatorial Counter Current and North Equatorial Current) of the northeast Pacific. Maximum depth integrated values (DIV) of nutrients in the upper layer (0~100 m depth range) were shown in July 2007 (mean 21.12 gN/$m^2$, 4.27 gP/$m^2$, 33.72 gSi/$m^2$) and higher variability of DIV in the equatorial thermocline ridge was observed at $10^{\circ}N$ during the study periods. Also, maximum concentration of dissolved organic carbon (DOC) in the upper 50 m depth layer was observed in July 2007 (mean $107.48{\pm}14.58\;{\mu}M$), and particulate organic carbon (POC, mean $9.42{\pm}3.02\;{\mu}M$) was similar to that of DOC. Nutrient concentration in the surface layer increased with effect of upwelling phenomenon in the equatorial thermocline ridge and La Ni$\~{n}$a episode, which had formed in the central Pacific. This process also resulted in the increasing of organic carbon concentration (DOC and POC) in the surface layer. From these results, it is suggested that spatial and temporal variation of chemical and biological factors were generated by physical processes in the equatorial thermocline ridge.

Extraction of Dimethyl-$\beta$-propiothetin from Enteromorpha intestinalis (창자파래(Enteromorpha intestinalis)로부터 Dimethyl-$\beta$-propiothetin 추출)

  • 배태진;강동수;최옥수
    • The Korean Journal of Food And Nutrition
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    • v.13 no.4
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    • pp.334-341
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    • 2000
  • The DMPT produced by marine algae is the main biogenic precursor of oceanic DMS. Also, DMPT is an efficient stimulant for growth, feeding, and body movement of fish and striped prawn, and appears to play a physiologic role as an osmoprotectant in algae. This study was focused on the extraction of dimethyl-$\beta$-propiothetin as bioactive substance from green seaweed. Identification and quantification of dimethyl-$\beta$-propiothetin were measured by headspace gas chromatography after conversion to dimethyl sulfide by treatment with saturated NaOH solution. Dimethyl-$\beta$-propiothetin was extracted through various processes(solvent extraction, ultrasonication, boiling and autoclaving) from Enteromorpha intesinalis. The content of dimethyl-$\beta$-propiothetin extracted by autoclaving treatment showed higher than those of various extraction methods. Dimethyl-$\beta$-propiothetin content in extract of Enteromorpha Enteromorpha was 311,200ng/g after autoclaving at 121$^{\circ}C$ for 60min. Dimethyl-$\beta$-propiothetin in extract of Enteromorpha intestinalis was comparatively stable under low temperature. The retentions of dimethyl-$\beta$-propiothetin content in extract of Enteromorpha intestinalis were 75.8 ~99.8% by incubation at 10~6$0^{\circ}C$ for 2 hours. Chemical decomposition of dimethyl-$\beta$-propiothetin was observed under laboratory conditions at pH values higher than 9.5.

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Study on Formation of FePd Nano-dot Using Agglomeration of Fe/Au Bilayer (Fe/Au 이중층의 응집현상을 이용한 FePd 나노 점 형성에 관한 연구)

  • Koo, J.K.;Kim, J.M.;Ryua, D.H.;Choi, B.J.;Kim, D.W.;Lee, D.H.;Kim, U.I.;Mitani, S.;J.G., M. Kamiko;Ha, J.G.
    • Journal of the Korean Vacuum Society
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    • v.20 no.1
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    • pp.7-13
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    • 2011
  • [ $L1_0$ ]phase FePd nano-dot structures were successfully fabricated on self-organized Fe/Au bilayers. With atomic force microscopy, it is determined that surface morphologies of initially flat Fe/Au bilayer films were agglomerated and transformed their shape into nano-dots structures with increasing annealing temperature. With this bilayer as a template, FePd multilayers were deposited at various temperatures, i.e. $300^{\circ}C$, $350^{\circ}C$, $400^{\circ}C$, and $450^{\circ}C$. Surface morphologies of FePd superlattice had a near resemblance to self-organized bilayer. According to X-ray diffraction results, it is confirmed that $L1_0$ superlattice structures of FePd were obtained from samples which were annealed above $350^{\circ}C$. Results of X-ray photoelectron spectroscopy depth-profile analysis showed that chemical composition is identical to deposition sequence. As a result, without additional etching processes, fabrication of chemically ordered FePd superlattice nano-dots was achieved.

Mechanism of Biological Nitrogen Fixation in Azotobacter vinelandii (Azotobacter vinelandii에서의 생물학적 질소고정 작용 메카니즘)

  • Kim, Yong-Ung;Han, Jae-Hong
    • Applied Biological Chemistry
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    • v.48 no.3
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    • pp.189-200
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    • 2005
  • Biological nitrogen fixation is an important process for academic and industrial aspects. This review will briefly compare industrial and biological nitrogen fixation and cover the characteristics of biological nitrogen fixation studied in Azotobacter vinelandii. Various organisms can carry out biological nitrogen fixation and recently the researches on the reaction mechanism were concentrated on the free-living microorganism, A. vinelandii. Nitrogen fixation, which transforms atmospheric $N_2$ into ammonia, is chemically a reduction reaction requiring electron donation. Nitrogenase, the biological nitrgen fixer, accepts electrons from biological electron donors, and transfers them to the active site, FeMo-cofactor, through $Fe_4S_4$ cluster in Fe protein and P-cluster in MoFe protein. The electron transport and the proton transport are very important processes in the nitrogenase catalysis to understand its reaction mechanism, and the interactions between FeMo-cofactor and nitrogen molecule are at the center of biological nitrogen fixation mechanism. Spectroscopic studies including protein X-ray crystallography, EPR and $M{\ddot{o}}ssbauer$, biochemical approaches including substrate and inhibitor interactions as well as site-directed mutation study, and chemical approach to synthesize the FeMo-cofactor model compounds were used for biological nitrogen fixation study. Recent research results from these area were presented, and finally, a new nitrogenase reaction mechanism will be proposed based on the various research results.

Effects of Gamma Irradiation on Queso Blanco Cheese (퀘소블랑코 치즈의 감마선 조사 처리 효과)

  • Jeong, Seok-Geun;Noh, Young-Bae;Shin, Ji-Hye;Han, Gi-Sung;Chae, Hyun-Seok;Yoo, Young-Mo;Ahn, Jong-Nam;Lee, Ju-Woon;Jo, Cheor-Un;Lee, Wan-Kyu;Ham, Jun-Sang
    • Journal of Dairy Science and Biotechnology
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    • v.25 no.1
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    • pp.15-20
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    • 2007
  • Effects of gamma irradiation on chemical, microbiological, and immunological changes of Queso Blanco cheese were investigated. Although Queso Blanco cheese was made by heat pasteurization at 85$^{\circ}$C and addition of acid without lactic starter culture, total bacterial counts and lactic acid bacterial counts of control cheese were 7.65${\pm}$0.04 and 7.64${\pm}$0.02 log CFU/mL, respectively. It was thought that this microbial growth was due to the incomplete inactivation of raw milk by the heat treatment, resulting into growth during the pressing and the drying process. It demonstrated the possibility that if heat- and acid-resistant hazard microbes are present in raw milk, they can grow during the processes. Lactic acid bacterial counts of the irradiated cheese were 5.45${\pm}$0.02 log CFU/mL at 1kGy, 2.12${\pm}$0.12 log CFU/mL at 2kGy, and not detected at 3kGy or higher doses. The reduction of antigenicity by gamma irradiation was not found. It might be caused by the fact that most whey proteins of milk, a major antigen in milk, were already denaturated by heat process and removed during the draining.

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Identifying Risk Management Locations for Synthetic Natural Gas Plant Using Pipe Stress Analysis and Finite Element Analysis (배관응력해석 및 유한요소해석에 의한 SNG플랜트의 리스크 관리 위치 선정)

  • Erten, Deniz Taygun;Yu, Jong Min;Yoon, Kee Bong;Kim, Ji Yoon
    • Journal of Energy Engineering
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    • v.26 no.2
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    • pp.1-11
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    • 2017
  • While they are becoming more viable, synthetic natural gas (SNG) plants, with their high temperatures and pressures, are still heavily dependent on advancements in the state-of-the-art technologies. However, most of the current work in the literature is focused on optimizing chemical processes and process variables, with little work being done on relevant mechanical damage and maintenance engineering. In this study, a combination of pipe system stress analysis and detailed local stress analysis was implemented to prioritize the inspection locations for main pipes of SNG plant in accordance to ASME B31.3. A pipe system stress analysis was conducted for pre-selecting critical locations by considering design condition and actual operating conditions such as heat-up and cool-down. Identified critical locations were further analyzed using a finite element method to locate specific high-stress points. Resultant stress values met ASME B31.3 code standards for the gasification reactor and lower transition piece (bend Y in Fig.1); however, it is recommended that the vertical displacement of bend Y be restricted more. The results presented here provide valuable information for future risk based maintenance inspection and further safe operation considerations.

Investigation and Evaluation of Algae Removal Technologies Applied in Domestic Rivers and Lakes (국내 하천/호수에 적용된 조류저감기술의 조사 및 평가)

  • Byeon, Kyu Deok;Kim, Ga Young;Lee, Inju;Lee, Saeromi;Park, Jaeroh;Hwang, Taemun;Joo, Jin Chul
    • Journal of Korean Society of Environmental Engineers
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    • v.38 no.7
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    • pp.387-394
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    • 2016
  • Commercial 28 algae removal technologies that have been applied in domestic rivers and lakes with green tide were investigated, analyzed and classified. The classification of algae removal technologies was based on the three criteria (i.e., principle, flow rate of water body, and application period). Also, algae removal technologies were evaluated in terms of cost effectiveness, field applicability, effect durability, and eco friendliness. From the analysis results, technologies using physical, chemical, biological, and convergent controls were 32.2%, 25%, 21.4%, and 21.4%, respectively. The 75% of technologies have been applied to stagnant water body (${\leq}0.2m/s$). Also, algae harvesting ship with dissolved air flotation, conveyor belt and filtration processes and natural floating coagulant were found to have better field applicability, compared to other technologies. However, proper algae removal technology in specific rivers and lakes should be chosen after the evaluation of long-term pilot scale field test. Also, development of energy and resource recovery technologies from algae biomass is warranted.

Activation of transient receptor potential vanilloid 3 by the methanolic extract of Schisandra chinensis fruit and its chemical constituent γ-schisandrin

  • Nam, Yuran;Kim, Hyun Jong;Kim, Young-Mi;Chin, Young-Won;Kim, Yung Kyu;Bae, Hyo Sang;Nam, Joo Hyun;Kim, Woo Kyung
    • The Korean Journal of Physiology and Pharmacology
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    • v.21 no.3
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    • pp.309-316
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    • 2017
  • Transient receptor potential vanilloid 3 (TRPV3) is a non-selective cation channel with modest permeability to calcium ions. It is involved in intracellular calcium signaling and is therefore important in processes such as thermal sensation, skin barrier formation, and wound healing. TRPV3 was initially proposed as a warm temperature sensor. It is activated by synthetic small-molecule chemicals and plant-derived natural compounds such as camphor and eugenol. Schisandra chinensis (Turcz.) Baill (SC) has diverse pharmacological properties including antiallergic, anti-inflammatory, and wound healing activities. It is extensively used as an oriental herbal medicine for the treatment of various diseases. In this study, we investigated whether SC fruit extracts and seed oil, as well as four compounds isolated from the fruit can activate the TRPV3 channel. By performing whole-cell patch clamp recording in HEK293T cells overexpressing TRPV3, we found that the methanolic extract of SC fruit has an agonistic effect on the TRPV3 channel. Furthermore, electrophysiological analysis revealed that ${\gamma}$-schisandrin, one of the isolated compounds, activated TRPV3 at a concentration of $30{\mu}M$. In addition, ${\gamma}$-schisandrin (${\sim}100{\mu}M$) increased cytoplasmic $Ca^{2+}$ concentrations by approximately 20% in response to TRPV3 activation. This is the first report to indicate that SC extract and ${\gamma}$-schisandrin can modulate the TRPV3 channel. This report also suggests a mechanism by which ${\gamma}$-schisandrin acts as a therapeutic agent against TRPV3-related diseases.

A Comparative Study on the Manufacturing Processes of Red Wine (포도주(葡萄酒) 제조방법(製造方法)에 관(關)한 비교연구(比較硏究))

  • Byun, Sang-Sook
    • Journal of Nutrition and Health
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    • v.13 no.3
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    • pp.139-144
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    • 1980
  • A study was conducted to examine the physical and chemical changes of wines fermented from three different varieties by three different methods. The products were evaluated by twenty subjects on color, aroma, and taste. The results were as follows; 1) The moisture contents of those varieties were ranged from 90. 70 to 90.82% The Brix sugar and sugar contents were in order of Muscat Bailey A>Alden>Cambell Early. The titratable acidity was higher in Muscat Bailey A and Alden than in Cambell Early while PH of Cambell Early was higher than those of the two others. 2) The specific gravities of the products were slightly decreased as the fermentation progressed. 3) The yeast-fermentation showed the higher degree of alcoholic contents compared to the natural fermentations. of the natural fermentations, the washed-natural fermentation resulted in the lower alcoholic contents than unwashed one. 4) The PH's were also higher in the yeast-fermentation products than in the natural fermentation groups. The difference, however, was smaller as the fermentation progressed further. 5) The total ester coutents of the yeast fermentation group were slightly higher at the beginning of the fermentation than those of the natural fermentation products and the contents were increased during the fermentation in overall. 6) Twenty panel mentors judged the ripe wine products and the order of preference was Alden>Muscat Baliey A>Cabell Early. They preferred the yeast-fermentation wine to the natural fermentation products.

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Characterization of Summertime Aerosol Particles Collected at Subway Stations in Seoul, Korea Using Low-Z Particle Electron Probe X-ray Microanalysis

  • Kim, Bo-Wha;Jung, Hae-Jin;Song, Young-Chul;Lee, Mi-Jung;Kim, Hye-Kyeong;Kim, Jo-Chun;Sohn, Jong-Ryeul;Ro, Chul-Un
    • Asian Journal of Atmospheric Environment
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    • v.4 no.2
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    • pp.97-105
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    • 2010
  • A quantitative single particle analytical technique, denoted low-Z particle electron probe X-ray microanalysis (low-Z particle EPMA), was applied to characterize particulate matters collected at two underground subway stations, Jegidong and Yangje stations, in Seoul, Korea. To clearly identify the source of the indoor aerosols in the subway stations, four sets of samples were collected at four different locations within the subway stations: in the tunnel; at the platform; near the ticket office; nearby outdoors. Aerosol samples collected on stages 2 and 3 ($D_p$: $10-2.5\;{\mu}m$ and $2.5-1.0\;{\mu}m$, respectively) in a 3-stage Dekati $PM_{10}$ impactor were investigated. Samples were collected during summertime in 2009. The major chemical species observed in the subway particle samples were Fe-containing, carbonaceous, and soil-derived particles, and secondary aerosols such as nitrates and sulfates. Among them, Fe-containing particles were the most popular. The tunnel samples contained 85-88% of Fe-containing particles, with the abundance of Fe-containing particles decreasing as the distances of sampling locations from the tunnel increased. The Fe-containing subway particles were generated mainly from mechanical wear and friction processes at rail-wheel-brake interfaces. Carbonaceous, soil-derived, and secondary nitrate and/or sulfate particles observed in the underground subway particles likely flowed in from the outdoor environment by human activities and the air-exchange between the subway system and the outdoors. In addition, since the platform screen doors (PSDs) limit air-mixing between the tunnel and the platform, samples collected at the platform at the Yangjae station (with PSDs) showed a marked decrease in the relative abundances of Fe-containing particles compared to the Jegidong station (without PSDs).