• Title/Summary/Keyword: Chemical Processes

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Atomic Scale Modeling of Chemical Mechanical Polishing Process (Chemical Mechanical Polishing 공정에 관한 원자단위 반응 모델링)

  • Byun, Ki-Ryang;Kang, Jeong-Won;Song, Ki-Oh;Hwang, Ho-Jung
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.18 no.5
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    • pp.414-422
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    • 2005
  • This paper shows the results of atomistic modeling for the Interaction between spherical nano abrasive and substrate In chemical mechanical polishing processes. Atomistic modeling was achieved from 2-dimensional molecular dynamics simulations using the Lennard-jones 12-6 potentials. We proposed and investigated three mechanical models: (1) Constant Force Model; (2) Constant Depth Model, (3) Variable Force Model, and three chemical models, such as (1) Chemically Reactive Surface Model, (2) Chemically Passivating Surface Model, and (3) Chemically Passivating-reactive Surface Model. From the results obtained from classical molecular dynamics simulations for these models, we concluded that atomistic chemical mechanical polishing model based on both Variable Force Model and Chemically Passivating-reactive Surface Model were the most suitable for realistic simulation of chemical mechanical polishing in the atomic scale. The proposed model can be extended to investigate the 3-dimensional chemical mechanical polishing processes in the atomic scale.

A novel method of surface modification to polysulfone ultrafiltration membrane by preadsorption of citric acid or sodium bisulfite

  • Wei, Xinyu;Wang, Zhi;Wang, Jixiao;Wang, Shichang
    • Membrane and Water Treatment
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    • v.3 no.1
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    • pp.35-49
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    • 2012
  • In membrane processes, various agents are used to enhance, protect, and recover membrane performance. Applying these agents in membrane modification could potentially be considered as a simple method to improve membrane performance without additional process. Citric acid (CI) and sodium bisulfite (SB) are two chemicals that are widely used in membrane feed water pretreatment and cleaning processes. In this work, preadsorptions of CI and SB were developed as simple methods for polysulfone ultrafiltration membrane modification. It was found that hydrogen bonding and Van Der Waals attraction could be responsible for the adsorptions of CI and SB onto membranes, respectively. After modification with CI or SB, the membrane surfaces became more hydrophilic. Membrane permeability improved when modified by SB while decreased a little when modified by CI. The modified membranes had an increase in PEG and BSA rejections and better antifouling properties with higher flux recovery ratios during filtration of a complex pharmaceutical wastewater. Moreover, membrane chlorine tolerance was elevated after modification with either agent, as shown by the mechanical property measurements.

New Trends of Non-Traditional Machining Technology (특수가공기술의 최신동향)

  • 김정두
    • Journal of the Korean Professional Engineers Association
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    • v.34 no.2
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    • pp.10-13
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    • 2001
  • Workpiece materials may be relatively easy to machine by traditional methods but workpiece geometry also may be a constraint. Many shapes that are geometrically difficult to handle conventionally may be candidates for nontraditional processes. Nontraditional processes provide new opportunities for product design innovation and productivity improvements. Difficult-to-machine materials of geometric shapes difficult o produce with traditional equipment and tooling, may often be easily and cost effectively machined using nontraditional processes. Notraditional machining processes are relative newcomers o the manufacturing arena. Nontraditional chemical solutions, or even electrolytic current as the working medium rather than a conventional cutting tool or abrasive to remove or shape materials.

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Transprt Phenomena in Bulk Crystal Growth Processes

  • Lan, C.W.
    • Proceedings of the Korea Association of Crystal Growth Conference
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    • 1998.06a
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    • pp.29-33
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    • 1998
  • Transport phenomena paly an inmportant role in bulk crystal growth processes. During crystal growth, the control of the growth front and the dopant concentration is crucial to crystal quality. The growth feasibility in thus determined by the heat transfer controlling the interface convexity and by the mass transfer controlling the constitutional supercooling. Through numerical modeling, a thorough understanding of the growth processes is possible, which in turn is a key to process improvenment. In this paper, we will summarize some work dine in my laboratory, both numerical and experimental, to illustrate the importance of understanding the transport phenomena during crystal growth processes.

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A Case Study of Risk Assessments and Safety Measures in a PCB Manufacturing Process (인쇄회로기판 제조 공정에서 위험성평가와 안전조치 적용 사례 연구)

  • Lee, Young Man;Lee, Inseok
    • Journal of the Korean Society of Safety
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    • v.37 no.4
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    • pp.120-128
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    • 2022
  • Printed circuit boards (PCBs) are a basic component in the electronics industry and are widely used in nearly all electronic products, such as mobile phones, tablet computers, and digital cameras, as well as in electric equipment. PCB manufacturing involves the use of many chemicals and chemical processes and therefore has more risks than other manufacturing sectors. This study aims to identify the causes of possible accidents during PCB manufacturing through risk assessment, develop and implement safety measures, and evaluate the effectiveness of these measures. Note that the safety measures developed to mitigate the risks of a certain process were also implemented for other similar processes. The risk assessments conducted over seven years, from 2015 to 2021, at a PCB manufacturing company identified 361 hazardous processes. Between 2016 and 2019, 41-56 hazardous processes were identified per year; such processes decreased to fewer than 20 per year after 2020. Application of the risk assessment results to the improvement of the hazardous processes with the similar characteristics seems to be effective in decreasing the risks. Equipment-related factors such as lack of appropriate maintenance, low work standards, and defective protection devices were responsible for 59.8% of all possible accidents. Because PCB manufacturing involves many chemicals, skin contact with hazardous substances, electric shock, fire, and explosion were the most common types of possible accidents (81.7%). In total, 505 safety measures were implemented, including 157 related to purchase and improvement of equipment and devices for safety (31.1%), 147 related to the installation/modification of fire prevention facilities (29.1%), and 69 related to the use of standard electrical appliances (13.7%). Risk assessment conducted after implementing the safety measures showed that these measures significantly decreased risk; 247 processes (68.4%) had a risk level of 3, corresponding to "very low," and 114 processes (31.6%) showed a risk level of 4, corresponding to "low." In particular, risk assessment of 104 processes with risk scores of 12 and 10 other processes with risk score of 16 showed that the risk decreased to 4 after implementing the safety measures. Thus, implementing these measures in similar manufacturing sectors that involve chemical processes can mitigate risk.

Anti-apoptosis Engineering

  • Kim, Eun-Jeong;Park, Tai-Hyun
    • Biotechnology and Bioprocess Engineering:BBE
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    • v.8 no.2
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    • pp.76-82
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    • 2003
  • An increased understanding of apoptosis makes anti-apoptosis engineering possible, which is an approach used to inhibit apoptosis for the purpose of therapeutic, or industrial applications in the treatment of the diseases associated with increased apoptosis, or to improve the productivity of animal cell cultures, respectively. Some known anti-apoptosis proteins are the Bcl-2 family, IAP (inhibitor of apoptosis) and Hsps (heat shock proteins), with which anti-apoptosis engineering has progressed. This article reviews anti-apoptosis engineering using known anti-apoptosis compounds, and introduces a 30 K protein, isolated from silkworm hemolymph, as a novel anti-apoptotic protein, that Shows no homology with other known anti-apoptotic proteins. The regulation of apoptosis, using anti-apoptotic proteins and genes originating from the silkworm, Bombyx mori, may provide a new strategy in this field.

Environmental Sensing Technology with Nanotechnology for the Clean Technology (청정공정구현을 위한 나노기술기반 환경 센싱 기술의 개발)

  • Kim, Younghun;Yi, Jongheop
    • Clean Technology
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    • v.11 no.2
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    • pp.75-81
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    • 2005
  • With a development of nanotechonlogy, the concept of environmental technology has been changed from end-of-pipe to green or clean technology. Nanoscience or nanotechnology involves studying and working with matter on a nano-scale. In this article, we introduced the necessity for the development of environmental sensing/monitoring technologies with nanotechnologies for the clean technology.

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Physical and Rheological Properties of Thermoplasticized Crosslinked-Polyethylene Foam in Supercritical Methanol

  • Cho, Hang-Kyu;Hong, Soon-Man;Baek, Kyung-Yeol;Koo, Chong-Min;Lee, Hong-Shik;Lee, Youn-Woo
    • Macromolecular Research
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    • v.17 no.12
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    • pp.950-955
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    • 2009
  • The physical and rheological properties of thermoplasticized irradiation-crosslinked polyethylene foam using supercritical methanol treatment were investigated by GPC, FTIR, DSC, WAXS, DMTA and UDS. The polyethylene foam was selectively decrosslinked into thermoplasticized polyethylene in an appropriate supercritical methanol condition without any undesirable side reactions such as oxidation and disproportionation. The thermoplasticization was promoted with increasing reaction temperature to reach completion above $380^{\circ}C$. The supercritical reaction condition affected the crystallization behavior, and mechanical and rheological properties of the decrosslinked polyethylene foam, but not its crystallographic structure or crystallinity.

Optimal Reaction Conditions for Minimization of Energy and Byproducts in a Poly(ethylene terephthalate) Process

  • Ha, Kyoung-Su;Rhee, Hyun-Ku
    • 제어로봇시스템학회:학술대회논문집
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    • 1999.10a
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    • pp.248-251
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    • 1999
  • The optimal reaction conditions are determined for a PET process, which consists of transesteriflcation, prepolymerization and polycondensation reactors in series. Based on the simulation results of the reactor system, we scrutinize the cause and effect between the reaction conditions and the final properties of the polymer product. We then select the process variables with significant influence on the properties of polymer as control variables and calculate the optimal reaction conditions by iterative dynamic programming (IDP) algorithm with constraints. A new reaction scheme incorporating reactions for by-products as well as three main reactions is considered in the constrained IDP method.

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Comparisons of Reverse Osmosis and Pervaporation Membrane Processes. II. Experimental Interpretations. (역삼투와 투과 증발막 공정의 비교. II. 실험적 해석)

  • Rhim, Ji-Won;Bae, Seong-Youl;Kimura, Shoji;H
    • Membrane Journal
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    • v.3 no.1
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    • pp.35-39
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    • 1993
  • Reverse osmosis(RO) and pervaporation(PV) membrane separation proceaes were compared with each other experimentally for the system of water-ethanol mixtures by using nylon 4 blended membranes. The separation effciencies of PV were better than those of RO as expected in previous paper covering the theoretical comparisons of both processes, however tbe permeabilities data showed erraerie results due to the membrane imperfections.

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