• Computers and Concrete
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• 제22권4호
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• pp.407-417
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• 2018

Over the past three decades, self-compacting concrete (SCC), which is characterized by its superior rheological properties, has been gradually used in construction industry. It is now recognized that the application of SCC using supplementary cementitious materials (SCM) is highly attractive and promising technology reducing the environmental impact of the construction industry and reducing the higher materials costs. This paper presents an experimental study that investigated the mechanical and durability properties of SCCs manufactured with blended binders including fly ash, slag, and micro-silica. A total of 8 batches of SCCs were manufactured. As series of tests were conducted to establish the rheological properties, compressive strength, and durability properties including the water absorption, water permeability, rapid chloride permeability and initial surface absorption of the SCCs. The influences of the SCC strength grade, blended types and content on the properties of the SCCs are investigated. Unified reactive indices are proposed based on the mix proportion and the chemical composition of the corresponding binders are used to assess the compressive strength and strength development of the SCCs. The results also indicate the differences in the underlying mechanisms to drive the durability properties of the SCC at the different strength grades.

• 한국신재생에너지학회:학술대회논문집
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• 한국신재생에너지학회 2010년도 추계학술대회 초록집
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• pp.86.2-86.2
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• 2010

In order to improve polymer electrolyte membrane fuel cell (PEMFC) durability, the durability of membrane electrode assemblies (MEA), in which the electrochemical reactions actually occur, is one of the vital issues. Many articles have dealt with catalyst layer degradation of the durability-related factors on MEAs in relation to loss of catalyst surface area caused by agglomeration, dissolution, migration, formation of metal complexes and oxides, and/or instability of the carbon support. Degradation of catalyst layer during long-term operation includes cracking or delamination of the layer which result either from change in the catalyst microstructure or loss of electronic or ionic contact with the active surface, can result in apparent activity loss in the catalyst layer. Membrane degradation of the durability-related factors on MEAs can be caused by mechanical or thermal stress resulting in formation of pinholes and tears and/or by chemical attack of hydrogen peroxide radicals formed during the electrochemical reactions. All of these effects, the mechanical damage of membrane and degradation of catalyst layers are more facilitated by uneven stress or improper MEA fabrication process. In order to improve the PEMFC durability, therefore, it is most important to minimize the uneven stress or improper MEA fabrication process in the course of the fabrication of MEA. We analyzed the effects of the MEA fabrication condition on the PEMFC durability with MEA produced using CCM (catalyst coated membrane) method. This paper also investigated the effects of MEA fabrication condition on the PEMFC durability by adding additional treatment process, hot pressing and pressing, on the MEA produced using CCM method.

• 지질공학
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• 제27권4호
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• pp.451-462
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• 2017

Physical weathering caused by external forces and chemical weathering caused by the decomposition or alteration of constituent materials are the two factors that dominate the mechanical properties of rocks. In this study, a field investigation was undertaken to identify the physical and chemical weathering characteristics of the biotite granite and granitic weathered soils in Gyeongju, South Korea. Samples were collected according to their grade of weathering and subjected to modal analysis, XRD analysis, XRF analysis, physical property tests, particle size distribution tests, and slake durability tests. Modal and XRD analysis identified these rocks as biotite granite; secondary alteration minerals were not observed. Physical property tests and particle size distribution analyses indicate an average porosity of 41.28% and a sand content of > 90 wt.%. These values are somewhat higher than those of granites in general. The results of the slake durability test and XRF analyses show that the physical and chemical weathering indices of the samples vary with the degree of weathering.

• Korean Chemical Engineering Research
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• 제52권5호
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• pp.558-563
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• 2014

고분자 전해질 연료전지의 성능과 내구성에 미치는 막 전극 접합체(MEA) 제조방법의 영향에 대해 연구하기 위해 닥터 블레이드 방법, 스프레이 방법, 스크린 프린트 방법 그리고 스크린 프린트+스프레이 방법에 의해 MEA를 제조하였다. 제조된 MEA를 체결한 단위전지의 성능을 측정해 각 MEA의 초기 성능을 비교하였다. 10초간 0.6V 일정전압 유지 후 0.9 V에서 10초간 유지하는 전극 열화 가속 시험(AST)을 각 MEA 적용해 내구성을 시험하였다. 전극 열화 가속 시험 6,000 사이클 전 후 I-V 곡선, 임피던스, 순환 전압측정법(CV), 선형쓸음 전기량측정법(LSV), 투과전자현미경(TEM) 등을 측정하였다. 닥터 블레이드 방법에 의해 제조한 MEA의 초기 성능이 제일 높았고, 스크린 프린트+스프레이 방법에 의해 제조한 MEA가 제일 낮은 열화 속도를 보였다.

• 한국건축시공학회:학술대회논문집
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• 한국건축시공학회 2009년도 춘계 학술논문 발표대회 학계
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• pp.247-252
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• 2009

The LMC method of construction which have application to the road bridge is being considered the least relative importance about the watertight performance, because it focused on the durability of concrete. However, The LMC which is being expanded scope of application to the method of construction has grown importance about the watertight performance on the usability and maintenance side as well as durability. In this study, The latex concrete of two types which are different from mingled-ratio of the latex made a comparison to the compressive strength, watertight performance, dynamic wheel load resistance performance and confirmed what it has resistibility about chemical action through the chemical resistance test. The initial strength and watertight performance showed that were tendency the downward at 14 days. However, The long-term strength after 28 days showed that it has firm performance. In consequence, The initial curing of latex concrete is required to scrupulous care and attention at the site application. As a chemical resistance test result, The specimen that is steeped in sulphuric acid solution of 2% discovered the delamination phenomenon. However, it was confirmed that delamination phenomenon don't have an effect on the compressive strength. Moreover, As a dynamic wheel load resistance test result, The latex concrete was concluded to confirming the durability and running stability, because it had hardly any thickness reduction of latex concrete surface about dynamic wheel load and rarely found crack and delamination.

• KIEAE Journal
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• 제8권5호
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• pp.55-60
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• 2008

The purpose of this study is to increase the use of Hwangto and examine the strength according to what it is compounded with. Hwangto-concrete containing Hwanto without cement nor organic chemical products were compared to the traditional cement concrete through some durability experiments. We expect to gain more knowledge on the potentials of Hwangto-concrete as an architectural source. 1) As Hwangto binder amount rises, the value of slump increases too. The reason is that the increase of the quantity of cement causes the increase of the amount of material and the decrease of the amount of aggregate. 2) When the mixed component into Hwangto-concrete remains at 2%, the compress strength is generally dispersed high along the per unit fission, in case the amount of which is at $400(g/m^3)$. The highest compress strength is 39MPa. It means that it can be applied to common structures and we need to conduct a basic property test to ensure the strength and fluidness. 3) Hwangto-concrete is expected to be highly used in the ocean structure and chemical industry because it has better resistance to sulfuric acid and to hydrochloric acid than the cement-concrete has. The result of this study is as follows. It is expected that Hwangto-concrete will be widely applied and further research on its durability and tests for its basic substantial characteristics based on future component added to it.

• 한국산학기술학회논문지
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• 제14권2호
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• pp.943-948
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• 2013

본 연구에서는 콘크리트의 내구수명 개선을 위한 친환경 수지인 UM수지 화합물을 혼합한 시멘트 모르타르의 특성을 연구하였다. 친환경수지인 UM수지를 일반 시멘트 모르타르와 일정비율로 혼합하였다. UM수지를 혼합한 폴리머 시멘트 모르타르에 대하여 압축강도, 쪼갬인장강도, 휨강도, 흡수율 및 내약품성 실험을 수행하였다. 재료실험결과 친환경 수지인 UM수지를 함유한 시멘트 모르타르는 압축강도와 쪼갬인장강도는 감소하는 반면 휨강도와 흡수율 및 내약품성에서는 성능이 개선되었다. 친환경 UM수지 폴리머 시멘트 모르타르는 콘크리트 내구성 보강성능이 우수하였다.

• 한국지반공학회지:지반
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• 제12권2호
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• pp.115-132
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• 1996

연약지반 안정화공법으로서 각종 고결공법이 성행하고 있으나 해성점토지반이나 통수지반과 같은 특수조건하에서는 시공도 까다롭지만 강도발현이나 내구성 등의 측면에서 보강효과가 저하하는 것을 볼 수 있다. 고결공법은 혼합(고압)처리방식과 주입방식으로 대별할 수 있는 데, 본 연구에서는 첫째로 해성점토지반에 시멘트에 의한 지반보강시의 강도열화문제와 두번째로 지하수흐름이 있는 지반에서의 물유리계 약액주입시의 주입효과증대 및 내구성 문제에 촛점을 맞추어 그 해결방안을 검토 하였다.

• 한국건축시공학회:학술대회논문집
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• 한국건축시공학회 2005년도 추계 학술논문 발표대회
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• pp.97-100
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• 2005

Recently sewage facilities mainly consisted of concrete structures are being deteriorated seriously by biodeterioration originated from sulfur-oxidizing bacteria. In this study, to prevent biochemical corrosion of the sewer concrete, antibiotics which prevent the growth of sulfur-oxidizing bacteria were developed and antimicrobial performance of it was investigated. After that, to consider applicability of antibiotics to concrete, durability such as resistance to carbonation, salt damage and chemical attack of concrete covered with inorganic and complex antibiotics were investigated. As a result of this study, it was proved that the antimicrobial performance of antibiotics was available. Also resistance to carbonation, salt damage and chemical attack of concrete covered with inorganic antibiotics was little improved but, in case of complex antibiotics, was remarkably improved. Moisture content of concrete, as a application condition of antibiotics in whole case, have little effect on performance but covering times of antibiotics have effect on performance only in case of complex antibiotics.

• 한국환경과학회지
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• 제17권1호
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• pp.107-112
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• 2008

A study on the enhancement of environmental durability of EPDM rubber materials for the aerator membrane was performed using a butyl rubber as a modifier. A conventional EPDM rubber formulation was evaluated as having about 26.0 wt% or more oil content from the chloroform immersion test. These oils would be gradually and continuously deleted from the aerator membrane when directly exposed to a waste-water or chemically corrosive fluids, making the membrane less flexible and the performance worse. To improve this, a butyl rubber (IIR) was utilized as the modifier for a low-ENB type of EPDM rubber formulation with low-oil content. The environmental durability of the IIR-modified EPDM rubber material was expected to be greatly enhanced compared to the conventional one. However, the mechanical and performance properties such as elongation, tensile strength, and air bubble size, etc. were still maintained as good as in the conventional one. Furthermore, TGA analysis of the IIR-modified EPDM material showed that there would be partially compatible between IIR and EPDM. It also showed that the initial degradation temperature of the IIR-modified EPDM could be somewhat increased, exhibiting the enhanced compatibility among the components and, thereby, more enhanced environmental durability.