• Title/Summary/Keyword: Chemical Durability

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Chemical Resistance Characteristics of Concrete Surface Coating Agent with Flexibility (유연성을 갖는 콘크리트 표면보호재의 내화학적 특성)

  • Han, Sang-Hoon;Yoon, Ju-Yong;Lee, Byung-Ro;Hong, Ki-Nam
    • Journal of the Korean Society of Safety
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    • v.27 no.3
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    • pp.96-103
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    • 2012
  • The purpose of this study is evaluate the ability of coating materials developed in order to prevent the durability deterioration of the concrete structure. Neutralization test, freezing and thawing test, and sulfate resistance test were performed in this study. Test results show that the developed coating material is effective against durability deterioration.

The Evaluation of Durability and Bond of Resin Concrete (레진 콘크리트의 부착성 및 내구성 평가)

  • Yoo Sung Won;Suh Jeong In;Jeon Sung Hwan;Hwang Sun Bok
    • Proceedings of the Korea Concrete Institute Conference
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    • 2004.11a
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    • pp.715-718
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    • 2004
  • The evaluation of durability of resin concrete was examined through various tests, i.e., compressive strength, absorption, abrasion, chemical attack resistance and bond between general and resin concrete. 2 types of concrete were used such as 40 MPa of general concrete and 90 MPa of resin concrete. The characteristics of resin concrete was more improved than that of general concrete, and especially, resin concrete was most effective on compressive strength, the resistance to $H_2SO_4$ solution attack and absorption. However, abrasion. is almost same between general concrete and resin concrete.

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The Effect of Corona Treated on Laminating Film and Its Analytical Study by SEM (라미네이팅 필름의 코로나 처리 효과와 주사 전자현미경을 이용한 해석)

  • Kim, Jong-Gyu;Kim, Yang-Pioung
    • Journal of the Korean Graphic Arts Communication Society
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    • v.26 no.2
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    • pp.15-30
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    • 2008
  • Studies were carried out the phenomenal observation on the effect of corona treated hotmelt laminating film in process of manufacture by 2 kinds of experiments. These are as follow: 1) In order to verify the treatment reducing value of dynes and dynes durability with the lapse of time, it was checked dynes of a pair of 4 bar discharge electrode with 9 one for 144 hr., and it show results that 9 bar discharge electrode has higher initial dynes as well as keep up 48 dynes durability long than 4 one. 2) Drawn an inference from 3 actions -Chemical-Physical-Mechanical, on laminating film in terms of SEM's observation that are the adhesive status in boundary of corona treated base film, extrusion coating hotmelt layer, and configuration of hotmelt surface after corona treated. In tandem system, EVA layers adhesion keep its stability without corona discharge treatment.

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Evaluation of Performance on Repair Materials for Creek Concrete Structures (콘크리트 복개구조물용 보수재료의 성능 평가)

  • Lee, Chang-Soo
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.6 no.1
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    • pp.205-212
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    • 2002
  • The deterioration rate of concrete structures in urban area is accelerated due to rapid urbanization and environmental pollution. Repair materials and methods newly introduced in Korea should be investigated whether they are appropriate for the urban environment in Korea. The creek concrete structures are exposed in severe environmental condition than others. Based on these background in mind, the study is focused on evaluation of performance on repair materials used to rehabilitate creek concrete structures. To evaluate the performance of repair materials, four kinds of repair materials were selected based on polymer emulsion. This experimental study was conducted on fundamental performance such as setting time, compressive strength, bending strength, bonding strength, thermal expansion coefficient, and durability performance such as chloride diffusion, carbonation, chemical attack, and steel corrosion rate. On the basis of this study, the optimal repair material which is proper to the environment condition can be selected and service life of creek concrete structures can be extended. As a result, the life cycle cost can be reduced and the waste of material resources will be cut down.

Potential of Torrified Tulip-tree for the Production of Solid Bio-fuels (백합나무의 반탄화 처리를 이용한 고체연료화 가능성 조사)

  • Ahn, Byoung Jun;Yang, In;Kim, Sang Tae;Park, Daehak
    • New & Renewable Energy
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    • v.9 no.4
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    • pp.40-50
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    • 2013
  • This study was performed to investigate the potential of torrefied tulip tree (TT) for the production of pellets. For this purpose, chemical composition and fuel characteristics of torrefied TT were examined. In addition, pellets were fabricated by using sawdust of torrefied TT chip, and durability of the pellet was measured. Lignin content of torrefied TT was higher than that of non-torrefied TT, and increased with the increases of torrefaction temperature and time. Fuel characteristics of torrefied TT were affected by torrefied conditions, and the characteristics were influenced more by torrefaction temperature than by torrefaction time. Higher heating value (HHV) and ash content (AC) of torrefied tulip tree increased with increasing torrefaction temperature, and the values were much higher than HHV and AC values of non-torrefied TT. Durability of pellets fabricated with $230^{\circ}C$- and $250^{\circ}C$-torrefied TT was higher than that of $270^{\circ}C$-torrefied TT, and the value exceeded the minimum requirement (-97.50%) of the 1st-grade pellet standard designated by Korea Forest Research Institute. Based on the results, torrefaction treatment of $250^{\circ}C/50min$ to TT might be a optimal condition for the production of TT pellets considering the mass balance and fuel characteristics of TT as well as the durability of the pellets. Thus, it is confirmed that torrefied TT can be used as a raw material for the production of bio-pellets.

A Study on Characteristics of Supports Materials for Durability Improvement of Electrocatalysts (전극촉매의 내구성 향상을 위한 지지체 특성 평가 연구)

  • JANG, JEONGYUN;YIM, SUNG-DAE;PARK, SEOK-HEE;JUNG, NAMGEE;PARK, GU-GON
    • Journal of Hydrogen and New Energy
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    • v.30 no.6
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    • pp.531-539
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    • 2019
  • The development of cost-effective electrocatalysts with high durability is one of the most important challenges for the commercialization of polymer electrolyte fuel cells (PEFCs). The durability of the electrocatalyst has been studied in terms of structural change in the active metal and the support. In particular, in fuel cell vehicles, degradation of the carbon-based support is known to have a significant effect on the electrocatalyst deterioration since the start-up/shut-down cycle is frequently repeated. The requirements for the support of the electrocatalyst include high surface area, electrical conductivity, chemical stability, and so on. In this study, we propose the evaluation methods for choosing better support materials and present the physicochemical properties that promising carbon supports should have. Three kinds of carbon materials with different crystallinity are compared. From in-depth study using X-ray diffraction, Raman spectroscopy, thermogravimetric analysis, and accelerated stress test, it is clearly confirmed that the durability of carbon-supported electrocatalysts is closely related to the physicochemical properties of the carbon supports.

Effect of Steel Fiber Addition on the Mechanical Properties and Durability of High-Flowable Retaining Wall Material (고유동 흙막이 벽체 재료의 역학적 성능 및 내구성에 대한 강섬유 혼입률의 영향)

  • Donggyu Kim;Seungtae Lee
    • Journal of the Korean GEO-environmental Society
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    • v.24 no.6
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    • pp.13-20
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    • 2023
  • This paper is aimed to evaluate the mechanical properties and durability of high-flowable retaining wall material (RWM) with different levels of steel fiber (SF) content. To produce the specimens of RWM, some chemical agents such as superplasticizer (SP), air-entrained agent (AEA) and viscosity modifying agent (VMA) were added in the fresh RWM. The compressive and split tensile strength measurements were performed on the hardened RWM specimens at the predetermined periods. Additionally, surface electric resistivity and absorption tests according to ASTM standards were carried out to examine mechanical properties of RWM mixes. The durable performances such as chloride ions penetrability and freezing-thawing resistance of RWM mixes were experimentally investigated. As resutls, it was found that the performance of RWM mix with SF were much better than that without SF, especially at the 2% addition of SF. Thus, it is noted that the proper addition of SF in the RWM mix may have a beneficial effect to improve mechanical properties and durability of RWM mixes.

Effect of universal adhesive pretreatments on the bond strength durability of conventional and adhesive resin cements to zirconia ceramic

  • Tae-Yub Kwon;Seung-Hee Han;Du-Hyeong Lee;Jin-Woo Park;Young Kyung Kim
    • The Journal of Advanced Prosthodontics
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    • v.16 no.2
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    • pp.105-114
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    • 2024
  • PURPOSE. This study aimed to evaluate the effect of pretreatment of three different universal adhesives (Single Bond Universal [SBU], All-Bond Universal [ABU], and Prime&Bond universal [PBU]) on the bonding durability of an adhesive (Panavia F 2.0, PF) and a conventional (Duo-Link, DL) resin cements to air-abraded zirconia. MATERIALS AND METHODS. Rectangular-shaped zirconia specimens were prepared. The chemical composition and surface energy parameters of the materials were studied by Fourier transform infrared spectroscopy and contact angle measurement, respectively. To evaluate resin bonding to the zirconia, all the bonding specimens were immersed in water for 24 h and the specimens to be aged were additionally thermocycled 10000 times before the shear bond strength (SBS) test. RESULTS. The materials showed different surface energy parameters, including the degree of hydrophilicity/hydrophobicity. While the DL/CON (no pretreatment) showed the lowest SBS and a significant decrease in the value after thermocycling (P < .001), the PF/CON obtained a higher SBS value than the DL/CON (P < .001) and no decrease even after thermocycling (P = .839). When the universal adhesives were used with DL, their SBS values were higher than the CON (P < .05), but the trend was adhesive-specific. In conjunction with PF, the PF/SBU produced the highest SBS followed by the PF/ABU (P = .002), showing no significant decrease after thermocycling (P > .05). The initial SBS of the PF/PBU was similar to the PF/CON (P = .999), but the value decreased after thermocycling (P < .001). CONCLUSION. The universal adhesive pretreatment did not necessarily show a synergistic effect on the bonding performance of an adhesive resin cement, whereas the pretreatment was beneficial to bond strength and durability of a conventional resin cement.

Effect of Ramping Rate on the Durability of Proton Exchange Membrane Water Electrolysis During Dynamic Operation Using Triangular Voltage Cycling

  • Hye Young Jung;Yong Seok Jun;Kwan-Young Lee;Hyun S. Park;Sung Ki Cho;Jong Hyun Jang
    • Journal of Electrochemical Science and Technology
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    • v.15 no.2
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    • pp.253-260
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    • 2024
  • Proton exchange membrane water electrolysis (PEMWE) is an efficient method for utilizing renewable energy sources such as wind and solar powers to produce green hydrogen. For PEMWE powered by renewable energy sources, its durability is a crucial factor in its performance since irregular and fluctuating characteristics of renewable energy sources, especially for wind power, can deteriorate the stability of PEMWE. Triangular voltage cycle is well able to simulate fluctuating wind power, but its effect on the durability has not been investigated extensively. In this study, the performance degradation of the PEMWE cell operated with the triangular voltage cycling was investigated at different ramping rates. The measured current responses during the cycling gradually decreased for both ramping rates, and I-V curve measurements before and after the cycling confirmed the degradation of the performances of PEMWE. For both measurements, the degradation rate was larger for 300 mV s-1 than 30 mV s-1, and they were determined as 0.36 and 1.26 mV h-1 (at the current density of 2 A cm-2) at the ramping rates of 30 and 300 mV s-1, respectively. The comparison with other studies on triangular voltage cycling also indicate that an increase in the ramping rate accelerates the deterioration of the PEMWE performance. X-ray photoelectron spectroscopy and transmission electron microscopy results showed that the Ir catalyst was oxidized and did not dissolve during the voltage cycling. This study suggests that the ramping rate of the triangular voltage cycling is an important factor for the evaluation of the durability of PEMWE cells.

Molecular Dynamics and Quantum Chemical Molecular Dynamics Simulations for the Design of MgO Protecting Layer in Plasma Display Panel

  • Kubo, Momoji;Serizawa, Kazumi;Kikuchi, Hiromi;Suzuki, Ai;Koyama, Michihisa;Tsuboi, Hideyuki;Hatakeyama, Nozomu;Endou, Akira;Takaba, Hiromitsu;Kajiyama, Hiroshi;Shinoda, Tsutae;Miyamoto, Akira
    • 한국정보디스플레이학회:학술대회논문집
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    • 2008.10a
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    • pp.1049-1052
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    • 2008
  • We developed novel molecular dynamics and quantum chemical molecular dynamics simulators for the design of MgO protecting layer in plasma display panel. These simulators were applied to the investigations on the destruction processes of the MgO protecting layer as well as the evaluation of its second electron emission ability. From the simulation results, we successfully proposed new guidelines for MgO protecting layer with high durability and high second electron emission ability.

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