• Title/Summary/Keyword: Chemical Accidents

Search Result 477, Processing Time 0.026 seconds

A Study on the Marine Environmental Protection of Northeast Asian Seas in International Law (국제법상 동북아해저환경보존에 관한 연구)

  • 이윤철
    • Journal of the Korean Institute of Navigation
    • /
    • v.19 no.2
    • /
    • pp.77-97
    • /
    • 1995
  • The protection of the marine environment is one of the main international legal problems in recent years. In parallel with the industrial development, a great quantity of chemical materials were used and in consequence, mass transportation of oil and other dangerous materials was required on the one hand, and discharge of industrial wasters drew also the attention on the other hand. Furthermore, oil tankers accidents, mass use of nuclear materials, sea-bed exploration and exploitation stimulated further deep human concern on the marine environment. The expansion of international concern to new and more dangerous sources of marine pollution regarded more strict and legal control on the Oil Tanker(DWT 95, 000tons, Cb=0.805) model. Calculation results are compared to the international, especially regional level. In particular, this study is concerned with the preservation of the Northeast Asian Seas surrounded by Japan, the Russian Far East, South Korea, North Korea, China and Taiwan. These adjacent countries must intensify cooperation regarding the prevention, reduction and control of the contamination of the sea. And this cooperation between the States concerned should, as much as possible, be aimed at maximizing the effectiveness of measures to prevent or abate transboundary environmental pollution. To achieve this purpose, States concerned should be imposed upon duties such as duty to assess the environmental impact, duty to inform, duty to consult and duty to assist on the basis of general principle of international law, international customary law and other various resolutions of international bodies. Depending on the nature and extent of actual or potential transboundary pollution with the use of a natural resource or the environment in general the establishment of some form of institutionalized cooperation between the States concerned may become useful or indispensable. The functions of this Organization are, inter alia, to keep the implementation of the Convention and the protocals under continuous observation, to make recommendations on regional or sub-regional rules and standards to be elaborated and on measures to be taken by the Contracting Parties, to be notified of any grave and imminent danger from pollution or threat of pollution by the Contracting Parties and to promote in close cooperation with appropriate governmental bodies additional measures to protect the marine environment of the Northeast Asian Seas, and so on. Above mentioned countries, first of all, are located within the Northeast Asian Seas geographically and, therefore, take responsibilities of preserving the clean sea against marine interferences regardless of any difference of the social, political and economic systems. They must be followed under the UNCLOS and other marine conventions. Under the present circumstances, Northeast Asian Seas will become dead seas in case that there is no instant and prompt action against pollution. Hence we have an absolute obligation to promote the development of the mandatory international environmental law, which in turn can faciliate more effective implementation of the regional cooperation by the neighbouring states within this area.

  • PDF

Potential Environmental Influences in Soil by Accidental Fluorine (F) Leakage, Using Leaching Test (용출시험을 통한 불산 누출사고지역의 토양 내 불소(F)의 거동특성)

  • Kim, Doyoung;Lee, Junseok;Kwon, Eunhye;Lee, Hyun A;Yoon, Hye-On;Lee, Sanghoon
    • Journal of Korean Society of Environmental Engineers
    • /
    • v.37 no.4
    • /
    • pp.234-239
    • /
    • 2015
  • Various leaching tests were applied to the soil affected by accidental leakage of HF in an industrial area in Korea. Three different leaching methods including pH-stat, continuous batch leaching, and column tests were adopted to assess leaching characteristics and mobility of fluorine(F) in soil and the potential risks to ecosystem. Both natural and spiked samples were used for the leaching tests. F concentrations in the batch tests increased by leaching rapidly in the early stage of leaching and then maintained rather constant levels. Column leaching test also show similar result to that of the batch test. pH also controlled the leaching behavior of the soil. With increasing pH, more F was released in the pH-stat test. This is mainly due to the competition and exchange with hydroxyl ions, as pH increase to the alkaline range. Most of the F released by the accident seem to have removed in the very early stage of leaching, whereas some natural proportion from soil minerals are thought to have been released very slowly. Therefore, little F released during the accident remained, based on the results of this study on the samples after two years of the accident. We could conclude that soil contaminated by external effects such as chemical accidents should be managed immediately, especially with F.

A Study on the Destruction or Removal Efficiency of Toxic Gas Reduction Facilities in Semiconductor and Display Industries (반도체 & 디스플레이 업종에서 사용되는 독성가스 저감시설의 처리효율 측정방법에 관한 연구)

  • Jang, Sung-Su;Han, Jae-Kook;Cho, Hyun-Il;Lee, Su-Kyung
    • Journal of the Korean Institute of Gas
    • /
    • v.21 no.6
    • /
    • pp.88-95
    • /
    • 2017
  • The usage of toxic gas in Korea is increasing in the development of high-tech industries such as semiconductors, displays and solar panels. The recent survey of domestic toxic gas consumption indicates an increase in annual average of 12.4 percent, but it is still focused on usage, and it is negligent in safety and treating the post. In September 2012, an accident occurred in Gu-mi involving hydrofluoric acid leak demonstrates the absence of safety management. Due to the incident, the government, industry and academia have been interested in chemical substances(toxic gas), and the government-led safety management has been established and implemented, but there are still a lot of safety blind spots. The purpose of this study is to develop effective measurement methods for the destruction or removal efficiency of gaseous materials emitted from the Scrubber used in the semiconductor and display industries. Also, this study demonstrated how toxic gas facilities can be applied without error by verification test for the measurement method guideline of the destruction or removal efficiency of the green-house gas reduction facility in the semiconductor and display industries used by the National Institute of Environmental Research and the UNFCCC, and suggested the differentiated measurement methods for toxic gas reduction facilities, and the third party certification for safety facilities is needed to prevent toxic gas accidents.

Risk Assessment and Safety Measures for Methanol Separation Process in BPA Plant (BPA 공장의 메탄올 분리공정에서 위험성 평가 및 안전대책)

  • Woo, In-Sung;Lee, Joong-Hee;Lee, In-Bok;Chon, Young-Woo;Park, Hee-Chul;Hwang, Seong-Min;Kim, Tae-Ok
    • Journal of the Korean Institute of Gas
    • /
    • v.16 no.3
    • /
    • pp.22-28
    • /
    • 2012
  • For a methanol separation column of the BPA (Bisphenol A) plant, HAZOP (hazard and operability) assessment was performed and damage ranges were predicted from the accident scenarios for the fire and the explosion. As a result, the damage range of the jet fire was 20 m in the case of rupture of the discharge pipe (50 mm diameter) of safety valve, and that of the flash fire was 267 m in the case of catastrophic rupture. Also, the damage ranges of the unconfined vapor cloud explosion (UVCE) for the rupture of the discharge pipe and for the catastrophic rupture were 22 m and 542 m, respectively. For the worst case of release scenarios, safety measures were suggested as follows: the pressure instruments, which can detect abnormal rise of the internal pressure in the methanol separation column, should be installed by the 2 out of 3 voting method in the top section of the column. Through the detection, the instruments should simultaneously shut down the control and the emergency shut-off valves.

A Study on the Safety Distance of Benzene and Acrylonitrile Releases in Sccordance with Dike and Hole Size (벤젠 및 아크릴로나이트릴 누출시 방류벽 유무 및 누출공에 따른 피해 영향범위 산정에 관한 연구)

  • Kawg, Youngmin;Oak, Jaemin;Yoon, Sukyoung;Jung, Seungho
    • Journal of the Korean Institute of Gas
    • /
    • v.22 no.1
    • /
    • pp.18-25
    • /
    • 2018
  • As the industries become more developed, the amounts of hazardous materials have been increased. Because of that, the possibility of accidents in plants is expected to increase. Especially, the dispersions of toxic materials cause serious effect to human life and environment, So it is very important to confirm safety distance of discharge accident. For this paper, we proposed new algorithms for toxic liquid, such as benzene and acrylonitrile. and using this argorithm, we are going to predict safety distance. The scenario of accidental release was assumed to be the release of entire quantity in 10 minutes is defined as worst-case scenario and Instantaneous release. Also the release from a partial rupture of line is used as an alternative case scenarios as NICS(National Institute of Chemical Safety) guidelines. Using ALOHA program and the algorithm for liquid toxic materials and suggested the graph, as well as correlated equations which can utilize emergency responders.

A Quantitative Risk Analysis of LPG Leaked During Cylinder Delivery (가스용기 운반 중 누출된 LPG의 정량적 위험 분석)

  • Kim B-J,;Park Ki-Chang;Lee Kuen-Won
    • Journal of the Korean Institute of Gas
    • /
    • v.7 no.2 s.19
    • /
    • pp.33-41
    • /
    • 2003
  • There exists high hazard when transporting LPG as well as using, storing, and producing. For small scale LPG consumer, retailers deliver LPG to customers via a truck loading many LPG cylinders. Suppose there occurred a accident during LPG cylinder transfer, this could result in serious damages to the life and properties in the near or neighbor of the accident spot. In this regard, we made a quantitative risk analysis to estimate the possible damages and the probability through the identification of accidents causes and the simulation of the possible scenario. In this study, we made the Excel & Visual Basic computer program to perform quantitative LPG accident analysis. The simulation showed the following results. In case of UVCE(Unconfined Vapor Cloud Explosion), the effect within l0m of the accident spot showed very severe structural damages and even the accident can break the window glasses of the area of 150 m apart from accident spot. In case of TNT corresponding probit analysis, after 10 minutes LPG leaking, $75\%$ window glasses of 40 m distance was expected to be broken. And $16\%$ frames of 20m distance, $10\%$ frames of 40m distance was expected to be collapsed.

  • PDF

Development of Methane Gas Leak Detector Using Mid-infrared Ray Sensors with $3.2\;{\mu}m$ ($3.2\;{\mu}m$ 중적외선 센서를 이용한 메탄가스누출검지기의 개발)

  • Park, Gyou-Tae;Lyu, Keun-Jun;Han, Sang-In;Oh, Jeong-Seok;Kim, Ji-Yoon;Ahn, Sang-Guk;Yoon, Myung-Seop;Kwon, Jeong-Rock
    • Journal of the Korean Institute of Gas
    • /
    • v.12 no.2
    • /
    • pp.48-52
    • /
    • 2008
  • According to extremely industrial growth, gas facilities, equipments and chemical plants are gradually increased due to incremental demands of annual amount of gases. The safety management of gases, however, is still far from their requirements. Methane, the principal ingredient of natural gas, is inflammable and explosive and is much used in factories and houses. Therefore, these gas safety management is essential. So, we, with a program of the gas safety management, hope to develop the detection system of methane gas leak using mid-infrared ray LED and PD with $3.2\;{\mu}m$. The cryogenic cooling device is indispensible at laser but needless at LED driven on the room temperature if manufacturing optical sensor with $3.2\;{\mu}m$. It, consequently, is not only possible to implement for subminiature and portable type but also able to speedily detect methane of extremely small quantities because the $CH_4$ absorption intensity at $3.2\;{\mu}m$ is stronger than that at $1.67\;{\mu}m$. Our objective of research is to prevent gas leak accidents from occurring previously and to minimize the extent of damage from them.

  • PDF

Study on Characteristics of Change of Physical/Chemical Property in Domestic Aviation Fuel by the Quality Monitoring Analysis (국내 항공유(Jet A-1) 품질모니터링을 통한 물성 변화 특성 연구)

  • Doe, Jin-woo;Youn, Ju-min;Jeon, Hwa-yeon;Yim, Eui-soon;Lee, Joung-min;Kang, Hyung-kyu
    • Journal of the Korean Applied Science and Technology
    • /
    • v.35 no.4
    • /
    • pp.1327-1337
    • /
    • 2018
  • Aviation fuel oil is more strictly controlled than other transport fuels because it can lead to major accidents in the event of a problem. The quality standards of the aircraft are specified by the domestic Korean Standard, the American Society for Testing and Materials and the International Air Transport Association, respectively. From 2016 to 2017, the quality analysis of 6 items such as aromatic content, sulfur content and distillation characteristics was carried out on the jet fuel produced at five domestic refineries. Domestic production of jet fuel has been shown to be in conformity with the quality standards and has been maintained at a constant level throughout the year. Compared with the specification of ASTM and IATA the aromatic content of domestic KS specification is set to be strictly 1.5 wt% higher than the ASTM and IATA setting specification, but it satisfies this specification sufficiently. In addition, other items such as sulfur content, distillation property and flash point satisfied both domestic and international specification.

CFD-based Fire Accident Impact Analysis in Clean Room for semiconductor PR Process (반도체 PR 공정의 클린룸내 CFD 기반 화재 사고 영향 분석)

  • Chun, Kwang-Su;Yi, Jinseok;Park, Myeongnam
    • Journal of the Korean Institute of Gas
    • /
    • v.25 no.6
    • /
    • pp.35-44
    • /
    • 2021
  • The PR (Photo Resist) process in the semiconductor process is a process that uses a mixture of flammable substances. Due to the process equipment is installed in a clean room and when flammable substances leak, there is a high risk of suffocation, fire, and explosion. It is necessary to analyze the impact of accidents that may occur during operation and to evaluate whether the safety of workers can be guaranteed. In this study, the value of radiant heat and temperature change at the monitor point set up virtual inside the clean room was confirmed through CFD simulation of 10 leak and fire scenarios using the FLACS CFD - Fire Module. A fire that occurs inside a clean room transfers high radiant heat to the inter-story structure, but its scope is quite limited, and it is unlikely that it will collapse in a single fire accident. There was no scenario in which two stairs leading to the exit were exposed to high radiant heat at the same time due to a fire accident, therefore workers were able to escape in case of a fire. In addition, it was confirmed that the level of radiant heat and temperature rise rapidly decreased as they moved downstairs. According to the API 520 standard, workers exposed to 6.31 kW/m2 of radiant heat that workers can withstand for 30 seconds were confirmed that it was possible to sufficiently escape from the inside.

A Study of Explosion Risk Assessment for Designation of Dangerous Goods Transshipment Pier at Ulsan Port (울산항 위험물 환적부두 지정을 위한 폭발 위험성 평가에 관한 연구)

  • Kang, Min-Kyoon;Lee, Yun-Sok;Ahn, Young-Joong
    • Journal of Navigation and Port Research
    • /
    • v.45 no.3
    • /
    • pp.109-116
    • /
    • 2021
  • The explosion of a chemical tanker ship during cargo transshipment via double-banking at Ulsan Port, resulted in major damage including fires involving nearby ships. As a follow-up measure to prevent the recurrence of similar accidents, the 'Safety Management of Dangerous Goods in Port' was established, and the designation of a transshipment pier for dangerous goods is required given the risk of explosion and the impact on major facilities in the port. This study evaluated the Fire & Explosion Index of major transshipment cargoes in Ulsan Port to design a transshipment pier based on the Explosion Risk Assessment. Based on the results of Fire & Explosion Index evaluation of styrene monomer and benzene, severe explosion risk was confirmed, and the exposure radius was calculated. Based on the results of the exposure radius, the risk range for each major pier was calculated, and 12 terminals were proposed as transshipment pier candidates considering port facilities, surrounding dangerous facilities, and residential aspects. Since the results of the study suggest transshipment piers based on the risk radius alone, maritime traffic safety, pier and mooring facilities, safety facilities and accessibility for emergency response should be considered comprehensively to designate actual transshipment piers.