• 제목/요약/키워드: Charge transfer efficiency

검색결과 126건 처리시간 0.024초

$3{\beta}$[L-Lysinamide-Carbamoyl] Cholesterol Cationic Lipid as a Biocompatible Vector for Efficient Gene Transfer

  • Choi, Joon-Sig;Lee, Eun-Jung;Jang, Hyung-Suk;Park, Jong-Sang
    • BMB Reports
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    • 제33권6호
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    • pp.476-482
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    • 2000
  • In this paper, we report a new cationic lipid composed of L-lysinamide and cholesterol as a potent gene delivery vector. $3{\beta}$[L-Lysinamide-carbamoyl] cholesterol could self-assemble with plasmid DNA forming discrete lipoplexes. From atomic force microscopic images of the complexes, the size distribution was observed to range from 100 to 150 nm in diameter. The transfection efficiency of this amphiphile on different cell lines was evaluated as a micellar solution in the absence of the fusogenic helper lipid, dioleoyl phosphatidyletbanolamine (DOPE). Transfection experiments were performed as a function of charge ratio (lipid/DNA) and transfection time. Cytotoxicity and in vitro transfection efficiency of the amphiphile was demonstrated and compared with those of commercially available Lipofectin and polyethylenimine (PEI).

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보현산천문대 2K CCD 카메라의 특성 (CHARACTERISTICS OF THE BOAO 2K CCD CAMERA)

  • 박병곤;천무영;육인수;성현철
    • 천문학논총
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    • 제16권1호
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    • pp.31-36
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    • 2001
  • We present the characteristics of the 2K CCD camera at the Bohyunsan Optical Astronomy Observatory of the Korea Astronomy Observatory at the time of its development. The purpose of this paper is to support the observers who may need detailed information on the characteristics of the camera and to provide helpful information on the optimization' of a CCD camera for those who try to develop their own camera. The 2K CCD camera was optimized to have a gain of $1.8e^-/ADU$ and a read out noise of $7e^-$ from an experiment using radioactive $^{55}Fe$ X-ray source. The charge transfer efficiency was measured as 0.9999976 for serial and 0.9999942 for parallel direction, which means $0.5\%$ charge loss along the serial direction and $1.2\%$ along the parallel direction across the chip. The quantum efficiency of the camera was measured from an experiment using a homogeneous light source consisting of a halogen lamp and an integrating sphere with a monochromator. The resulting quantum efficiency of the camera peaked at the wavelength range 600-700 nm with the value of $\~0.89$.

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Controlled Charge Carrier Transport and Recombination for Efficient Electrophosphorescent OLED

  • Chin, Byung-Doo;Choi, Yu-Ri;Eo, Yong-Seok;Yu, Jai-Woong;Baek, Heume-Il;Lee, Chang-Hee
    • 한국정보디스플레이학회:학술대회논문집
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    • 한국정보디스플레이학회 2008년도 International Meeting on Information Display
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    • pp.1418-1420
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    • 2008
  • In this paper, the light emitting efficiency, spectrum, and the lifetime of the phosphorescent devices, whose emission characteristics are strongly dominated not only by the energy transfer but also by the charge carrier trapping induced by the emissive dopant, are explained by differences in the energy levels of the host, dopant, and nearby transport layers. On the basis of our finding on device performance and photocurrent measurement data by time-of-flight (TOF), we investigated the effect of the difference of carrier trapping dopant and properties of the host materials on the efficiency roll-off of phosphorescent organic light emitting diode (OLED), along with a physical interpretation and practical design scheme, such as a multiple host system, for improving the efficiency and lifetime of devices.

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Pd/r-TiO2 나노튜브 이종결합 광촉매의 합성과 특성 (Synthesis and Characteristics of Pd/r-TiO2 Nanotube Arrays Hetrojunction Photocatalyst)

  • 이종호;이영기;김영직;장경욱;오한준
    • 한국재료학회지
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    • 제32권1호
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    • pp.14-22
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    • 2022
  • To improve light absorption ability in the visible light region and the efficiency of the charge transfer reaction, Pd nanoparticles decorated with reduced TiO2 nanotube photocatalyst were synthesized. The reduced TiO2 nanotube photocatalyst was fabricated by anodic oxidation of Ti plate, followed by an electrochemical reduction process using applied cathodic potential. For TiO2 photocatalyst electrochemically reduced using an applied voltage of -1.3 V for 10 min, 38% of Ti4+ ions on TiO2 surface were converted to Ti3+ ion. The formation of Ti3+ species leads to the decrease in the band gap energy, resulting in an increase in the light absorption ability in the visible range. To obtain better photocatalytic efficiency, Pd nanoparticles were decorated through photoreduction process on the surface of reduced TiO2 nanotube photocatalyst (r10-TNT). The Pd nanoparticles decorated with reduced TiO2 nanotube photocatalyst exhibited enhanced photocurrent response, and high efficiency and rate constant for aniline blue degradation; these were ascribed to the synergistic effect of the new electronic state of the TiO2 band gap energy induced by formation of Ti3+ species on TiO2, and by improvement of the charge transfer reaction.

염료감응형 태양전지의 $TiO_2$ Layer 다분할 효과에 따른 효율 향상 연구 (Improvement of Efficiency about $TiO_2$ Layer Multi-dividing Effect in Dye-sensitized Solar Cell)

  • 손민규;서현웅;이경준;홍지태;김희제
    • 한국신재생에너지학회:학술대회논문집
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    • 한국신재생에너지학회 2008년도 춘계학술대회 논문집
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    • pp.425-427
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    • 2008
  • Active area of dye-sensitized solar cell (DSSC) has an effect on the efficiency of DSSC. As the active area increases, the efficiency goes down in a general way. This is caused by the increase of internal resistance in DSSC. The internal resistances are related to various resistant elements. The charge transfer processes at Pt counter electrode and the sheet resistance of TCO are two of these resistant elements. In this study, we try to divide the active area into several small sections in a large sized cell to reduce these two internal resistant elements. As a result, we find out that the fill factor is increased and then the conversion efficiency is improved as the number of dividing active area into several small sections is increased.

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강유전 고분자를 첨가한 유기태양전지의 효율 특성 (The Efficiency Characteristics of the Ferroelectric Polymer Added Organic Solar-cells)

  • 박자영;정치섭
    • 한국전기전자재료학회논문지
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    • 제29권9호
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    • pp.589-594
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    • 2016
  • P3HT:PCBM bulk heterojunction solar cells added with ferroelectric polymer were fabricated and characterized. By incorporating P3HT:PCBM solar cell with P(VDF-TrFE) ferroelectric additive, the power conversion efficiency was increased up to nearly 50%. Photoacoustic analysis on this phenomena was carried out for the first time. Through this study, we find that the ferroelectricity of the polymer additive plays the key role in the enhancement of the power conversion efficiency of the organic solar cell by suppressing the non-radiative recombination of charge transfer exciton more effectively.

Photocatalytic Performance of Graphene-TiO2 Hybrid Nanomaterials Under Visible Light

  • Park, Jaehyeung
    • 한국전기전자재료학회논문지
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    • 제32권2호
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    • pp.161-164
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    • 2019
  • This study describes the development of graphene-$TiO_2$ conjugates for the enhancement of the photocatalytic efficiency of $TiO_2$. Graphene-based hybrid nanomaterials have attracted considerable attention because of the unique and advantageous properties of graphene. In the proposed hybrid nanomaterial, graphene serves as an electron acceptor to ensure fast charge transfer. Effective charge separation can, therefore, be achieved to slow down electron-hole recombination. This results in an enhancement of the photocatalytic activity of $TiO_2$. In addition, increased adsorption and interactions with the adsorbed reagents also lead to an improvement in the photocatalytic activity of graphene-$TiO_2$ hybrid nanomaterials. The acquired result is encouraging in that the photocatalytic activity of $TiO_2$ was initiated using visible light (630 nm) instead of the typical UV light.

고분자 전해질을 이용한 고체형 염료감응 태양전지 (New Polymer Electrolytes for Solid State Dye-Sensitized Solar Cells)

  • 강용수;이용건;강문성;김종학;차국헌
    • 한국신재생에너지학회:학술대회논문집
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    • 한국신재생에너지학회 2007년도 춘계학술대회
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    • pp.231-234
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    • 2007
  • The solid state dye-sensitized saolrc cells (DSSCs) employing polymer electrolytes show high overall energy conversion efficiency as high as 4.5% at 1 sun conditions. The improved efficiency may be primarily due to the enlarged interfacial contact area between the electrolyte and dyes in addition to the increased ionic conductivity, which were done by utilizing liquid oligomers, followed by in situ self-solidification, to form the solid DSSCs "Oligomer Approach". The effect of the charge transfer resistance at the counter electrode side on the effciency has also been investigated.

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Solid State Dye-Sensitized Solar Cells Employing Polymer Electrolytes : Oligomer Approach

  • Kang, Yong-Soo;Lee, Yong-Gun;Kang, Moon-Sung;Kim, Jong-Hak;Char, Kook-Choen
    • 한국고분자학회:학술대회논문집
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    • 한국고분자학회 2006년도 IUPAC International Symposium on Advanced Polymers for Emerging Technologies
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    • pp.63-64
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    • 2006
  • The solid state dye-sensitized solar cells (DSSCs) employing polymer electrolytes show high overall energy conversion efficiency as high as 4.5 % at 1 sun conditions. The improved efficiency may be primarily due to the enlarged interfacial contact area between the electrolyte and dyes in addition to the increased ionic conductivity, which were done by utilizing liquid oligomers, followed by in situ self-solidification, to form the solid DSSCs: "Oligomer Approach". The effect of the charge transfer resistance at the counter electrode side on the efficiency has also been investigated.

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Enhancement of electro-optic performance in dyesensitized solar sell using homeotropically aligned liquid crystal molecular

  • Kim, Hyeon-Kyung;Jin, Sung-Ho;Lee, Gi-Dong
    • 한국정보디스플레이학회:학술대회논문집
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    • 한국정보디스플레이학회 2009년도 9th International Meeting on Information Display
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    • pp.1130-1132
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    • 2009
  • We propose a novel way for enhancement of efficiency on a quasi solid-state dye-sensitized solar cell (DSSC). It contained gel type electrolyte mixing the liquid crystal (LC) of specific concentration and applied voltage for alignment of the LC. Aligned LC is supported charge transfer inside electrolyte and efficiency is increased in DSSC. We made a quasi solid-state DSSC which applied DC voltage or not and have measured the power conversion efficiency (PCE) and the fill factor. From measurement, we obtain high performances in case of cell applied voltage compare to reference cell.

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