• Bulletin of the Korean Chemical Society
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• 제21권4호
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• pp.412-418
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• 2000

Association of cytochrome c with anionic membranes involved both electrostatic and hydrophobic interactions and their relative contributions depended on the physical state of the membrane and the redox state of cyto-chromec.Hydrophobic interaction was favored by the membranes in gel phase, by the membranes with a large curvature, and by the membranes with a high surface charge density. Ferrocytochrome c was less dissociable by NaCl than ferricytochrome c suggesting that a lower protein stability is beneficial for hydrophobic interac-tion.Hydrophobic interaction induced larger structural perturbations on cytochrome c as monitored by the loss of the Fe-Met bond and by the increase in the distance between heme and Trp-59. When bound to anionic mem-branes,spin-labeled cytochrome c showed an electron paramagnetic resonance spectrum with two or more components, providing a direct evidence for multiple conformations of bound cytochrome c.

• Bulletin of the Korean Chemical Society
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• 제18권2호
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• pp.156-161
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• 1997

Aqueous 6-hydroxyquinoline in the first excited singlet state undergoes protonation to the imine group first in 15 ps, then in the time scale of 40 ps deprotonation from the enol group and finally, however, quickly as in 11 ps electron rearrangement to change into a resonance hybrid structure of quinoid-prevailing forms. Despite the fact that the decay time constant is smaller than the formation time constant, fluorescence from excited protropic zwitterion is observed to assign its maximum at 510 nm. The electron rearrangement is basically an intramolecular charge transfer from the deprotonated oxygen atom to the positively charged iminium ring without any notable change in nuclear geometry, producing a zwitterionic quinoid structure with much a smaller electric dipole moment than the zwitterionic protropic species. This photoproduct formed by consecutive excited state proton and electron transfers shows a smaller dipole moment in S1 than in S0 and a hypsochromic shift although its S1 state has (π, π*) character.

• 한국표면공학회지
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• 제56권4호
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• pp.227-232
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• 2023

In this study, complex admittance as a function of temperature and frequency was measured to analyze the important relaxation properties of lead scandium niobate, which is physically important, although it is not an environmentally friendly electrical and electronic material, including lead. Lead scandium niobate was synthesized by heat treating the solid oxide, and the conductance, susceptance and capacitance were measured as a function of temperature and frequency from the temperature dependence of the RLC circuit. The relaxation characteristics of lead scandium niobate were found to be affected by contributions such as grain size, grain boundary characteristics, space charge, and dipole arrangement. As the temperature rises, the maximum admittance and susceptance increase in one direction, but the resonance frequency decreases below the transition temperature but increases after the phase transition.

• Steel and Composite Structures
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• 제50권1호
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• pp.45-61
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• 2024

This research explores the domain of organic solar cells, a photovoltaic technology employing organic electronics, which encompasses small organic molecules and conductive polymers for efficient light absorption and charge transport, leading to electricity generation from sunlight. A computer simulation is employed to scrutinize resonance and dynamic stability in OSCs, with a focus on size effects introduced by nonlocal strain gradient theory, incorporating additional terms in the governing equations related to displacement and time. Initially, the Navier method serves as an analytical solver to delve into the dynamics of design points. The accuracy of this initial step is verified through a meticulous comparison with high-quality literature. The findings underscore the substantial impact of viscoelastic foundations, size-dependent parameters, and geometric factors on the stability and dynamic deflection of OSCs, with a noteworthy emphasis on the amplified influence of size-dependent parameters in higher values of the different layers' thicknesses.

• 전기화학회지
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• 제14권4호
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• pp.201-207
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• 2011

수퍼커패시터는 다양한 응용범위를 갖는 유망한 에너지 저장장치로서 활발히 연구되고 있으며, 에너지 밀도 향상을 위하여 이온성 액체의 적용이 필요하다. 본 연구에서는 4급화 반응과 음이온 교환반응을 거쳐 4급 imidazolium 염을 생성하는 반응으로 두 종류의 EMI-$BF_4$를 합성하였다. $^1H$-NMR을 통하여 EMI-$BF_4$의 합성을 확인하였고 TGA를 통하여 열적안정성을 확인하였으며, 이때 합성된 이온성 액체를 열처리한 경우 열적 안정성이 향상되었다. LSV를 통하여 본 연구에서 합성한 EMI-$BF_4$가 4 V 이상의 넓은 전위창을 가지고 있어, 기존의 전해질 대비 우수한 전기화학적 안정성을 가지고 있음을 확인하였다. 충방전 실험 결과 본 실험에서 합성한 이온성 액체를 상용화 제품과 비교한 경우 용량은 각각 0.067 F 및 0.073 F로 측정되었다.

• 한국정보전자통신기술학회논문지
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• 제12권2호
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• pp.142-149
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• 2019

전기자동차를 무선으로 충전하기 위하여서는 전기에너지를 전송하기 위한 코일이 꼭 필요하다. 코일의 형태는 기본적인 원형 코일에서부터 두 코일 간의 커플링 효과를 높이기 위한 DD 형상의 코일 등 여러 종류가 있다. 하지만 코일 간 커플링이 좋은 DD 형상의 코일은 송수신 측 전력변환장치의 구조가 복잡해지는 단점이 있어 사용에 제한이 있다. 본 논문에서는 자유공간에서 2개의 코일을 이용하여 무선으로 전력을 전송할 때 제작이 편리한 스파이럴 인덕터의 인덕턴스 값을 계산하고 적절한 크기의 인턱터를 설계하는 방법을 제시하였다. 공진기에서 XLm 값이 부하저항 값과 비슷하여질 때 bifurcation 현상이 나타나므로, 이 현상이 덜 일어나도록 XLm 값을 최소부하저항 값과 같도록 선택하여 공진기에 필요한 인덕턴스 값을 계산하였다. 계산된 인덕턴스 값을 스파이럴 인덕터로 구현하기 위하여 스파이럴 인덕터에서 인덕턴스 값과 인턱터의 크기, 턴 수, 총 코일 길이와의 관계를 알아보았다. 또한, 두 개의 코일의 수평 이격에 따른 결합계수 k 값의 변화를 알아본 후 적절한 인덕터를 선정하였다.

• 대한화학회지
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• 제55권3호
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• pp.335-340
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• 2011

양이온성 수용성 5, 10, 15, 20-tetrakis(N-methylpyridinium-4-yl) porphyrin (TMPyP)의 존재 하에서 음이온 계면 활성제인 sodium n-dodecyl sulfate 의 용액 특성을 전도도법, UV-vis 및 공명 빛 산란 (RLS) 분광학적 방법을 이용하여 포괄적으로 연구하였다. 그 결과에 따르면 TMPyP 농도의 증가로 SDS 용액의 임계 미셀 농도는 감소하였는데, SDS 미셀의 안정화는 미셀 표면에 존재하는 음전하의 중화 때문이다. SDS용액 내에는 자유 포르피린 단량체, 미셀에 속박된 포르피린 단량체 또는 응집체, 그리고 nonmicellar porphyrin/계면 활성제 응집체와 같은 세 종류의 TMPy종이 분명히 존재하였다. 우리의 연구 결과는 SDS가 TMPyP의 응집을 유도한다는 것을 나타내었다. 실제로 두 종류의 J-aggregations이 관찰되었는데, 하나는 미셀에 속박된 포르피린 단량체 또는 응집체였으며, 다른 하나는 nonmicellar porphyrin/계면 활성제 응집체이다. 그러나, cmc이하에서는 TMPyP가 SDS 음이온과 정전기 상호작용을 나타내었다.

• 대한전기학회:학술대회논문집
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• 대한전기학회 2009년도 제40회 하계학술대회
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• pp.1232_1233
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• 2009

Paraquat is well-known to cause hepatotoxic responses in human and other mammal species. In solution, it forms free radicals and charge-transfer complex of which formation plays an important role in determination of its biological activity in the presence of various anions. The HepG2 cells were cultured onto a quartz crystal sensor which is possible to detect the density and a viscosity changes using the resonance frequency (F) and the resonance resistance (R). The plot of F-R diagram is able to explain the rheological change of cells onto the surface of the quartz crystal sensor. In this paper, we investigated the physical properties of the HepG2 cells cultured onto a ITO electrode of the quartz crystal sensor according to the paraquat injection at various concentrations (100 mM, 10 mM, 1 mM). We also observed the morphological changes with a micro CCD camera, simultaneously. The HepG2 cells were cultured onto the ITO electrode surface of the quartz crystal modified a collagen film in $CO_2$ incubator. After the paraquat injection, we observed the changes of the morphologies by the micro CCD camera depending on time and analyzed the physical changes of cells on the electrode surface of quartz crystal using F-R diagram. From all results, we proved the effect of paraquat at various concentrations which is led to an apoptosis such as weakening and death of the cells by oxidation and reduction reaction that were produced the superoxide anions and other free radicals.

• 한국진공학회:학술대회논문집
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• 한국진공학회 2013년도 제44회 동계 정기학술대회 초록집
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• pp.537-537
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• 2013

Cyclotron-accelerated ion beams are used for various researches, such as nuclear physics, nuclear chemistry, biotechnology, and material sciences including radio-isotope production. Recently considerable applications are asked to the cyclotron development undertaken to meet user requirements of various ions'energies, intensities, and their pulsed beams. For instance, a cocktail beam acceleration technique rapidly changing the ion species and energies was developed to irradiating integrated circuit chips. Also a chopping system in a cyclotron injection line is considered for producing a pulsed ion beam with a relatively long period compared with that generated by the resonance frequency. For the research in neutron time-of-flight measurement, a single-pulsed beam with a repetition interval of the order of mili-seconds or longer is necessary to have a good resolution and to remove background events. In this paper a feasibility of pulsed beam with an external ion source is simulated by adopting a combination system of a chopper accompanying with a bunching stage in the injection line and an additional chopper after the exit of the cyclotron in order to produce beam pulses with a range of $1{\mu}s{\sim}1ms$ periods from a resonance RF cycle. The pulseperiod will be adjusted by chopping the number of beam bunches from the injected pulses in the injection line. However, the longer pulses will have reduced number of beam pulses and sacrificed beam currents. Because the beam users need an intense single pulsed beam, a careful tuning of the acceleration phase and a high-intense external ion source are necessary to achieve an intense single-pulsed beam from the cyclotron. It is essential to strictly match the acceleration phase of injected beams in the central region of the cyclotron to improve its efficiency. An effect of space charge at each pulse from the ion source will be also considered.

• 한국세라믹학회지
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• 제54권6호
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• pp.530-534
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• 2017

The figures of merit in the on-resonance and off-resonance conditions ($FOM_{on}$ and $FOM_{off}$) for the piezoelectric energy harvester (PEH) were measured and compared in $[(K_{0.485}Na_{0.515})_{1-X}Li_X](Nb_{0.99}Ta_{0.01})O_3$ (x = 0.04 ~ 0.09) (KNLNT) ceramics with various Li contents. The crystal structure of CuO-doped KNLNT ceramics changes from orthorhombic to tetragonal around the Li fraction of 0.065. The stable temperature range for the tetragonal phase widens to both higher and lower temperatures as Li is substituted. The piezoelectric charge constant ($d_{33}$), electromechanical coupling factor ($k_p$) and mechanical quality factor ($Q_m$) have maximum values at the Li fraction between 0.055 and 0.065 where the phase boundary lies between the orthorhombic and tetragonal phases. Both $FOM_{on}$ and $FOM_{off}$ have peak values around the phase boundary but the peak compositions are not exactly coincided. The optimal Li fraction in the KNLNT ceramic for a PEH application was found to be between 0.055 and 0.065.