• 제목/요약/키워드: Charge resonance

검색결과 122건 처리시간 0.022초

여러고리 방향족 화합물과 요오드 사이의 전하이동 착물생성에 관한 열역학적 연구 (Thermodynamics of the Formation of Polynuclear Aromatics-Iodine Charge Transfer Complexes)

  • 권오천;김정림;이영훈
    • 대한화학회지
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    • 제29권6호
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    • pp.575-581
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    • 1985
  • 벤젠, 나프탈렌 및 페난스렌과 요오드 사이의 각계를 사염화 탄소 용액에서 자외선 분광광도법에 의하여 연구한 결과 1:1분자 착물이 형성됨을 알았다. 이들 착물 생성에 의한 흡수 최대는 온도가 상승함에 따라 blue shift되므로 이에 따른 각 온도에서의 평형 상수를 구하였다. 이 값으로부터 이들 착물 생성에 대한 열역학적 파라미터를 산출한 결과 각 온도에서 여러 고리 방향족화합물과 요오드 사이에 생성된 착물의 상대적 안정도는 방향족 고리의 수가 증가함에 따라 증가함을 알 수 있다. 이러한 사실을 요오드에 대한 여러 고리 방향족 화합물들의 상대적 염기성도를 나타내며 방향족 화합물과 요오드 사이의 상호작용에 관한 공명현상에 의하여 설명할 수 있다. 그리고 이 계열의 연구결과를 폴리메틸 벤젠계열의 연구결과와 비교 고찰하였다.

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Silver Colloidal Effects on Excited-State Structure and Intramolecular Charge Transfer of p-N,N-dimethylaminobenzoic Acid Aqueous Cyclodextrin Solutions

  • 최정관;김양희;윤민중;이승준;김관;정새채
    • Bulletin of the Korean Chemical Society
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    • 제22권2호
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    • pp.219-227
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    • 2001
  • The silver colloidal effects on the excited-state structure and intramolecular charge transfer (ICT) of p-N,N-dimethylaminobenzoic acid (DMABA) in aqueous cyclodextrin (CD) solutions have been investigated by UV-VIS absorption, steady-state and time-resolved fluorescence, and transient Raman spectroscopy. As the concentration of silver colloids increases, the ratio of the ICT emission to the normal emission (Ia /Ib) of DMABA in the aqueous $\alpha-CD$ solutions are greatly decreased while the Ia /Ib values in the aqueous B-CD solutions are significantly enhanced. It is also noteworthy that the ICT emission maxima are red-shifted by 15-40 nm upon addition of silver colloids, implying that DMABA encapsulated in $\alpha-CD$ or B-CD cavity is exposed to more polar environment. The transient resonance Raman spectra of DMABA in silver colloidal solutions demonstrate that DMABA in the excited-state is desorbed from silver colloidal surfaces as demonstrated by the disappearance of νs (CO2-)(1380 cm-1 ) with appearance of ν(C-OH)(1280 cm -1) band, respectively. Thus, in the aqueous B-CD solutions the carboxylic acid group of DMABA in the excited-state can be readily hydrogen-bonded with the secondary hydroxyl group of B-CD while in aqueous and $\alpha-CD$ solutions the carboxylic acid group of DMABA has the hydrogen-bonding interaction with water. Consequently, in the aqueous B-CD solutions the enhancement of the Ia /Ia value arises from the intermolecular hydrogen-bonding interaction between DMABA and the secondary hydroxyl group of B-CD as well as the lower polarity of the rim of the B-CD cavity compared to bulk water. This is also supported by the increase of the association constant for DMABA/ B-CD complex in the presence of silver colloids.

자기공명영상 검사에서 외국인 환자를 위한 자동음성 시스템 개발 (Development of Automatic Voice System for Foreign Patients in Testing of Magnetic Resonance Imaging)

  • 구은회
    • 한국방사선학회논문지
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    • 제10권1호
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    • pp.59-64
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    • 2016
  • 본 연구의 목적은 자기공명영상을 이용하여 외국인 환자를 검사할 때 언어의 소통을 위하여 자동음성시스템을 개발하고자 하였다. 자동음성을 위해 사용된 문장은 병원에서 자주 사용하고 있는 12개의 문장과 5개의 외국어를 선택하였다. 이러한 번역된 문장은 Oddcast's website로 부터 무료로 재공 되며 Wav 파일로서 각 언어 특징에 소리로 기록하게 된다. 기록된 오디오 파일은 Mobile phone 환경에서 적용되는 PHP 프로그램을 사용하여 MS-파워포인트(extension; ppsx) 와 Web-enabled system 형태로 재생하게 된다. 음성 시스템 개발은 방사선사에게 언어 소통의 어려움에 관하여 스트레스를 해소될 것이며, 다양한 언어로 설계된 자동음성시스템은 외국인 환자를 검사 할 때 환자에게 진단적 정보를 증가시킬 것이다. 본 연구를 위해 개발된 음성 시스템은 한국의 방사선사와 외국인 환자 사이에서 검사의 이해를 증가시킬 수 있기 때문에 임상실무에서 더욱더 유용하게 이용될 것이라고 기대된다.

자기공명 무선전력전송용 100 W급 수신기 설계 및 제작 (Design and Implementation of a 100 W Receiver for Wireless Power Transfer Using Coupled Magnetic Resonance)

  • 김성민;조인귀;최현철
    • 한국전자파학회논문지
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    • 제27권1호
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    • pp.84-87
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    • 2016
  • 본 논문에서는 자기공명 방식의 무선전력전송 시스템용 100 W급 수신기를 설계, 제작하였다. 제안된 수신기는 1.8 MHz 대역, 100 W급 full-bridge 다이오드 정류기와 정전류 충전기로 구성되어 있다. 특히 정류기에는 30 V 이상의 과전압으로부터 수신기를 보호하는 과전압 보호회로와 수신기에 입력되는 여분 전력을 자동으로 소모하여 수신기의 임력임피던스를 부하변동에 관계없이 일정하게 유지시키는 능동 더미 부하가 내장되어 있다. 정전류 충전기는 최대 1 A의 충전 전류로 배터리를 충전할 수 있도록 설계, 제작되었으며, 충전전류를 제어할 수 있도록 구성되었다. 구성된 수신기를 이용하여 자기공명방식 무선충전 시스템을 구성하였다. 시스템은 130 W 송신기, 1.8 MHz 대역 송수신 공진기, 그리고 제안된 수신기로 구성되어 있으며, 자기공명방식으로 48 V 리튬-이온 배터리를 충전하도록 설계되었다. 시스템 측정 결과, 30 cm의 전송거리에서 약 54 %의 시스템 효율을 나타내었다.

Color Discerning Device의 구조해석을 통한 성능향상에 대한 연구 (A Study on Structural Analysis of Color Discerning Device for the Performance Enhance)

  • 김성현;이규호;정진태
    • 한국소음진동공학회:학술대회논문집
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    • 한국소음진동공학회 2006년도 추계학술대회논문집
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    • pp.571-576
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    • 2006
  • A Color Discerning Device(CDD) is the equipment to use in Rice Processing Complex(RPC). By use a high-speed charge-coupled device camera, CDD can sorting discolored grain according to light and shade. The existing CDD's driving performance is not so good as overseas machine. Besides, transportation process causes a defect in the mechanism from impact or harmonic excitation or etc. This study is represented the problem of CDD through modal analysis and static analysis by using ANSYS workbench. To analysis the problem of driving condition, devide each part of CDD for performed modal analysis. The problem of driving condition and transportation process solved by carry out modal analysis and static analysis.

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Resonant Loop Design and Performance Test for a Torsional MEMS Accelerometer with Differential Pickoff

  • Sung, Sang-Kyung;Hyun, Chul;Lee, Jang-Gyu
    • International Journal of Control, Automation, and Systems
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    • 제5권1호
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    • pp.35-42
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    • 2007
  • This paper presents an INS(Inertial Navigation System) grade, surface micro-machined differential resonant accelerometer(DRXL) manufactured by an epitaxially grown thick poly silicon process. The proposed DRXL system generates a differential digital output upon an applied acceleration, in which frequency transition is measured due to gap dependent electrical stiffness change. To facilitate the resonance dynamics of the electromechanical system, the micromachined DRXL device is packaged by using the wafer level vacuum sealing process. To test the DRXL performance, a nonlinear self-oscillation loop is designed based on the extended describing function technique. The oscillation loop is implemented using discrete electronic elements including precision charge amplifier and hard feedback nonlinearity. The performance test of the DRXL system shows that the sensitivity of the accelerometer is 24 Hz/g and its long term bias stability is about 2 mg($1{\sigma}$) with dynamic range of ${\sigma}70g$.

Thermodynamics of Partitioning of Substance P in Isotropic Acidic Bicelles

  • Baek, Seung Bin;Lee, Hyeong Ju;Lee, Hee Cheon;Kim, Chul
    • Bulletin of the Korean Chemical Society
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    • 제34권3호
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    • pp.743-748
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    • 2013
  • The temperature dependence of the partition coefficients of a neuropeptide, substance P (SP), in isotropic acidic bicelles was investigated by using a pulsed field gradient nuclear magnetic resonance diffusion technique. The addition of negatively charged dimyristoylphosphatidylserine to the neutral bicelle changed the SP partitioning a little, which implies that the hydrophobic interaction between the hydrophobic residues of SP and the acyl chains of lipid molecules is the major interaction while the electrostatic interaction is minor in SP binding in a lipid membrane. From the temperature dependence of the partition coefficients, thermodynamic functions were calculated. The partitioning of SP into the acidic bicelles is enthalpy-driven, as it is for small unilamellar vesicles and dodecylphosphocholine micelles, while peptide partitioning into a large unilamellar vesicle is entropy-driven. This may mean that the size of lipid membranes is a more important factor for peptide binding than the surface curvature and surface charge density.

PTFE 일렉트롯트를 이용한 초저주파 검출 (Infrasonic Detection using PTFE Electret)

  • 김충혁;김기준;홍진웅;이준웅
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 1989년도 춘계학술대회 논문집
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    • pp.114-117
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    • 1989
  • An infrasonic wide band transducer fabricated by polytetrafluoroethylene(PTFE)is studied experimentally. The sensitivity of the transducer depends largely on the surface charge of the Electret and is typically between-50 and -62[dBV] for a sound-pressure level of 1[ubar]. The sensitivity of the transducer does not decay over periods of the order of years at room temperature. The frequency response is within 1.5[dB] from 1 to 6,000[Hz] and within 12[dB] from 0.05[Hz] to 1[Hz] respectively. The resonance frequency of the element is 510 [Hz]. We conjectures that the element is applicable to accustics, communication system, seismological observation and other similar filed.

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Shaping of piezoelectric polyvinylidene fluoride polymer film for tip position sensing of a cantilever beam

  • 이영섭
    • 센서학회지
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    • 제14권4호
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    • pp.225-230
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    • 2005
  • This paper describes a novel tip position sensor made of a triangularly shaped piezoelectric PVDF (polyvinylidene fluoride) film for a cantilever beam. Due to the boundary condition of the cantilever beam and the spatial sensitivity function of the sensor, the charge output of the sensor is proportional to the tip position of the beam. Experimental results with the PVDF sensor were compared with those using two commercially available position sensors: an inductive sensor and an accelerometer. The resonance frequencies of the test beam, measured using the PVDF sensor, matched well with those measured with the two commercial sensors and the PVDF sensor also showed good coherence over wide frequency range, whereas the inductive sensor became poor above a certain frequency.

Viologen-TCNQ(2:2) LB막의 전기 및 자기적 특성에 관한 연구 (A study on the electrical and magnetic properties of Viologen-TCNQ(2:2) LB films)

  • 이용수;신동명;김태완;강도열
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 1996년도 추계학술대회 논문집
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    • pp.195-198
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    • 1996
  • In conducting systems based on LB films, TCNQ derivatives have been extensively studied as electron acceptor molecules. We have investigated the optical, electrical, and magnetic properties of Viologen-(TCNQ ̄)$_2$LB films. In UV/visible absorption measurements, we have observed TCNQ ̄ peak at 380 nm and dimer peak at 620 nm. The electron spin resonance measurements infer that Viologen-(TCNQ ̄)$_2$LB film exhibits anisotropic properly. In other words, the LB film shows angular dependence. Iodine doping affects the degree of charge transfer and the conductivity of the films. The UV/visible absorption spectra of the LB film doped with I$_2$show peaks at near 400~430 nm and there is no dimer absorption peak. The in-plane electrical conductivity of the undoped film is approximately 4.2$\times$10$^{-6}$ S/cm.

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