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Role of modifiers on the structural, mechanical, optical and radiation protection attributes of Eu3+ incorporated multi constituent glasses

  • Poojha, M.K. Komal;Marimuthu, K.;Teresa, P. Evangelin;Almousa, Nouf;Sayyed, M.I.
    • Nuclear Engineering and Technology
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    • v.54 no.10
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    • pp.3841-3848
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    • 2022
  • The effect of modifiers on the optical features and radiation defying ability of the Eu3+ ions doped multi constituent glasses was examined. XRD has established the amorphous nature of the specimen. The presence of various functional/fundamental groups in the present glasses was analyzed through FTIR spectra. The physical, structural and elastic traits of the glasses were explored. The variation in the structural compactness of the glass structure according to the incorporated modifier was enlightened to describe their suitability for a better shielding media. For the examined glasses, the metallization criterion value varied in the range 0.613-0.692, indicating the non-metallic character of the glasses with possible nonlinear optical applications. The computed elastic moduli expose the Li-containing glass (BTLi:Eu) to be tightly packed and rigid, which is a requirement for a better shielding channel. Furthermore, the optical bandgap and the Urbach energy values are calculated based on the optical absorption spectra. The evaluated bonding parameters revealed the nature of the fabricated glasses covalent. In addition, we investigated the radiation attenuation attributes of the prepared Eu3+ ions doped multi constituent glasses using Phy-X software. We determined the linear attenuation coefficient (LAC) and reported the influence of the five oxides Li2O3, CaO, BaO, SrO, and ZnO on the LAC values. The LAC varied between 0.433 and 0.549 cm-1 at 0.284 MeV. The 39B2O3-25TeO2-15Li2O3-10Na2O-10K2O-1Eu2O3 glass has a much smaller LAC than the other glasses.

Suppression of stray electrons in the negative ion accelerator of CRAFT NNBI test facility

  • Yuwen Yang ;Jianglong Wei ;Junwei Xie ;Yuming Gu;Yahong Xie ;Chundong Hu
    • Nuclear Engineering and Technology
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    • v.55 no.3
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    • pp.939-946
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    • 2023
  • Comprehensive Research Facility for Fusion Technology (CRAFT) is an integration of different demonstrating or testing facilities, which aim to develop the critical technology or composition system towards the fusion reactor. Due to the importance and challenge of the negative ion based neutral beam injection (NNBI), a NNBI test facility is included in the framework of CRAFT. The initial object of CRAFT NNBI test facility is to obtain a H0 beam power of 2 MW at the energy of 200-400 keV for the pulse duration of 100 s. Inside the negative ion accelerator of NNBI system, the interactions of the negative ions with the background gas and electrodes can generate abundant stray electrons. The stray electrons can be further accelerated and dumped on the electrodes or eject from the accelerator. The stray electrons, including the ejecting electrons, cause the unwanted particle and heat flux onto the electrodes and the inner components of beamline (especially the temperature sensitive cryopump). The suppression of the stray electrons from the CRAFT accelerator is carried out via a series of design and simulation works. The paper focuses the influence of different magnetic field configurations on the stray electrons and the character of the ejecting electrons.

Characteristics of Water Budget on Throughfall and Stemflow in Pinus densiflora and Quercus acutissima (소나무와 상수리나무림의 임내우 물수지 특성)

  • 이헌호;박재철
    • Korean Journal of Environment and Ecology
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    • v.12 no.3
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    • pp.259-270
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    • 1998
  • This study, as an essential research to develope a mountainous runoff model, was conducted to clarify the hydrologic character and water budget equation of Pinus densiflora and Quercus acutissima. Net rainfall quantity division for two species was investigated at Youngsung experiment forest and Yeungnam University for 30 months(Sep. 1995-Jun. 1998). The results were summarized as follows; 1. The percentages of throughfall and stemflow to gross precipitation are 73.8% and 0.8% in the Pinus densiflora, and 76.9% and 3.8% in the Quercus acutissima, respectively 2. In the Pinus densiflora, regression fomula of stemflow, throughfall, and net rainfall to gross precipitation are S$_{f}$ = 0.01GP-2.05 ($r^2$=0.54) T$_{f}$ = 0.79Gp - 26.04 ($r^2$=0.92), N$_{r}$ = 0.81Gp - 28.09 ($r^2$=0.92). Stemflow and throughfall increased in direct proportion to gross precipitation. 3. In the Quercus acutissima, regression fomula of stemflow, throughfall, and net rainfall to gross precipitation are S$_{f}$ = 0.03Gp + 12.25 ($r^2$=0.74), T$_{f}$ = 0.78Gp + 19.75 ($r^2$=0.96), N$_{r}$ = 0.81Gp + 3199 ($r^2$=0.96), respectively. Comparing with two species, gross precipitation has a much larger effect on the stemflow and throughfall of Quercus acutissima than those of Pinus densiflora. 4. In the analysis of intercorrelation between stemflow and throughfall of each species and crown area(CA), diameter at breast height(DBH), and gross precipitation(Gp), correlation coefficient was higher by following order at each species; Gp>CA>DBH on stemflow of Pinus densinora, Gp>DBH>CA on stemflow of Quercus acutissima, and Gp>CA>DBH on throughfall of Pinus densiflora and Quercus acutissima.ssima.

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Theoretical Study on Antitumor Activity of trans-Platinum(Ⅱ) Complexes with Planar Ligands (Ⅱ) (평면형리간드가 배위된 trans-백금(Ⅱ) 착물의 항암활성에 관한 이론적 연구 (제2보))

  • Song, Young Dae;Kim, Jung Sung;Park, Byung Kak
    • Journal of the Korean Chemical Society
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    • v.41 no.6
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    • pp.277-283
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    • 1997
  • Platinum(II) complexes(where, $[Pt(L)_2X_2]$; L=isoxazole(isox), 3,5-dimethylisoxazole(3,5-diMeisox), 3-methyl,5-phenylisoxazole(3-Me,5-Phisox), and 4-amino-3,5-dimethylisoxazole(4-ADI); X=Cl, Br) with planar ligands are investigated on antitumor activity by MM2 and EHMO calculations. It was found that, the net atomic charges of the halogen atoms in all of cis-, trans-isomers are greater than that of the nitrogen with planar form, indicating that ionic character of Pt-X bond is greater than that of Pt-N. Also, the ${\sigma}MO$ energy level($E{\sigma}_{(Pt-X)}$) of the interaction between $d_{x2-y2}$ orbital of Pt atom and $p_x$ orbital of X found to be higher than that of between $d_{x2-y2}$ orbital of Pt atom and $p_x$ orbital of N about all the complexes. It is found that bond strength of between Pt and X atom is weaker than that of between Pt and N atom. The ${\sigma}MO$ energy level($E{\sigma}_{(Pt-X)}$) of trans- complexes found to be higher than that of cis- complexes, as a result of bond strength of Pt-X in cis- and trans-complexes, for all the complexes. The degree of dissociation of X atom in Pt-X bond for trans-complexes are related to antitumor activity and the logIA value of inhibitory activity coefficient(IA).

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Evaluation of Ground Properties for Marine Ground in Pusan Area using Elastometer-200 Type (Elastometer-200을 이용한 부산지역 해저지반의 지반특성치 평가)

  • 김동철;최용규
    • Journal of the Korean Geotechnical Society
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    • v.16 no.4
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    • pp.83-94
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    • 2000
  • Applicability of PMT in domestic area, test procedure, and methods determining the shear strength parameters $(cu,\phi)$and deformation character (E) using PMT results were studied. At six test boreholes of three construction sites in Pusan, PMT using Elastometer-200 type was performed. The problems occurring during tests were investigated and the test results were analysed.In-situ total horizontal stress could be obtained by observation from pressuremeter curve and limit pressure, p could be determined by $p-log(\Deltav/v)$ method. Shear strength parameters$(cu,\phi)$ and deformation modulus(G, E) could be determined from the PMT results. But effective friction angle and undrained cohesion determined from PMT results were greater than those obtained from laboratory test.Using PMT results, marine soil in Pusan could be classified approximately. Net limite pressure values were in the range of 6.4~22.5 $kg/cm^2$, in clay, 2.2~30.$kg/cm^2$, in sand, 13.0~58.0$kg/cm^2$, in weathered soil and 47.0~190.0 $kg/cm^2$, in weathered rock. Also, Em/p values were in the range of 2.4~7.0 in clay, 2.6~12.1 in sand, 6.8~17.1 in weathered soil and 7.2~29.6 in weathered rock.

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Syntaxonomy and Synecology of the Robinia pseudoacacia Forests (아까시나무림의 군락분류와 군락생태)

  • Cho, Kwang-Jin;Kim, Jong-Won
    • The Korean Journal of Ecology
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    • v.28 no.1
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    • pp.15-23
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    • 2005
  • The black locust (Robinia pseudoacacia L.) forests were studied by a phytosociological approach. Particular attention was given to characterize the vegetation classification, distribution pattern, and ecological flora of the syntaxa classified. A total of 38 releves were analyzed by using Correlation coefficient, UPGMA as the clustering method, and Principal Coordinates Analysis for ordination. Ecological flora analyzed by plant character sets such as scrambler, annual and biennial plants, forest elements, and actual urbanization index. The analyzed data are based on site-releve matrix with relative net contribution degree (r-NCD) of species. A total of 77 families, 193 genera and 323 species of vascular plants are recorded. Camellino-Robinietum pseudoacaciae ass. nov. and Phragmites-Robinia pseudoacacia community were described. Main cluster and ordination could be separated: 1) urban type, 2) rural type, 3) riparian type, and 4) combined type. It is defined that the Robinietum is a representative unit on the black locust afforestation, Phragmites-Robinia community on the lentic zone in the river ecosystem, and Cameliino-Robinietum ailanthetosum altissimae as an urban forest type. The Robinietum was considered as a perpetual community.

Spawning Character and Early Life History of the Endangered Korean Dwarf Loach, Kichulchoia brevifasciata (Teleostei: Cobitidae) (멸종위기종 좀수수치 Kichulchoia brevifasciata의 산란기 특징 및 초기생활사)

  • Ko, Myeong-Hun;Bang, In-Chul
    • Korean Journal of Ichthyology
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    • v.26 no.2
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    • pp.89-98
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    • 2014
  • Eggs development and early life history of the endangered Korean dwarf loach, Kichulchoia brevifasciata (Teleostei: Cobitidae) was investigated to provide basic information regarding biological characteristics and restoration. Adult fish specimens were sampled using a spoon net at Geurnsan-myeon, Goheung-gun, Jeollanam-do, Korea from June to July 2011. Since, spawning characteristics were analyzed, and females were induced to spawn by injecting Ovaprim (0.5 mL/kg) and their eggs were artificially fertilized with sperms by the dry method in the laboratory. Total length of mature female were 46~76 mm with GSI $9.6{\pm}3.77%$, and total length of mature male was 42~52 mm with GSI $3.5{\pm}1.04%$. Sex ratio (♂/♀) was 0.10, and there were no secondary sexual characteristics. The number of mature eggs was averaged $60{\pm}28.7$ per female. The lemon yellow eggs were slightly adhesive $1.46{\pm}0.07mm$ in diameter. The embryo hatched approximately 66 h after fertilization at $25^{\circ}C$, and the hatched larvae were averaged $5.5{\pm}0.07mm$ in total length (TL). At 6 days after hatching, the larvae averaged $9.0{\pm}0.29mm$(TL) and their yolk sac was completely absorbed. At 17 days after hatching, they entered the juvenile stage and reached $12.6{\pm}0.24mm$ (TL). At 80 days after hatching, the band patterns and external form of the juveniles were similar to those of adults, and they averaged $33.0{\pm}2.19mm$(TL).

Molecular Orbital Interpretation on Antitumor Activity of trans-Palladium(Ⅱ) Complexes by Geometrical Structure of Ligands (Ⅰ) (리간드의 기하학적 구조에 의한 trans-팔라듐(Ⅱ) 착물의 항암활성에 관한 분자궤도함수론적 해석 (Ⅰ))

  • Song, Young Dae;Park, Byung Kak
    • Journal of the Korean Chemical Society
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    • v.39 no.4
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    • pp.244-251
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    • 1995
  • The palladium(II) complexes(where, [Pd(L)2X2], L=isoxazole(isox), 3,5-dimethylisoxazole(3,5-diMeisox), 3-methyl, 5-phenylisoxazole(3-Me, 5-Phisox), and 4-amino, 3,5-dimethylisoxazole(4-ADI); X=Cl, Br] with isoxazole and its derivatives are investigated on antitumor activity by EHMO calculation. It is found that the net charge of the two halogen atoms in trans-isomers are greater than those in cis-ones, indicating that ionic character of Pd-X bond in trans-isomers is greater than that of cis-ones, and so dissociation of Cl- ion is easier than that of Br- ion in aqueous solution in body. Furthermore, it is found that the ${\sigma}MO$ energy of Pd(dx2-y2)-X(px) bond $(E{\sigma}(Pd-X))$ is higher than that of Pd(dx2-y2)-N(px) bond $(E{\sigma}(Pd-N))$ without exception, about all the complexes, and also the $E{\sigma}(Pd-X)$ of trans-isomers is higher than that of cis-isomers. From the above facts, the degree of dissociation in Pd-X bond would be related to antitumor activity. In fact, the linear equation of correlation coefficient 0.96 is fairly established between ${\Delta}E{\sigma}(N-X)(E\sigma(Pd-N)-E{\sigma}(Pd-X))$ and inhibitory activity coefficient, logIA.

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A Phytosociological Comparison of Forest Vegetation between Igneous and Sedimentary Rock Areas in Kyungpook Province, South Korea (경북 일원의 화성암 산지와 퇴적암 산지의 삼림식생에 대한 식생학적 비교)

  • 제갈재철;김종원
    • The Korean Journal of Ecology
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    • v.26 no.1
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    • pp.23-28
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    • 2003
  • In order to identify plant species and communities characteristic of lithospheric condition, forest vegetations of igneous(mainly granite) and sedimentary(mainly sandstone) areas in Kyungpook province were compared. We collected 108 phytosociological releves from the older forests over 20 years old. 444 vascular plant species and 25 plant communities were identified. Results of Principal Coordinates Analysis (PCA) indicated that lithospheric conditions and human impacts were the most important factors related to the plant community diversity and species richness. In the igneous rock areas net contribution degree (rNCD) of 139 species including Quercus serrata, Q. mongolica, Lindera obtusiloba and Fraxinus sieboldiana increased and those of Carpinus laxiflora and Styrax japonica decreased. In the sedimentary rock areas, to a lesser extent, 96 species including Q. aliena, Zanthoxylum schinifolium, Potentilla fragarioides var. major, Rhus javanica, and Plectranthus japonicus increased, whereas character species of Lindero-Quercion mongolicae such as Q. mongolica, Q. serrata, Rhododendron schlippenbachii, Acer mono and Styrax obassia decreased, and particularily the species Sasa borealis, the Alangium-Zelkova serrata community and the Philadelphus-Fraxinus mandshurica community were absent. The vegetation of sedimentary rock area is characterized as a regional type shaping dwarf pine forests and sparse and light broad-leaved forests.

Morphological and Physiological Characteristics of Acclimated Liriodendron tulipifera Tree Produced by Several Types of In Vitro Germination Culture (백합나무 체세포배 기내발아 방식에 따른 순화묘의 형태적 및 생리적 특성)

  • An, Chan Hoon;Yi, Jae Seon;Moon, Heung Kyu;Kim, Yong Wook
    • Journal of Korean Society of Forest Science
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    • v.101 no.1
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    • pp.158-162
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    • 2012
  • The acclimatization of in vitro propagated plants is an important step to produce vigorous plants for clonal forestry and in vitro micro-environment may affect the growth in ex vitro condition. To monitor in vitro environmental effects on the growth in ex vitro condition, several culture systems such semi-solid medium(SS), temporary immersion bioreactor(TIB) and continuous immersion bioreactor(CIB) culture types were tested to compare for the growth of acclimated plants of Liriodendron tulipifera. Results suggested that morphological characters, stomatal conductance, evapotranspiration and chlorophyll contents of acclimated plants were affected by the different of in vitro culture conditions. CIB type of culture was resulted to the lowest value in the biomass of acclimated plants. Net photosynthsis rate of CIB was the same level as those of SS and TIB. However, stomatal conductance, evapotranspiration and $CO_2$ partial pressure in the intercellular air space were lower than those of SS and TIB. The amounts of chlorophyll a, b and carotenoids were also lower than those of the other two culture systems. TIB, showing a little lower or higher value than SS in many growth character, is recommended rather than CIB to produce healthy yellow poplar plants in ex situ condition.