• 제목/요약/키워드: Changes of state of water

검색결과 362건 처리시간 0.023초

地下터널 굴착作業場內 作業環境豫測 (Prediction of the Environmental Conditions in Underground Tunnelling Spaces)

  • 박희봉
    • 터널과지하공간
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    • 제2권1호
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    • pp.116-122
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    • 1992
  • A comprehensive, nonsteady state, computer simulation program for the environmental conditions in advancing tunnels (the HEADSIM simulation program) is constructed and successfully validated with heat balance amongst all heat sources, and with mass conservation amongst various airflows including the leakage air from ducts, under timedependent variations of inlet air conditions. which include sudden, diurnal and seasonal changes. Heat conduction in the wall strata and face strata is simulated with most complicated boundary conditions using the finite difference method, and the climatic conditions in roadway sections which contain air ducts, booster fan, spray cooler, compressed air pipes, cold water pipes, return water pipes, machinery and broken rock are simulated taking into account the variations of face operation and the heat storage mechanism in the strata. The limitations of simulation time steps and roadway section lengths are defined according to the stability criteria satisfying the principles of thermodynamics. Variations of heat transfer coefficients, which are newly set, and those of wetness factors are taken into account according to the variations of other parameters and the stepwise advance of the face. Newly-derived formulae are used for computing the air duct leakage and the pressure inside of the duct. A new concept of an 'imaginary duct' is introduced to simulate the climatic conditions in tunnels during holiday periods, which directly affect conditions on subsequent working days under the consideration of natural convection. A subsidiary program (the WALLSIM simulation program) is made to compute the dimensionless tunnel surface temperatures and to compare the results with those from analytical approaches, and to demonstrate the stability, convergence and accuracy of the strata heat conduction simulation, adopting the finite difference method. The WALLSIM also has wide applications, including those for the computation of age coefficients.

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(Polymer/18-Crown-6)복합박막 제조용액의 수면전개 특성 (The Spreading Characteristics of the (Polymer/18-Crown-6) Composite Solution for Water Cast-Membranes)

  • 남석태;최호상;최성부;김병식
    • 멤브레인
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    • 제6권4호
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    • pp.265-272
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    • 1996
  • 금속이온 분리를 위한 운반체 지지형 (고분자/운반체) 복합막을 수면전개법에 의하여 제조하였다. 이들 막의 형상은 전개용액의 물성에 의하여 영향을 받는다. (고분자/18-crown-6) 복합용액의 표면장력은 18-crown-6의 농도가 증가함에 따라 감소하는 경향을 나타내며, 고분자에 따른 용액의 표면장력은 PVC>PS>CA 순서로 감소하였다. 점도는 18-crown-6의 농도가 증가함에 따라 PVC계와 PS계 용액은 큰 변화가 없으나 CA계 용액은 감소하는 경향을 나타내었다. 18-crown-6 환형고리분자는 고분자쇄 사이에서 전기적인 완충역할을 하여 고분자쇄간의 분자간력을 약화시켜줌으로써 복합 용액의 전개성을 증가시켰다. 복합박막의 표면형상은 단일박막보다 균일하였으며, 18-crown-6가 증가함에 따라 전후면은 모두 균일한 구조극 나타내었다.

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한강 수계 주요 댐호에서의 동물플랑크톤 군집 구조와 천이 (Structure and Succession of Zooplankton Community in Several Artificial Lakes in the Han River System)

  • 유경아;박혜경;공동수;황순진
    • 한국물환경학회지
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    • 제26권5호
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    • pp.850-859
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    • 2010
  • Structure and succession of zooplankton community studied by hydraulic and ecological characteristics targeting the five lakes in the Han river system from March to December 2008. Results separated by river-type lake and lake-type lake depending on the type of hydraulic, Paldang lake and Cheongpyeong lake were river-type lake, while Chungju lake, Hoengseong lake and Doam lake was lake-type lake. The Paldang lake was a eutrophic lake, zooplankton community density and species number were the most among the five lakes. Relative dominance of the rotifera was the largest and the yearly first dominant species was a small cladocera Bosmina longirostris. The Cheongpyeong lake was a mesotrophic-eutrophic lake, hydraulic characteristics and zooplankton community changes were similar the Paldang lake. Relative dominance of the cladocera was the largest and the yearly first dominant species was a small cladocera Bosmina longirostris. The Chungju lake was a oligotrophic-mesotrophic lake, zooplankton community density was the least among the five lakes. Relative dominance of the copepoda was the largest and the yearly first dominant species was a large cladocera Daphnia galeata. The Hoengseong lake was a oligotrophic-mesotrophic lake, relative dominance of the rotifera was the largest and the yearly first dominant species was a small cladocera Bosmina longirostris. The Doam lake was a mesotrophic-eutrophic lake, zooplankton community density showed dramatic difference at the investigation time. Relative dominance of the rotifera was the largest and the yearly first dominant species was the copepoda Nauplius.

자료기간 증가에 따른 확률강우량의 거동특성 분석 (Analysis of the Changes in Rainfall Quantile according to the Increase of Data Period)

  • 안재현;김태웅;유철상;운용남
    • 한국수자원학회논문집
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    • 제33권5호
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    • pp.569-580
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    • 2000
  • 지구온난화와 같은 기후변화로 인해 최근에 한반도에서 급증하고 있는 집중호우의 영향을 알아보기 위해서 12개 우량관측소 지점의 연 최대 강우량 계열에 대한 빈도해석을 실시하였다. 확률강우량의 시간적인 변화를 알아보기 위해 자료기간을 30년으로 한 후 1년씩 이동하면서 l00년 빈도 확률강우량을 산정하였고, 80% 이상의 지점에서 최근의 집중호우가 과거에 비해 상대적으로 증가하고 있음을 확인하였다. 또한 자료기간을 1년씩 누가하면서 100년 일최대 확률강우량을 산정하여 집중호우가 발생했던 해의 연 최대 강우량 포함에 따른 확률강우량의 증가 경향을 파악하였다. 이를 통해 수공고조물의 설계를 위한 빈도해석시 자료기간 산정의 중요성과 기존 하천시스템의 홍수방어능력에 대한 재평가 필요성을 확인할 수 있었다.

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이분자막 형성능을 가지는 인산형 양친매성 화합물의 단분자막 특성 (Monolayer Characteristics of Bilayer Forming Phosphate Amphiphiles)

  • 김종목
    • 멤브레인
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    • 제5권2호
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    • pp.89-96
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    • 1995
  • Azobenzene기를 가지는 인산형 양친매성 화합물의 기/액 계면에 있어서으 단분자막 거동이 $\pi-A$ 곡선 및 표면흡수스펙트라로 검토되었다. 분자간의 강한 수소결합력을 가지는 이 화합물들은 수면에 전개 후 즉시 결정화하여 단분자막 domain들을 형성한 회합체 흡수스펙트라를 나타내었다. 그러나 subphase의 조건(분자량이 큰 유가염의 첨가 및 pH의 상승)을 변화시킴에 의해 결정 domain 형성을 제어하는 것이 가능하였다. 한편, 금속이온 첨가는 인산령 양친매성 단분자막의 분재배향상태를 변화시켰다. 금속이온의 전하가 높을수록 ($1\leq2$ < 3 < 4 가), azobenzene기를 가지는 양친매성 화합물의 분자상태가 tilt된 배향성에 기인하는 장파장으로 이동한 흡수극대를 나타내었다. 이것은 서로 다른 전하를 가진 금속이온을 흡착시킴에 의해 단분자막의 분자배향성을 변화시켜, 단분자막의 집합상태 제어 가능성을 시사한다.

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UASB 공정에 의한 당밀폐수의 최적처리 방안 (Optimal Treatment of Molasses Wastewater Using UASB Process)

  • 허관용;정의근;정윤진;유상근
    • 상하수도학회지
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    • 제11권2호
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    • pp.112-127
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    • 1997
  • The purpose of this study is to get optimum operating factors of Upflow Anaerobic Sludge Blanket (UASB) reactor by introducing methods that make it to reduce inhibition possible in each process wastewater treatment. The used substrates, concentrated corn starch liquid (CSL) wastewater, modified starch, filtering and decoloring wastewater, ion refining wastewater, and mixed wastewater including modified starch and not including modified starch, are generated from molasses process. The seeding sludge is the digested sludge that had been applied to molasses wastewater. Batch test to reduce the inhibition factors that might be existed in each wastewater was examined. Based on the this test, the optimum operating factors according to alkalinity and pH variation was studied through the continuous test using three 5.5 L UASB reactor. The first reactor added $NaHCO_3$ to control alkalinity. The hydraulic retention time (HRT) reduced to 8 hours and the organic loading rate increased gradually. The second reactor changed the pH of influent from 7.0 to 6.0 using NaOH. The third reactor was operated without changes to compare the above two reactors. As the result, the inhibition in concentrated CSL wastewater was removed by adding iron (II). When trace metals were added to mixed wastewater not including modified starch, the digestability by gas production rate increased to more fifty percentage than mixed wastewater that was not adding the trace metals. The reason that the inhibition did not decreased in spite of adding trace metals and nutrients was influenced by high concentration generated during the acid fermentation. The UASB reactors using the mixed wastewater with the most effective performance were operated as 500 mg/L as $CaCO_3$ alkalinity and 6.0 pH at steady state, and at this time, the gas production rates were 283 and 311mL gas/g $COD_{added}$. The COD removal rates were 84.7 and 86.3%, respectively.

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소아안신탕(小兒安神湯)이 STRESS를 유발한 흰쥐의 적출심장(摘出心臟)에 미치는 영향 (Effects of Soaansintang(SOAT) on the hemodynamics and electrocardiogram of isolated rat hearts induced by electrical stimulation)

  • 이승준;이진용;김덕곤
    • 대한한방소아과학회지
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    • 제14권2호
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    • pp.1-32
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    • 2000
  • It has long been known that SOAT is effective for sudden palpitation occurring unexpectedly in Oriental Medicine. However, effect of SOAT on the isolated heart has not been studied yet. The purpose of this study is to investigate the effect of SOAT on hemodynamics and ECG of isolated rat hearts induced by electrical stimulation using Langendorff perfusion apparatus for nonworking heart. SOAT extract was manufactured by water-alcohol precipitated method. Sprague-Dawley rats weighting $120{\sim}150g$ were used for the experiments, Subject animals were divided into four groups, which are consisted of 1) control(Group orally administered by normal saline 1ml for 14days), 2) sample A(Group orally administered by SOAT extract 1ml for 14days), 3) sample C(Group injected by SOAT extract 0.5ml after stimulation, 4) sample C(Group injected by SOAT extract 1ml after stimulation. To evluate the effects of SOAT on hemodynamics and ECG of isolated rat heart induced by stimulation, heart rate, left ventricular pressure, systolic power, diastolic power, coronary artery perfusion volume and ECG were measured using Langendorff apparatus in both stimulation mode(5 volts, 450 beats/min) and arrythmic mode(5 volts, 420 beats/min including 60 beats/min) The results obtained are as follows : 1. After receiving stressful electrical stimuli, isolated heart showed the heart rate, left ventricular pressure, systolic power, diastolic power, coronary artery perfusion volume were all decreased temporarily, but perfusion continued longer recovery to the control state appeared. However, the coronary artery perfusion volume diminished continuously. 2. The heart rates did not change significantly with both stimulation mode and arrhythmic mode, among experimental groups. 3. The left ventricular pressure showed with both stimulation mode and arrhythmic mode, the significant changes(p<0.05) especially in the injection sample group. In case of stimulation mode, low concentration injection group(0.5ml) was more significantly increased rather than high concentration group(1ml) and in case of arrhythmic mode, high density group(1ml) was so increased than the other(0.5ml). 4. For the systolic power and diastolic power, no significant changes were noticed in the stimulation mode, but in the arrhythmic mode of injection sample groups, significant change(p<0.05) was noticed in both systolic power and diastolic power. Specially the high concentration group(1ml) showed more significant increase than the low concentration group. 5. For the coronary artery perfusion volume, no significant change difference among sample groups was observed in both the stimulation mode and the arrhythmic mode. 6. For the ECG recordings, arrhythmia was induced by electrical stimulus of arrythmia mode and after the stimulus was removed, irregular wave appeared temporarily, but as perpusion continued, recovery to the control state was abtained like the stimulation mode. According to the above results, SOAT significantly changed the hemodynamic data from the electrically stressed, isolated hearts of connected Langendorff perfusion apparatus and we propose SOAT has the direct effects on the muscular function of heart.

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동결토의 압축강도에 관한 실험적 연구 (Experimental Studies on the Compressive Strength of the Frozen Soils)

  • 유능환;최중돈;유영선;조영택
    • 한국농공학회지
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    • 제35권4호
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    • pp.55-66
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    • 1993
  • Upon freezing a soil swells due to phase change and its compression stress increase a lot. As the soil undergo thawing, however, it becomes a soft soil layer because the 'soil changes from a solid state to a plastic state. These changes are largely dependent on freezing temperature and repeated freezing-thawing cycle as well as the density of the soil and applied loading condition. This study was initiated to describe the effect of the freezing temperature and repeated freezing-thawing cycle on the unconfined compressive strength. Soil samples were collected at about 20 sites where soil structures were installed in Kangwon provincial area and necessary laboratory tests were conducted. The results could be used to help manage effectively the field structures and can be used as a basic data for designing and constructing new projects in the future. The results were as follows ; 1. Unconfined compressive strength decreased as the number of freezing and thawing cycle went up. But the strength increased as compression speed, water content and temperature decreased. The largest effect on the strength was observed at the first freezing and thawing cycle. 2. Compression strain went up with the increase of deformation speed, and was largely influenced by the number of the freezing-thawing cycle. 3. Secant modulus was responded sensitivefy to the material of the loading plates, increased with decrease of temperature down to - -10$^{\circ}$C, but was nearly constant below the temperature. Thixotropic ratio characteristic became large as compression strain got smaller and was significantly larger in the controlled soil than in the soil treated with freezing and thawing processes 4. Vertical compression strength of ice crystal(development direction) was 3 to 4 times larger than that of perpendicular to the crystal. The vertical compression strength was agreed well with Clausius-Clapeyrons equation when temperature were between 0 to 5C$^{\circ}$, but the strength below - 5$^{\circ}$C were different from the equation and showed a strong dependency on temperature and deformation speed. When the skew was less then 20 degrees, the vertical compression strength was gradually decreased but when the skew was higher than that, the strength became nearly constant. Almost all samples showed ductile failure. As considered above, strength reduction of the soil due to cyclic freezing-thawing prosses must be considered when trenching and cutting the soil to construct soil structures if the soil is likely subject to the processes. Especially, if a soil no freezing-thawing history, cares for the strength reduction must be given before any design or construction works begin. It is suggested that special design and construction techniques for the strength reduction be developed.

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Biological Inspiration toward Artificial Photostystem

  • Park, Jimin;Lee, Jung-Ho;Park, Yong-Sun;Jin, Kyoungsuk;Nam, Ki Tae
    • 한국진공학회:학술대회논문집
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    • 한국진공학회 2013년도 제45회 하계 정기학술대회 초록집
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    • pp.91-91
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    • 2013
  • Imagine a world where we could biomanufacture hybrid nanomaterials having atomic-scale resolution over functionality and architecture. Toward this vision, a fundamental challenge in materials science is how to design and synthesize protein-like material that can be fully self-assembled and exhibit information-specific process. In an ongoing effort to extend the fundamental understanding of protein structure to non-natural systems, we have designed a class of short peptides to fold like proteins and assemble into defined nanostructures. In this talk, I will talk about new strategies to drive the self-assembled structures designing sequence of peptide. I will also discuss about the specific interaction between proteins and inorganics that can be used for the development of new hybrid solar energy devices. Splitting water into hydrogen and oxygen is one of the promising pathways for solar to energy convertsion and storage system. The oxygen evolution reaction (OER) has been regarded as a major bottleneck in the overall water splitting process due to the slow transfer rate of four electrons and the high activation energy barrier for O-O bond formation. In nature, there is a water oxidation complex (WOC) in photosystem II (PSII) comprised of the earthabundant elements Mn and Ca. The WOC in photosystem II, in the form of a cubical CaMn4O5 cluster, efficiently catalyzes water oxidation under neutral conditions with extremely low overpotential (~160 mV) and a high TOF number. The cluster is stabilized by a surrounding redox-active peptide ligand, and undergo successive changes in oxidation state by PCET (proton-coupled electron transfer) reaction with the peptide ligand. It is fundamental challenge to achieve a level of structural complexity and functionality that rivals that seen in the cubane Mn4CaO5 cluster and surrounding peptide in nature. In this presentation, I will present a new strategy to mimic the natural photosystem. The approach is based on the atomically defined assembly based on the short redox-active peptide sequences. Additionally, I will show a newly identified manganese based compound that is very close to manganese clusters in photosystem II.

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미국 브라운필드 관리 프로그램과 정책의 시기별 특성과 함의 (Periodic Characteristics and Implications of Programs and Policies for Brownfield Management in the U.S.A.)

  • 김유진;패트릭 밀러
    • 한국조경학회지
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    • 제43권1호
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    • pp.96-107
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    • 2015
  • 하수처리시설, 군부대 등의 산업이전적지의 공원화 계획이 늘어나면서 브라운필드 재개발은 조경계획 및 디자인에서 하나의 분야로 자리 잡았다. 특히, 주변 커뮤니티 활성화, 지가 상승 등 동반이익에 대한 기대가 높아지면서 선별된 부지들의 종합적 계획 및 관리에 대한 필요성이 인식되고 있다. 본 연구는 미국 브라운 필드 관리 정책의 변화양상을 살펴 본 기초적인 사례연구로서, 1980년 수퍼펀드 프로그램 도입 이후, 약 30 여 년간 확장하여 온 브라운필드 프로그램과 정책의 시기별 특성을 파악하는 것을 주 목적으로 한다. 연구 방법으로 서술적, 해석적 방법에 기반한 미국 환경부 산하 기관들의 웹문서 및 관련 문헌 분석을 통해 정책의 특성을 시계열적으로 분석하였다. 본 연구의 결과, 주요한 변화를 기점으로 하여, 환경규제시기, 오염정화 및 재개발 촉진시기, 종합적 계획시기의 세 가지 시기로 구분되었고, 주요 특성은 규제 완화 및 재조정, 지원 프로그램의 다양화, 하향식과 상향식 방식의 조화, 데이터베이스 구축의 네 가지 측면으로 요약되었다. 본 연구는 대상지 선별기준, 이해 당사자 파악 및 책임분쟁 조정, 오염도 평가비용 및 처리 등 브라운필드만이 가진 공통 문제들이 어떻게 다뤄져 왔는지 선례를 살펴봄으로써, 향후 한국의 체계적 브라운 필드 관리 및 계획에 시사점을 제공하는 것에 의의를 두고 있다.