• Title/Summary/Keyword: Change of solvent

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Morphological Analysis of Inkjet Printed Patterns on characteristics of Inks and Substrates (잉크 및 기판 특성 변화에 따른 잉크젯 프린팅 패턴의 형상 분석)

  • Shin, Kwon-Yong;Kim, Myong-Ki;Hwang, Jun-Young;Kang, Heui-Seok;Kang, Kyung-Tae;Oh, Je-Hoon;Lee, Sang-Ho
    • Proceedings of the KIEE Conference
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    • 2009.07a
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    • pp.1523_1524
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    • 2009
  • Inkjet technology has various merits as a direct patterning process in plenty of industrial applications, but critical issue such as coffee ring effect should be overcome for the application to an industrial manufacturing process. In this paper, we introduced the morphological analysis of inkjet printed pattrerns on the characristics of inks and substrates. In case of Triethlene Glycol Monoethly Ether based ink, the coffee ring effect was observed. However, an ethanol based ink showed the round shaped morphology under the same printing conditions and surface conditions. An ink consisted of the solvent with high boiling point results in coffee ring effect. This experimental results showed that the morphological change of the printed droplet is caused by the main solvent of ink, rather than the metal content, viscosity and surface tension.

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Mechanical Degradation of Polymers in Dilute Solution (III). The Influence of the Mixed Solvents (稀薄溶液에서의 Polymer의 機械的 切斷 (제3보). 混合溶媒의 영향)

  • Yeong Moo Won
    • Journal of the Korean Chemical Society
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    • v.17 no.3
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    • pp.207-212
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    • 1973
  • The mechanical degradation of poly (-vinylacetate) in several mixed solvents (dioxane-n-butanol, dioxane-sec-butanol, dioxane-ethyleneglycol, dioxane-kerosene.) was studied using the capillary flow method. The velocity constant of scission reaction (k) and the limited degree of polymerization (g) were compared at the same value of [${\eta}$], which is considered as the parameter of molecular dimension of polymers in solution. As result, (k) did not change much, even if the species and the volume fraction of poor (non-) solvents changed, while the value of (g) changed according to the species of poor solvents and the value of [${\eta}$]. From the facts described above, It follows that the limited degree of polymerization (g) were affected by the composition and distribution of mixed solvent molecules around the polymer chain, and the value of $\alpha$ (at [${\eta}$] = $KM^a$) in the polymer solution.

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Change in Molecular Weight Distribution of Diffusible Species on RTV Silicone Rubber Using Solvent Extraction and Recovery Rate of Hydrophobicity (용매추출에 의한 옥외용 RTV 실리콘고무의 분자량 변화와 발수성 회복속도)

  • Lee, Chang-R.;Kim, Dong-H.;Choi, Yong-C.;Kim, Jong-G.;Homma, H.;Izumi, K.
    • Proceedings of the KIEE Conference
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    • 2001.07c
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    • pp.1337-1339
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    • 2001
  • We have investigated the relation between the molecular weight distribution (MWD) of diffusible species and the recovery rate of hydrophobicity of room-temperature vulcanizing (RTV) silicone rubber (SIR) using solvent extraction at various temperatures. It was observed that the extract had a MWD ranging from a few hundreds g/mol to hundreds of thousands g/mol. By measuring the migration of siloxane to the extracted SIR surface through a thin carbon coating, the aspect of migration of diffusible species was observed as a real time plot, and the time constant of the migration was also calculated. According to the time dependence of IR-absorbance, the time constant was increased with the increase of MW of the extracts.

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Micro-structural Evolutions of Polyimide Composite Films with Graphenes (그라핀을 포함하는 폴리이미드 멤브레인의 미세조직구조 변화)

  • Shim, Seong Eun;Kim, Jungsoo;Nam, Dae-Geun;Oh, Weontea
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.27 no.1
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    • pp.56-60
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    • 2014
  • The polyimide composite membranes were prepared with polyimide composite solutions including graphenes by using the phase inversion method. The morphologies of these membranes were significantly changed according to the graphene loadings in composite solutions and the solvent systems of the composite solutions. The finger-like macro-voids were formed in the hollow fiber membranes which were prepared in the NMP solvent system with a small amount of ethanol. As increasing the content of the viscous alcohols such as glycerol or 1,3-propanediol in the composite solution, however, the morphologies of the hollow fiber membranes were changed to sponge-like types. In case of flat membranes, the increase of graphene content in polyimide composites causes that their membranes change from the finger-like macro-porous to sponge-like morphologies.

Surface Free Energy Change of Polypropylene Film treated by Atmospheric Pressure Plasma (대기압 플라즈마로 처리된 폴리프로필렌 필름의 표면 자유에너지 변화)

  • Kwon, Oh June;Tang, Shen;Lu, Na;Choi, Ho Suk
    • Journal of Adhesion and Interface
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    • v.4 no.4
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    • pp.1-6
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    • 2003
  • After atmospheric pressure plasma treatment of polypropylene(PP) film surface, we measured the contact angle of the surface by using polar solvent (water) and non-polar solvent (diiodomethane). We also calculated the surface free energy of PP film by using the measured values of contact angles. And then we analyzed contact angle and surface free energy with changing the condition of atmospheric pressure plasma treatment. Upon each condition of atmospheric plasma treatment, contact angle and surface free energy showed an optimum value or leveled off.

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Technology for the Preparation of Ash-free Coal from Low Rank Coal(LRC) (저등급 석탄으로부터 초청정석탄 제조 기술)

  • Lee, Sihyun;Kim, Sangdo
    • Korean Chemical Engineering Research
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    • v.46 no.3
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    • pp.443-450
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    • 2008
  • Efficient use of low rank coals (LRC) have been investigated as a method to cope with recent high oil price. Among the coals used in industry, lignite and sub-bituminous coals are belong to the LRC, and have abundant deposit and are distributed worldwide, but high moisture contents and self ignition properties inhibits their utilization. In this paper, chemical coal cleaning to produce ash-free coal from LRC has been investigated. Two technologies, that is, UCC(Ultra Clean Coal) process removing ash from coal and Hyper Coal process extracting combustibles from coal were compared with. UCC process has merits of simple and reliable when it compared with Hyper Coal process, but the remaining ash contents werehigher than Hyper Coal. Hyper Coal has ash contents under the 200ppm when raw coal is treated with appropriate solvent and ion exchange materials to remove alkali materials in extracted solution. The ash-free coal which is similar grade with oil can be used as alternate oil in the industry, and also used as a high grade fuel for IGCC, IGFC and other advanced combustion technology.

poly(D,L-lactide-co-glycolide) nanoparticles제조와 약물방출 거동 및 생분해도

  • Yu, Jeong-Jun;Jeong, Yeong-Il;O, Dong-Seok;Im, Gyun-Taek
    • 한국생물공학회:학술대회논문집
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    • 2000.04a
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    • pp.550-553
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    • 2000
  • The polymeric matrices made with poly(D,L-lactide-co-glycolide) were prepared using copolymer of poly(D,L-lactide) and poly(ethylene glycol) for application of drug delivery systems. Catalyst made use of stannous actoate. Particle size were differ greatly$(435.3{\pm}11.2{\sim}2284.1{\pm}188.5)$ that nanoparticle made use of according to solvent of various kinds. Polymer could a sharp distinction with copolymerized among LE-1, LE-2 and LE-3 of PLA and PEG of content that to examine $^1H-NMR$ of copolymer make refine and reprecipitation. Drug delivery effect at PLGA nanoparticle : PLA amount more then proved highly drug delivery amount that each LE-1, LE-2, LE-3, drug and solvent was 40mg, 20mg and 10mg. Drug delivery effect proved higher 20mg that change(10mg, 20mg, 40mg) at drug feeding amount with LE-2. The first a lot of drug proved delivery. LE-3 most lactide content proved much delivery since biodegradable on PLGA copolymer result from lactide. Also biodegradable rate was highest at LE-3 much of lactide content, because influence at biodegradable effect of lactide by inclusive of soft PEG.

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Effects of Temperature on the Tribological Characteristics of Thermoplastic Polymer Film (열가소성 폴리머 필름의 트라이볼로지 특성에 대한 온도의 영향)

  • Kim, Kwang-Seop;Heo, Jung-Chul;Kim, Kyung-Woong
    • Tribology and Lubricants
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    • v.25 no.4
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    • pp.207-216
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    • 2009
  • Friction tests were carried out in order to investigate the effects of temperature on the friction and wear behaviors between a PMMA film and a fused silica lens using a microtribometer. The friction forces on the PMMA film were measured under atmospheric condition as the temperature of the film was increased from 300 K to 443 K. The contact area between the film and the lens was observed. The tribological characteristics of the film were significantly changed as the temperature increased. The changes were discussed with the change of the film state from glassy to viscous flow. In addition, the results showed that the friction behavior can be varied with the thermal history of the PMMA film. Residual solvent in the PMMA film could emerge to the PMMA surface due to an additional heating and the solvent on the film surface decreased the friction force.

Freeze Cast Porous Mullite Ceramics and Recycling of Coal Fly Ash (동결주조 다공질 뮬라이트 세라믹스의 제조와 석탄회의 재활용)

  • Kim, Kyu Heon;Yoon, Seog Young;Park, Hong Chae
    • Korean Journal of Materials Research
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    • v.26 no.2
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    • pp.61-66
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    • 2016
  • In order to fabricate porous mullite ceramics with controlled pore structure and improved mechanical strength, a freeze casting route has been processed using camphene mixed with tertiary-butyl alcohol (TBA) and coal fly ash/alumina as the solvent and the ceramic material, respectively. After sintering, the solidification characteristics of camphene and TBA solvent were evident in the pore morphology, i.e., dendritic and straight pore channels formed along the solidification directions of camphene and TBA ice, respectively, after sublimation. Also, the presence of microcracks was observed in the bodies sintered at $1500^{\circ}C$, mainly due to the difference in solidification volume change between camphene and TBA. The compressive strength of the sintered bodies was found generally to be dependent, in an inverse manner, on the porosity, which was mainly determined by the processing conditions. After sintering at $1300{\sim}1500^{\circ}C$ with 30~50 wt% solid loading, the resulting mullite ceramics showed porosity and compressive strength values in ranges of 83.8~43.1% and 3.7~206.8 MPa, respectively.

Effect of Structure Change of Chocolate on Migration Behavior between Chocolate and Packaging Printing Solvent (쵸코렛의 구조 변화가 포장재 인쇄 용매의 전이에 미치는 영향)

  • An, Duek-Jun;Jang, Hean-Su;Jeong, Ji-Hwan;Lee, Jin-Seong;Han, Sang-Bin;Do, Se-Ho
    • KOREAN JOURNAL OF PACKAGING SCIENCE & TECHNOLOGY
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    • v.25 no.2
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    • pp.47-50
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    • 2019
  • Migration behavior of printing ink solvents on three types of chocolates with different fat content and fat compositions (different crystallinity) was investigated. Even though chocolate cream (29%) has lower fat content (29%) than that of chips (48%), it showed higher degree of migration. However, with increasing temperature, degree of migration was depended on mainly fat content. This result indicated that degree of migration was mainly affected by crystallinity at below melting point of chocolate, but the effect was diminshed as the temperature was close to melting temperature.