• Title/Summary/Keyword: Cermet

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Current Collector Effects on High Temperature Electrolysis by NI-YSZ Cermet Supported Solid Oxide Cells (집전체에 따른 NI-YSZ Cermet 기반의 가역적 고체산화물 연료전지를 이용한 고온 수증기 전기분해 특성)

  • Shin, Eui-Chol;Ahn, Pyung-An;Seo, Hyun-Ho;Lee, Jong-Sook;Yu, Ji-Haeng;Woo, Sang-Kuk
    • Transactions of the Korean hydrogen and new energy society
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    • v.21 no.6
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    • pp.533-539
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    • 2010
  • Ni-YSZ supported button cells were prepared by spray-coating YSZ and screen-printing YSZ-LSM powder as an electrolyte and oxygen electrode on Ni-YSZ cermet disks. In order to identify the polarization loss mechanism in high temperature electrolysis current-voltage characteristics coupled with electrochemical impedance spectroscopy were investigated as a function of temperature, current load, and the humidity. The effects of the different current collectors of platinum and silver for oxygen electrodes were compared. With Ag current collector two polarization losses were distinguished. The high frequency component was attributed to the Ni-YSZ cermet which was less susceptible to temperature variation but increasing in loss with humidity. The lower frequency component was attributed to the LSM electrode. Platinum current collector led to a much lower polarization loss.

Fabrication and Stability of V/YSZ Cermet Membrane for Hydrogen Separation (수소 분리를 위한 V/YSZ cermet 분리막의 제조 및 안정성)

  • Jeon, Sung-Il;Park, Jung-Hoon;Lee, Sang-Jin;Choi, Soo-Hyun
    • Membrane Journal
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    • v.20 no.1
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    • pp.62-68
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    • 2010
  • The powder mixture for fabricating the cermet membranes was prepared by mechanically mixing 60 vol.% vanadium with $Y_2O_3$-stabilized $ZrO_2$ (YSZ). The powder mixture was pressed into disks, which were then sintered in vacuum at $1600^{\circ}C$ for 2 h. As-sintered membrane was dense and mounted to a stainless steel ring with brazing filler. Hydrogen fluxes of V/YSZ membrane have been measured in the range of $200{\sim}350^{\circ}C$ with 100% $H_2$. The crack was formed in the both sides of membrane at $350^{\circ}C$ and pressure of 0.5 bar. During permeation experiment, vanadium of V/YSZ membrane reacted with hydrogen to form $V_2H$ which was the origin of crack formation.

Fabrication of Pd/YSZ Cermet Membrane for Hydrogen Separation (수소 분리를 위한 Pd/YSZ Cermet 분리막의 제조)

  • Jeon, Sung-Il;Park, Jung-Hoon;Lee, Yong-Taek
    • Membrane Journal
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    • v.21 no.2
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    • pp.148-154
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    • 2011
  • Metal-ceramic composite membrane have been developed to separate hydrogen from mixed gases, particularly product streams generated during coal gasification and methane reforming. Cermet membrane was fabricated with palladium as hydrogen-permeable metal and $Y_2O_3$-stabilized $ZrO_2$ (YSZ) as ceramic supporter. As-prepared membrane showed dense structure with continuous channel of palladium. The hydrogen flux of Pd/YSZ membrane have been measured in the range of 0.5~2 atm with 100% hydrogen gas. The results indicate that the hydrogen flux was 0.333 mL/$min{\cdot}cm^2$ at $450^{\circ}C$ and 2 atm. The crack was formed in the surface and cross-section of membrane.

Development of Cermet Cutting Tool by Powder Injection Molding

  • Chung, Seong-Taek;Kwon, Young-Sam
    • Proceedings of the Korean Powder Metallurgy Institute Conference
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    • 2006.09a
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    • pp.493-494
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    • 2006
  • Chip breaker of cutting tool is an important feature to enhance cutting performance. Powder injection molding process was used to produce a triangular-shape cermet grooving insert which has three chip breakers. Attrition milled cermet powders were mixed with wax-based binder system in continuous twin screw extruder. Three-plate injection mold with slide cores was used to produce injection-molded parts. After molding, solvent and thermal debinding was carried out. Sintering was conducted in a batch furnace with a graphite heater. The sintered parts satisfy the requirements of dimensional tolerances and material properties.

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Effect of Disk Material on the Performance of Cermet Tipped Circular Saw (서멧팁 은납형 둥근톱의 성능에 미치는 기판의 영향)

  • Lee Jae-Woo
    • Proceedings of the Korean Society of Precision Engineering Conference
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    • 2005.10a
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    • pp.350-353
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    • 2005
  • It is a feature of primary importance for a backing material for circular saw blades having teeth which are tipped with cermet, that the steel has not a too high hardenability in order that the backing material shall not be completely hardened through brazing, welding or grinding, etc. in connection with the finishing operation in the manufacturing of circular saw blade. It is believed that V-(2Mo+W) added steel from this point of view had best conditions. Using V-(2Mo+W) added backing steel, the tool failure can be effectively prevented due to superior damping performance.

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A Study on the Machinability of STS 304 (STS 304의 절삭성에 관한 연구)

  • 이재우
    • Proceedings of the Korean Society of Precision Engineering Conference
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    • 2000.05a
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    • pp.779-782
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    • 2000
  • This paper aimes to clarify the effects of tool geometry on the tool life in machining of STS 304. The main conclusions obtained were as follows. The lift of TiN coated cermet tool was the longest, exhibiting shorter life in the order of P2O, cermet, TiCN coated carbide and TiAIN coated carbide tools. S-type tool showed the best performance of all tools used in this tests due to preventing the boundary wear of the side cutting edge.

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Microstructural Evolution and Properties in Ti(CN)-Co/Ni Cermet Depending on the Starting Material for Incorporation of WC (WC 첨가 방법에 따른 Ti(CN)-Co/Ni 계 서멧트의 미세조직 및 특성변화)

  • Chung, Tai-Joo;Ahn, Sun-Yong;Ahn, Seung-Su;Shin, Myung-Soo;Kim, Hak-Kyu;Kim, Kyung-Bae;Oh, Kyung-Sik;Lee, Hyuk-Jae
    • Journal of Powder Materials
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    • v.14 no.2 s.61
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    • pp.132-139
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    • 2007
  • In the Ti(CN)-Co/Ni cermet, WC is an effective additive for increasing sinterability and mechanical properties such as toughness and hardness. In this work, WC, (WTi)C and (WTi)(CN) were used as the source of WC and their effects were investigated in the respect of microstructural evolution and mechanical properties. Regardless of the kinds of WC sources, the hard phase with dark core and bright rim structure was observed in the Ti(CN)-Co/Ni cermet under the incorporation of relatively small amount of WC. However, hard phases with bright core began to appear and their frequency increased with the increase of all kinds of WC source addition. The ratio of bright core to dark one in the (TiW)(CN)-Co/Ni cermet was greatest under the incorporation of (WTi)C compared at the same equivalent amount of WC. The mechanical properties were improved with the addition of WC irrespective of the kinds of sources, but the addition of (WTi)(CN) was less effective for the increase of fracture toughness.

Characterization of Ti(C,N) Solid Solutions in Densified Ti(C,N) and TiC-TiN-Ni Cermet (치밀화된 Ti(C,N)과 TiC-TiN-Ni 써멧에서의 Ti(C,N) 고용상의 특성평가)

  • Kim, Seong-Won;Chae, Jung-Min;Kang, Shin-Hoo;Ryu, Sung-Soo;Kim, Hyung-Tae
    • Journal of Powder Materials
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    • v.15 no.6
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    • pp.503-508
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    • 2008
  • Ti(C,N) solid solutions in hot-pressed Ti($C_{x}N_{1-x}$) (x=0.0, 0.3, 0.5, 0.7, 1.0) and 40TiC-40TiN-20Ni (in wt.%) cermet were characterized in this study. For hot-pressed Ti(C,N)s, the lattice parameters and hardness values of Ti(C,N) were determined by using XRD (X-Ray Diffraction) and nanoindentation. The properties of hot-pressed Ti(C,N) samples changed linearly with their carbon or nitrogen contents. For the TiC-TiN-Ni cermet, the hardness of the hard phase and binder phase were determined by nanoindentation in conjunction with microstructural observation. The measured hardness values were ${\sim}8.7$ GPa for the binder phase and ${\sim}28.7$ GPa for the hard phase, which was close to the hardness of hot-pressed Ti($C_{0.7}N_{0.3}$).

Study on Utilization of Cermets as Seed Corms in Tnro, Colocasia antiquorum var. esculenta $E_NGL$. 1 . The Effect of Cermet Weight on Growth and Yield in Taro (屑芋의 씨토란(種牛) 利用에 關한 硏究 I. 屑芋의 크기가 토란의 生育과 收量에 미치는 영향)

  • 최성규;윤경원
    • Korean Journal of Plant Resources
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    • v.14 no.3
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    • pp.229-234
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    • 2001
  • In order to investigate the possibility of utilizing small cermet as a seed corm in taro, the small cermets classified by the weight were planted on April 30,2000. The effect of weight of small cermets(5,10, If,20,25, and 30g) and corms on the growth, yield, and quality of taro was compared to those raised from cermets. The larger the size of cormel was, the more number of leaves developed, and the higher the yield was. Also the growth of small cormel was normal, so we forecast that it is possible to use small cermet as seed corm in mass production of taro.

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