• 한국수소및신에너지학회논문집
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• 제21권6호
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• pp.533-539
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• 2010

Ni-YSZ supported button cells were prepared by spray-coating YSZ and screen-printing YSZ-LSM powder as an electrolyte and oxygen electrode on Ni-YSZ cermet disks. In order to identify the polarization loss mechanism in high temperature electrolysis current-voltage characteristics coupled with electrochemical impedance spectroscopy were investigated as a function of temperature, current load, and the humidity. The effects of the different current collectors of platinum and silver for oxygen electrodes were compared. With Ag current collector two polarization losses were distinguished. The high frequency component was attributed to the Ni-YSZ cermet which was less susceptible to temperature variation but increasing in loss with humidity. The lower frequency component was attributed to the LSM electrode. Platinum current collector led to a much lower polarization loss.

• 멤브레인
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• 제20권1호
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• pp.62-68
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• 2010

Cermet 분리막 제조를 위한 혼합 분말은 60 vol.% vanadium과 $Y_2O_3$-stabilized $ZrO_2$ (YSZ)를 기계적으로 혼합하여 준비하였다. 혼합 분말을 원판으로 압축한 후 진공 분위기에서 $1600^{\circ}C$로 2시간동안 소결하였다. 소결 분리막은 치밀하였고, 브레이징 필러를 이용하여 스테인레스 링에 장착되었다. V/YSZ 분리막의 수소 투과량은 100% 수소를 흘려 $200{\sim}350^{\circ}C$ 범위에서 측정되었다. $350^{\circ}C$, 0.5 bar압력에서 분리막의 양 표면에 균열이 형성되었다. 투과실험 동안에 V/YSZ 분리막의 vanadium은 수소와 반응하여 $V_2H$를 생성하였으며, 이로 인해 분리막이 균열되는 것을 알 수 있었다.

• 멤브레인
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• 제21권2호
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• pp.148-154
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• 2011

금속-세라믹 복합 분리막은 특히 석탄가스화 공정이나 메탄 개질에서 발생되는 혼합가스로부터 수소를 분리하기 위해 개발되어졌다. 수소투과 금속인 팔라듐과 세라믹 지지체로 $Y_2O_3$-stabilized $ZrO_2$ (YSZ)를 이용하여 cermet 수소분리막을 제조하였다. 이렇게 제조된 분리막은 팔라듐의 연속상이 잘 발달된 치밀 구조를 보였다. Pd/YSZ 분리막의 수소 투과량은 100% 수소를 흘려 0.5~2 atm에서 측정되었다. 수소 투과량은 $450^{\circ}C$, 2 atm에서 0.333 mL/$min{\cdot}cm^2$를 보였다. 수소 투과 후 분리막의 표면과 단면에서 균열이 형성되었다.

• 한국분말야금학회:학술대회논문집
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• 한국분말야금학회 2006년도 Extended Abstracts of 2006 POWDER METALLURGY World Congress Part 1
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• pp.493-494
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• 2006

Chip breaker of cutting tool is an important feature to enhance cutting performance. Powder injection molding process was used to produce a triangular-shape cermet grooving insert which has three chip breakers. Attrition milled cermet powders were mixed with wax-based binder system in continuous twin screw extruder. Three-plate injection mold with slide cores was used to produce injection-molded parts. After molding, solvent and thermal debinding was carried out. Sintering was conducted in a batch furnace with a graphite heater. The sintered parts satisfy the requirements of dimensional tolerances and material properties.

• 한국정밀공학회:학술대회논문집
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• 한국정밀공학회 2005년도 추계학술대회 논문집
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• pp.350-353
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• 2005

It is a feature of primary importance for a backing material for circular saw blades having teeth which are tipped with cermet, that the steel has not a too high hardenability in order that the backing material shall not be completely hardened through brazing, welding or grinding, etc. in connection with the finishing operation in the manufacturing of circular saw blade. It is believed that V-(2Mo+W) added steel from this point of view had best conditions. Using V-(2Mo+W) added backing steel, the tool failure can be effectively prevented due to superior damping performance.

• 한국정밀공학회:학술대회논문집
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• 한국정밀공학회 2000년도 춘계학술대회 논문집
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• pp.779-782
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• 2000

This paper aimes to clarify the effects of tool geometry on the tool life in machining of STS 304. The main conclusions obtained were as follows. The lift of TiN coated cermet tool was the longest, exhibiting shorter life in the order of P2O, cermet, TiCN coated carbide and TiAIN coated carbide tools. S-type tool showed the best performance of all tools used in this tests due to preventing the boundary wear of the side cutting edge.

• 기계와재료
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• 제7권2호통권24호
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• pp.6-18
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• 1995

• 한국분말재료학회지
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• 제14권2호
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• pp.132-139
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• 2007

In the Ti(CN)-Co/Ni cermet, WC is an effective additive for increasing sinterability and mechanical properties such as toughness and hardness. In this work, WC, (WTi)C and (WTi)(CN) were used as the source of WC and their effects were investigated in the respect of microstructural evolution and mechanical properties. Regardless of the kinds of WC sources, the hard phase with dark core and bright rim structure was observed in the Ti(CN)-Co/Ni cermet under the incorporation of relatively small amount of WC. However, hard phases with bright core began to appear and their frequency increased with the increase of all kinds of WC source addition. The ratio of bright core to dark one in the (TiW)(CN)-Co/Ni cermet was greatest under the incorporation of (WTi)C compared at the same equivalent amount of WC. The mechanical properties were improved with the addition of WC irrespective of the kinds of sources, but the addition of (WTi)(CN) was less effective for the increase of fracture toughness.

• 한국분말재료학회지
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• 제15권6호
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• pp.503-508
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• 2008

Ti(C,N) solid solutions in hot-pressed Ti($C_{x}N_{1-x}$) (x=0.0, 0.3, 0.5, 0.7, 1.0) and 40TiC-40TiN-20Ni (in wt.%) cermet were characterized in this study. For hot-pressed Ti(C,N)s, the lattice parameters and hardness values of Ti(C,N) were determined by using XRD (X-Ray Diffraction) and nanoindentation. The properties of hot-pressed Ti(C,N) samples changed linearly with their carbon or nitrogen contents. For the TiC-TiN-Ni cermet, the hardness of the hard phase and binder phase were determined by nanoindentation in conjunction with microstructural observation. The measured hardness values were ${\sim}8.7$ GPa for the binder phase and ${\sim}28.7$ GPa for the hard phase, which was close to the hardness of hot-pressed Ti($C_{0.7}N_{0.3}$).

• 한국자원식물학회지
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• 제14권3호
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• pp.229-234
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• 2001

토란 재배시 관행적으로 이용가치가 적어서 버리는 설우(屑芋를 종우(種芋)로 활용하는 방법을 연구하고자 본 시험을 실시한 결과는 다음과 같다. 1. 토란의 출현은 종우(種芋)의 크기별로 약간의 차이가 인정되어 자우(子芋)인 설우(屑芋)나 소우(小芋)가 친우(親芋)보다 약간 빠른 경향이었으나 출현율은 친우가 높았다. 2. 생육은 자우(子芋)보다는 친우가 엽병장이 크고 엽병속수(葉炳束數)가 많아 양호하였으며, 자우(子芋)가 클수록 생육이 양호한 경 향이었다. 자우(子芋)중 설우(屑芋)도 엽병속이 1.5~2.6개 발생되어 정상적인 생장이 가능하였다. 3.토란 종우(種芋)의 크기에 따른 괴경(塊莖)과 부산물(副産物) 엽병(葉炳)의 수량은 자우(子芋)의 크기간에 차이가 인정되어 자우(子芋)가 클수록 수량이 증수되는 경향이었다. 또한 설우(屑芋)도 크기에 따라 10a 당730~1,680kg의 괴경(壞莖)과 100~310kg의 엽병(葉炳)을 생산할 수가 있어서 대면적의 재배시 종우(種芋)로 이용이 가능할 것으로 생각된다.