• Title/Summary/Keyword: Ceramic panel

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Preparation and Characterization of Anti-reflective and Anti-static Double Layered Films by Sol-Gel Spin-Coating Method (졸-겔 스핀코팅법에 의한 반사방지 및 정전기방지 복층막의 제조 및 특성)

  • 이준종;최세영
    • Journal of the Korean Ceramic Society
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    • v.34 no.1
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    • pp.79-87
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    • 1997
  • Anti-reflective and anti-static double layered films were prepared on the VDT panel by sol-gel spin-coating method. Their electrical, opticla, and mechanical properties were investigated. The outer SiO2 film with low re-fractive index was coated over the inner ATO(Antimony-doped Tin Oxide)-SiO2 film which was prepared by mixing ATO sol with SiO2 at molar ratio of 68:32 to satisfy the interference condition of double layers. The heat treatment was conducted at 45$0^{\circ}C$ for 30 min where residual organics were completely removed. The sheet resistance of ATO single layer showed the minimum value of 6$\times$107$\Omega$/$\square$ at 3 mol% addition of Sb and that of SiO2/ATO-SiO2 increased slightly with increasing SiO2 mol% up to 30 mol%, and then increased steeply to the value of 3$\times$108$\Omega$/$\square$ at 32 mol%. The reflectance of double layered films was about 0.64% at the wavelength of 550nm and the transmittance increased about 3.20%. The hardness of double layered films was almost the same as that of uncoated VDT panel, 471.4kg.f/mm2.

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A study on the fabrication of foamed glass by using refused coal ore and its physical properties (석탄 폐석을 이용한 발포유리의 제조 및 물리적 특성 연구)

  • Lim, Tae-Young;Ku, Hyun-Woo;Hwang, Jong-Hee;Kim, Jin-Ho;Kim, Jung-Kook
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.21 no.6
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    • pp.266-273
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    • 2011
  • Foamed glass was fabricated by using glass powder and foaming agents. For the glass powder, we used sodalime glass which's manufactured by using refused coal ore obtained as by-product from Dogye coal mine in Samcheok. And for the foaming agents, we used Calcium carbonate, Calcium phosphate and powder of shale type refused coal ore itself which has high content of carbon materials. We additionally used liquid binder for forming, and mixed together. And we formed rectangular shape and treated $800^{\circ}C$ for 20 min in an electrical furnace. The various kinds of foam glass samples were fabricated according to the kinds of foaming agents. The physical properties of samples, as specific gravity and compressive strength, were measured. Pore structure of each samples were investigated too. Foam glass with specific gravity of 0.4~0.7 and compressive strength of 30~72 kg/$cm^2$. Especially we get satisfying foam glass sample with low specific gravity of 0.47 and high compressive strength of 72 kg/$cm^2$ by the use of liquid calcium phosphate as foaming agent. It also had small and even shape of pore structure. Therefore, it is concluded that refused coal ore can be used for raw materials to manufacture secondary glass products such as a foamed glass panel for construction and industrial materials.

A study on the fabrication of soda-lime glass by using refused coal ore and its properties (석탄 폐석을 이용한 소다라임계 유리의 제조 및 특성 연구)

  • Lim, Tae-Young;Jeong, Sang-Su;Hwang, Jong-Hee;Kim, Jin-Ho
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.20 no.1
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    • pp.43-52
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    • 2010
  • Glass was fabricated by using refused coal ore obtained from Dogye coal mine in Samchuk. We additionally used soda ash and calcium carbonate as raw materials to make a glass with the chemical composition of soda-lime glass. And the properties of glass were measured when limestone was used as natural raw materials instead of calcium carbonate as chemical raw materials. Transparent glass was fabricated by melting raw materials at $1550^{\circ}C$ for 1 hr in an electrical furnace. The various kinds of glass samples were fabricated according to the kinds of refused coal ore and glass cullet. The optical properties of transmittance and color chromaticity were measured by UV/VIS/NIR spectrometer and the thermal properties of thermal expansion coefficient and softening point were measured. Transparent glass with the transmittance of over 70% in visible range was fabricated by using normal refused coal ore and black colored glass with the transmittance of 0~35% was fabricated by using shel1 type refused coal ore. Therefore, it is concluded that refused coal ore can be used for raw materials to manufacture secondary glass products such as a glass tile and foamed glass panel for construction material.

Experimental Study of Exterior Panel Properties using Ultra High Performance Concrete (UHPC를 활용한 건축용 외장 패널 특성에 관한 실험적 연구)

  • Park, Oh-Seong;Cho, Hyeong-Kyu
    • Journal of the Korea Institute of Building Construction
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    • v.22 no.3
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    • pp.229-237
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    • 2022
  • Ultra High Performance Concrete(UHPC) is a construction material that has a low water-binder ratio (W/B), a high-performance chemical admixture(SP), mixing material and steel fiber, and performance superior to that of regular concrete in terms of liquidity and strength. In the study, UHPC was used to prepare construction external panels that can replace existing stone panels. In addition, experiments were conducted to access the effects of differences in chemical admixture input amount, the number of fillers, antifoaming agent and steel fiber. An evaluation, was conducted, such of concrete compressive strength, flexural strength, impact strength, absorption rate, and frost resistance. The results showed compressive strength up to 115.5MPa, flexural strength of 20.3MPa, and an absorption rate of 1%. In this case, impact strength and frost resistance evaluation were satisfied with outward observed.

Synthesis of Concentrated Silver Nano Sol for Ink-Jet Method (잉크젯용 고농도 은 나노 졸 합성)

  • Park, Han-Sung;Seo, Dong-Soo;Choi, Youngmin;Chang, Hyunjoo;Kong, Ki-Jeong;Lee, Jung-O;Ryu, Beyong-Hwan
    • Journal of the Korean Ceramic Society
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    • v.41 no.9
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    • pp.670-676
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    • 2004
  • The synthesis of highly concentrated silver nano sol assisted by polymeric dispersant (polyelectrolytes) for inkjet method was studied. The silver nano sol was prepared with AgNO$_3$, polyelectrolytes (HS5468cf ; polyacrylic ammonium salt), and reducing agent. The polyelectrolytes play an important role in formation of complex composed of Ag$\^$+/ion and carboxyl group (COO$\^$-/), result in preparation of highly dispersed silver nano particles. The optimization of added amount of polyelectrolytes, and concentration of silver nano sol was studied. The silver nanoparticles were evaluated by XRD, particle size/zeta potential analyzer and FE-TEM. The silver nanoparticles with the range of 10 nm in diameter were produced. The concentration of batch-synthesized silver nano sol was possible up to 40 wt%.

Measurement of Glass Sintering Degree by Electro-chemical Method (전기 화학적 방법을 이용한 소결도의 측정)

  • 차재민;김웅식;이병철;류봉기
    • Journal of the Korean Ceramic Society
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    • v.40 no.6
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    • pp.553-559
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    • 2003
  • PDP rib is one of the important parts of manufacturing process and the sintering degree of rib plays an important role to prevent some problems such as cross talk. Nowadays, the screen-printing method, which is a low price and high production, is used to make a rib. However, it is hard to judge and value the sintering ratio of sintered body itself. In this study, we measured the sintering degree by the dielectric breakdown of pores with the potentiostat. We conformed that this has similar tendency to density of sintered samples and an error being expected by open and closed pores was inspected by change of the microstructure to scanning electron microscope. This result showed that the sintering degree of PDP rib could be analyzed into the electro-chemical method.

Luminescence Properties of Zn2SiO4:Mn, M(M=Cr, Ti) Green Phosphors Prepared by Sol-gel Method (졸-겔법으로 제조한 Zn2SiO4:Mn, M(M=Cr, Ti) 녹색 형광체의 발광특성)

  • 안중인;한정화;박희동
    • Journal of the Korean Ceramic Society
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    • v.40 no.7
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    • pp.637-643
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    • 2003
  • In order to improve the photoluminescent properties and crystallinity, Zn$_2$SiO$_4$:Mn, M(M=Cr, Ti) phosphors were synthesized by the sol-gel method. The willemite single phase was obtained at 110$0^{\circ}C$, which is lower temperature than that of the conventional solid-state reaction (130$0^{\circ}C$). The characteristics of fired samples were obtained by a 147 nm excitation source under VUV (Vacuum Ultraviolet). To investigation the effect of co-dopant, the content of Mn and the ratio of $H_2O$ to TEOS was fixed as 2 ㏖% and 36. 1, respectively. The highest emission intensity was obtained when the concentration of Cr and Ti was 0.1 ㏖% relative to Zn$_2$SiO$_4$:Mn. While the emission intensity decrease continuously the decay time improved as increased the Cr concentration. In the case of Ti added samples, however, the emission intensity increase up to 2 ㏖% concentration.

Laser Sealing of Dye-Sensitized Solar Cell Panels Using V2O5 and TeO2 Contained Glass (V2O5 및 TeO2 함유 유리를 이용한 염료감응형 태양전지 패널의 레이저 봉착)

  • Cho, Sung Jin;Lee, Kyoung Ho
    • Journal of the Korean Ceramic Society
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    • v.51 no.3
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    • pp.170-176
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    • 2014
  • Effective glass frit compositions enabled to absorb laser energy, and to seal a commercial dye-sensitized solar-cell-panel substrate were developed by using $V_2O_5$-based glasses with various amounts of $TeO_2$ substitution. The latter was intended to increase the lifetime of the solar cells. Substitution of $V_2O_5$ by $TeO_2$ provided a strong network structure for the glasses via the formation of tetrahedral pyramids in the glass, and changed the various glass properties, such as glass transition temperature ($T_g$), dilatometric softening point ($T_d$), crystallization temperature, coefficient of thermal expansion (CTE), and glass flowage without any detrimental effect on the laser absorption property of the glasses. The thermal expansion mismatch (${\Delta}{\alpha}$) between the glass frit and the substrate could be controlled within less than ${\pm}5%$ by addition of 10 wt% of ${\beta}$-eucryptite. An 810 nm diode laser was used for the sealing test. The laser sealing test revealed that the VZBT20 glass frit with 10 wt% ${\beta}$-eucryptite was successfully sealed the substrates without interfacial cracks and pores. The optimum sealing conditions were provided by a beam size of 3 mm, laser power of 40 watt, scan speed of 300 mm/s, and 200 irradiation cycles.

Additional Study on the Laser Sealing of Dye-Sensitized Solar-Cell-Panels Using V2O5 and TeO2 Containing Glass

  • Cho, Sung-Jin;Lee, Kyoungho
    • Journal of the Korean Ceramic Society
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    • v.52 no.2
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    • pp.103-107
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    • 2015
  • The effective glass frit composition used to absorb laser energy and to seal commercial dye-sensitized solar cell panel substrates has been previously developed using $V_2O_5-TeO_2$-based glass with 10 wt% ${\beta}$-eucryptite as a CTE controlling filler. The optimum sealing conditions are provided using a 3 mm beam, a laser power of 40 watt, a scan speed of 300 mm/s, and 200 irradiation cycles. In this study, the feasibility of the developed glass frit is investigated in terms of the sealing strength and chemical durability against the commercial iodide/triiodide electrolyte solution and fluorine-doped tin oxide (FTO) electrode in order to increase the solar cell lifetime. The sealing strength of the laser-sealed $V_2O_5-TeO_2$-based glass frit is $20.5{\pm}1.7MPa$, which is higher than those of thermally sealed glass frit and other reported glass frit. Furthermore, the developed glass frit is chemically stable against electrolyte solutions. The glass frit constituents are not leached out from the glass after soaking in the electrolyte solution for up to three months. During the laser sealing, the glass frit does not react with the FTO electrode; thus, the resistivity of the FTO electrode beneath the laser-sealed area remains the same.

A Study on the Similarity between Porcelain Models of Late Joseon Period and Silhouette of Women's Dress (조선(朝鮮)후기 자기기형(瓷器器形)과 여자의복실루엣의 유사성 연구)

  • Jung Ok-Im
    • Journal of the Korean Society of Costume
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    • v.56 no.7 s.106
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    • pp.54-68
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    • 2006
  • This study examined similarity between white porcelain models and dress silhouette of women painted in genre painting in late Joseon period, and found that gourd bottles that are one of main porcelain styles are very similar with dress silhouette of women presented in genre painting in Joseon period; that is, bottle necks of gourd bottles and women's waist, voluminous bottles and erotically full hips, the length of skirts which showed underwear dress and height of porcelain's bottom, waist panel winding slim waist and wide edge of porcelain's mouth. As images are personal mental process of potters who were not socially controlled, they used dress as an indirect means of women's bodies for the subjects of images that are obtained through direct and indirect experiences of the persons who perceive. It indicates that they intended to make their ceramic works express women's dressing style through images of porcelain's models. Such images were sensual, but not superficial. It is suggested that they were influenced by the society which considered ethical experimental mind and practicality of the governing class of that time who enjoyed it metaphorically, but not impudent.