• Title/Summary/Keyword: Cement paste

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Strength and Pore Characteristics of Alkali-activated Slag-Red Mud Cement Mortar used Polymer According to Red Mud Content (레드머드 대체율에 따른 폴리머 혼입 알칼리활성화 슬래그-레드머드 시멘트모르타르의 강도 및 기공특성)

  • Kwon, Seung-Jun;Kang, Suk-Pyo
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.20 no.2
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    • pp.26-33
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    • 2016
  • The alkali-slag-red mud(ASRC) cement belongs to clinker free cementitious material, which is made from alkali activator, blast-furnace slag(BFS) and red mud in designed proportion. This study is to investigate strength and pore characteristics of alkali-activated slag cement(NC), clinker free cementitious material, and ordinary portland cement(C) mortars using polymer according to red mud content. The results showed that the hardened alkali-activated slag-red mud cement paste was mostly consisted of C-S-H gel, being very fine in size and extremely irregular in its shape. So the hardened ASRC cement paste has lower total porosity, less portion of larger pore and more portion of smaller pore, as compared with those of hardened portland cement paste, and has higher strength within containing 10 wt.(%) of alkali-activated slag cement(NC) substituted by red mud.

Secondary Mineral Formation and Expansion Mechanisms Involved in Concrete Pavement Deterioration (콘크리트 포장 도로의 성능저하에 관련된 이차광물형성과 팽창메카니즘)

  • ;Rober D. Cody
    • The Journal of Engineering Geology
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    • v.12 no.1
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    • pp.95-109
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    • 2002
  • A significant question is what role does newly-formed expansive mineral growth play in the premature deterioration of concrete. These minerals formed in cement paste as a result of chemical reactions involving cement paste and coarse/fine aggregate. Petrographic observations and SEM/EDAX analysis were conducted in order to determine chemical and mineralogical changes in the aggregate and cement paste of samples taken from lowa concrete highways that showed premature deterioration. Formation and expansive mechanisms involved in deterioration were Investigated. Brucite, Mg(OH)$_2$, is potentially expansive mineral that farms in cement paste of concretes containing reactive dolomite aggregate as a result of partial dedolomitization of the aggregate. No cracking was observed to be spatially associated with brucite, but most brucite was microscopic in size and widely disseminated in the cement paste of less durable concretes. Expansion stresses associated with its growth at innumerable microlocations may be retrieved by cracking at weaker locations in the concrete. Ettringite, 3CaO.Al$_2$O$_3$.3CaSO$_4$.32$H_2O$, completely fills many small voids and occurs as rims lining the margin of larger voids. Microscopic ettringite is common disseminated throughout the paste in many samples. Severe cracking of cement paste causing premature deterioration is often closely associated with ettringite locations, and strongly suggests that ettringite contributed to deterioration. Pyrite, FeS2, is commonly present in coarse/fine aggregates, and its oxidation products is observed in many concrete samples. Pyrite oxidation provides sulfate ions for ettringite formation.

Mechanical Properties of High Strength Cement Composite with Carbon Fiber (탄소섬유 보강 고강도 시멘트 복합체의 기게적 특성에 관한 연구)

  • 전용희;한기성
    • Journal of the Korean Ceramic Society
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    • v.30 no.2
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    • pp.139-147
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    • 1993
  • Two sheets of high strength cement paste using ordinary Portland cement and water soluble polymer (polyacrylamide) were made by kneading with a twin roll mill. A carbon fiber layer out between two sheet of the cement paste, and then carbon fiber reinforced high strength cement composites were prepared by pressing them. The mechanical properties of the composites were investigated through the observation of the microstructure and the application of fracture mechanics. When the carbon fiber was added with 0.2 and 0.3wt% to the composites the flexural strength and Young's modulus were about 110∼116MPa and 74∼77GPa respectively, and critical stress intensity was about 3.14MPam1/2. It can be considered that the strength improvement of high strength cement fiber composites may be due to the removal of macropores and the increase of various fracture toughness effects; grain bridging, frictional interlocking, polymer fibril bridging and fiber bridging.

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An adaptive approach for the chloride diffusivity of cement-based materials

  • Tran, Bao-Viet;Pham, Duc-Chinh;Loc, Mai-Dinh;Le, Minh-Cuong
    • Computers and Concrete
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    • v.23 no.2
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    • pp.145-153
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    • 2019
  • Adaptive schemes are constructed in this paper for modeling the effective chloride diffusion coefficient of cement-based materials (paste and concrete). Based on the polarization approximations for the effective conductivity of isotropic multicomponent materials, we develop some fitting procedures to include more information about the materials, to improve the accuracy of the scheme. The variable reference parameter of the approximation involves a few free scalars, which are determined through the available numerical or experimental values of the macroscopic chloride diffusion coefficient of cement paste or concrete at some volume proportions of the component materials. The various factors that affect the chloride diffusivity of cement-based material (porous material structure, uncertainty of value of the chloride diffusion coefficient in water-saturated pore spaces, etc.) may be accounted to make the predictions more accurate. Illustrations of applications are provided in a number of examples to show the usefulness of the approach.

Effects of Sugar and Hydrated Cement Powder on the Reduction in Heat of Hydration (당분과 수화시멘트 분말이 수화열 저감에 미치는 효과)

  • Moon, Hoon;Kim, Ji-Hyun;Cho, Yong-Hun;Lee, Jae-Yong;Chung, Chul-Woo
    • Journal of the Korea Institute of Building Construction
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    • v.14 no.2
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    • pp.135-142
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    • 2014
  • The heat of hydration can be reduced through the use of retarding agents. Typical retarding agents include sugar and glucose. However, these significantly delay the setting of cement paste. For the efficient use of sugar and glucose for mass concrete construction, it is necessary to develop a technique that can provide a setting behavior equivalent to that of plain concrete. In this work, the temperature rise of cement paste was monitored with the addition of various retarders including sugar and glucose. Hydrated cement powder was made with a water to cement ratio of 5 in order to accelerate the retarded cement pastes. It was found that the addition of hydrated cement powder in retarded pastes reduced the maximum temperature of cement paste. The use of hydrated cement powder could also successfully reduce the time to reach the maximum temperature.

Rheological Properties of Cement Paste Containing Tailings in Sangdong Mine (상동광산 광미를 혼합한 시멘트 페이스트의 레올로지 특성)

  • Choi Yun Wang;Jung Moon Young;Jung Myung Chae;Koo Gi Jung
    • Proceedings of the Korea Concrete Institute Conference
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    • 2004.05a
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    • pp.616-619
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    • 2004
  • This study has focused on the possibility for recycling of tailings from the Sangdong tungsten mine as powder. The experimental tests for entrapped water ratio were carried out in accordance with the specificed method by Okamura. The rheological measurements of cement paste were conducted by using a commerically digital Brookfield viscometer (Model LVDV-II+) equipped with cylindrical spindles. The results of this study, in case of cement paste mixed with tailings, entrapped water ratio was decreased with increasement of mixing ratio. Thickness of pseudo water film was increased, and mean plastic viscosity was decreased with increasing replacement.

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Estimation of field application for the PHC pile backfill recycling In-site soil (현장 발생토를 재활용한 PHC파일 채움재의 현장 적용성 평가)

  • Choi, Hee-Bok;Noh, Chang-Suck;Han, Byung-Kwon;Lee, Hong-Gyu
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2011.05b
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    • pp.63-66
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    • 2011
  • The aim of this study is to estimate the field applicability of PBFM to replace in-site soil with pile backfill used to replace the existing cement paste. As results, the flowability, segregation and bleeding, and bond strength of PBFM was a good performance than that of the existing cement paste. But the skin friction of pile by Pile Driving Analyzer (PDA) and compressive strength was slightly decreased than that of the existing cement paste. However, as pile backfill materials, and in terms of economics and environment, the applicability of PBFM is considered very effective.

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An Experimental Study on the Properties of Cement Paste Using EM (EM을 활용한 시멘트 페이스트의 특성에 관한 실험적 연구)

  • Lee, Jun;Cho, Ku-Young;Seo, Jung-Pil;Cho, Chul-Ho;Seo, Dae-Suk;Kang, Suk-Pyo
    • Proceedings of the Korea Concrete Institute Conference
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    • 2010.05a
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    • pp.349-350
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    • 2010
  • This study was performed an evaluation of properties of cement paste according to type and content of EM. As the results of study, when considering the flow, compressive strength and application of cement paste, the proper type and content are thought to be type2 and 5~10%, respectively.

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The Experimental Study on the Influence of Relation between Cement Paste and Aggregate Volume to Effect the High Folwing and Engineering Properties of High Flowing Concrete (고유동콘크리트의 유동특성 및 공학적 특성에 미치는 시멘트페이스트용적 및 골재용적과의 관계에 관한 실험적 연구)

  • 김규용;최희용;강희관;김무한
    • Proceedings of the Korea Concrete Institute Conference
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    • 1996.10a
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    • pp.301-307
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    • 1996
  • High flowing concrete has been made using a combination of much amount cementitious materials and addition of SP agents, so that it makes possible to high flowing properties of fresh concrete. In the fluid mechanical and rheological point of view, high flowing concrete is affected on the relation between cement paste and aggregate of volume. In this experimental study, it is measured high flowing concrete of slump-flow about 65$\pm$5cm according to 0.54~0.80 of volume ratio and to analysed the properties of high flowing concrete in fresh and hardened concrete. It is the aim of this study to consider the affection of high flowing properties accoring to cement paste to aggregate ratio of volume on the combination of concrete.

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Cement Paste Hardened Body with High Temperature Exposure Time Fourier Transform Infrared Spectroscopy (고온 노출 시간에 따른 시멘트 페이스트 경화체의 푸리에 변환 적외분광 분석)

  • Kim, Min-Hyouck;Cho, Hyeon-Seo;Lee, Gun-cheol
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2019.05a
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    • pp.120-121
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    • 2019
  • In this study, FT-IR analysis was performed by exposing cement paste to high temperature in order to characterize the change of hydration behavior of concrete structure damaged by fire accident. As the holding time increased, the Al-O vibration region increased due to the increase of Si-O symmetric Ca2(SiO4) and Brownilerite, and the OH stretching region tended to increase due to thermal decomposition of Ca(OH)2.

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