• Title/Summary/Keyword: Cell temperature

Search Result 4,481, Processing Time 0.033 seconds

Polyhydroxyalkanoic Acid Production by Alcaligenes sp. GB-77 (Alcaligenes sp. GB-77 에 의한 Polyhydroxyalkanoic Acid의 생산)

  • 김근배;손홍주;이상준
    • Microbiology and Biotechnology Letters
    • /
    • v.23 no.2
    • /
    • pp.220-228
    • /
    • 1995
  • For polyhydroxyalkanoic acid (PHA) production, several microorganisms were isolated from sewage sludge. One of them, GB-77 strain, was chosen from its PHB/HV copolymer production on only fructose without cosubstrate. The isolated strain GB-77 was identified as the genus Alcaligenes. Optimal temperature and pH for cell growth were 36C and 6.8. Optimal medium composition was 10 g/l of fructose and 5 g/l of polypeptone, 1 $\times$ 10$^{-2}$M Na$^{2}$HP0$^{4}$, 1.3 $\times$ 10$^{-2}$M KH$^{2}$PO$^{4}$. To investigate the optimal condition for polyhydroxyalkanoic acid production two-stage culture technique was used; first stage for cell growth and second stage for PHA production on unbalanced growth conditions. Optimal conditions for high PHA production were C/N ratio 50, temperature 36$\circ$C and pH 6.8. To overcome fructose inhibition on cell growth, intermittent feeding fed-batch culture technique was used. Total cell concentration was 17.4 g/l with 9.1 g/l of PHA. The purified PHA was identified PHB/HV copolymer by NMR analysis.

  • PDF

A Study on the Optimization of Fuel-Cell Stack Design (연료 전지 냉각판의 최적 설계)

  • 홍민성;김종민
    • Transactions of the Korean Society of Machine Tool Engineers
    • /
    • v.12 no.6
    • /
    • pp.92-96
    • /
    • 2003
  • Feul-Cell system consists of fuel reformer, stack and energy translator. Among these parts, stack is a core part which produces electricity directly. In order to set a stack module, fabrication of appropriate stack, design of water flow path in stack and control of coolant are needed. Especially, oater or air is used as a coolant to dissipate heat. The different temperature of each electric cell after cooling affects the performance of the stack. Therefore, it is necessary that the relationship between coolant hearing rate, width of stack, properties of stack, and the shape of water flow path must be understood. For the optimal design, the computational simulation by CFD-ACE has been conducted and the resulting database has been constructed.

Recent Advances in Polybenzimidazole (PBI)-based Polymer Electrolyte Membranes for High Temperature Fuel Cell Applications

  • Vijayakumar, Vijayalekshmi;Kim, Kihyun;Nam, Sang Yong
    • Applied Chemistry for Engineering
    • /
    • v.30 no.6
    • /
    • pp.643-651
    • /
    • 2019
  • Polybenzimidazole (PBI), an engineering polymer with well-known excellent thermal, chemical and mechanical stabilities has been recognized as an alternative to high temperature polymer electrolyte membranes (HT-PEMs). This review focuses on recent advances made on the development of PBI-based HT-PEMs for fuel cell applications. PBI-based membranes discussed were prepared by various strategies such as structural modification, cross-linking, blending and organic-inorganic composites. In addition, intriguing properties of the PBI-based membranes as well as their fuel cell performances were highligted.

Atmospheric and Pressurized Operation of a 25 kW MCFC Stack (25 kW급 용융 탄산염 연료 전지 스택의 상압 및 가압 운전)

  • Koh, Joob-Ho;Seo, Hai-Kung;Lim, Hee-Chun
    • Proceedings of the KSME Conference
    • /
    • 2000.04b
    • /
    • pp.264-269
    • /
    • 2000
  • As a part of the ongoing effort towards commercial application of high-temperature fuel cell power generation systems, we have recently built a pilot-scale molten carbonate fuel cell power plant and tested it. The stack test system is composed of diverse peripheral units such as reformer, pre-heater, water purifier, electrical loader, gas supplier, and recycling systems. The stack itself was made of 40cells of $6000cm^2$ area each. The stack showed an output higher than 25kW power and a reliable performance at atmospheric operation. A pressurized performance was also tested, and it turned out the cell performance increased though a few cells have shown a symptom of gas crossover. The pressurized operation characteristics could be analyzed with numerical computation results of a stack model.

  • PDF

Heat and Mass Transfer Analysis of Phosphoric Acid Fuel Cell According to Variation of gas Flow passage (인산형 연료전지의 가스유로방향 변화에 따른 열 및 물질전달해석)

  • 전동협;정영식;채재우
    • Transactions of the Korean Society of Mechanical Engineers
    • /
    • v.18 no.5
    • /
    • pp.1338-1346
    • /
    • 1994
  • The objective of this study is to investigate the effect of various parameters, such as temperature, mean current density and voltage on the performance of phosphoric acid fuel cell (PAFC) by numerical analysis. Two types of flow passages, which are Z-parallel type and Z-counter type, are evaluated to obtain the best current density and temperature distribution. Parametric studies and sensitivity analysis of the PAFC system's operation in single cell are accomplished. A steady state simulation of the entire system is developed using nonlinear ordinary differential equations. The finite difference method and trial and error procedures are used to obtain a solution.

Experimental investigation of growth and transport behavior of single water droplet in a simplified channel of PEM fuel cell (PEM 연료전지의 단순화된 공기극 채널 내 단일 물방울의 성장 및 이동 특성에 대한 실험적 연구)

  • Kim, Bok-Yung;Kim, Han-Sang;Min, Young-Doug
    • 한국신재생에너지학회:학술대회논문집
    • /
    • 2006.06a
    • /
    • pp.81-84
    • /
    • 2006
  • To investigate the characteristics of water droplet on the gas diffusion layer from both upper-view and side-view of flow channel, a rig test apparatus was designed and fabricated with L-shape acryl plate in a $1mm{\times}1mm$ micro-channel. This experimental device is used to simulate the single droplet growth and its transport process under fuel cell operating condition. As a first step, we investigated the growth and transport of single water droplet with working temperature and air flow velocity. The contact angle and its hysteresis of water droplet at departing moment are measured and analyzed. It is expected that this study can provide the basic understanding of liquid water droplet behavior in gas flow channel and GDL interface during the PEM fuel cell operation.

  • PDF

A Numerical Modeling of the Temperature Dependence on Electrochemical Properties for Solid Oxide Electrolysis Cell(SOEC) (고체 산화물 수전해 시스템(SOEC)에서 전기화학적 특성의 온도 의존성에 대한 수치 모델링)

  • Han, Kyoung Ho;Jung, Jung Yul;Yoon, Do Young
    • Journal of Energy Engineering
    • /
    • v.29 no.2
    • /
    • pp.1-9
    • /
    • 2020
  • In recent days, fuel cell has received attention from the world as an alternative power source to hydrocarbon used in automobile engines. With the industrial advances of fuel cell, There have been a lot of researches actively conducted to find a way of generating hydrogen. Among many hydrogen production methods, Solid Oxide Electrolysis Cell(SOEC) is not only a basic way but also environment-friendly method to produce hydrogen gas. Solid Oxide Electrolysis Cell has lower electrical energy demands and high thermal efficiency since it is possible to operate under high temperature and high pressure conditions. For these reasons, experimental researches as well as studies on numerical modeling for Solid Oxide Electrolysis Cell have been under way. However, studies on numerical modeling are relatively less enough than experimental accomplishments and have limited performance prediction, which mostly is considered as a result from inadequate effects of electrochemical properties by temperature and pressure. In this study, various experimental studies of commercial Membrane Electrode Assembly (MEA) composed of Ni-YSZ (40wt%, Ni-60 wt% YSZ)/8-YSZ (TOSOH, TZ8Y)/LSM (La0.9Sr0.1MnO3) was utilized for improving effectiveness of SOEC model. After numerically analyzing effects of electrochemical properties according to operating temperature, causing the largest deviation between experiments and simulation are that Charge Transfer Coefficient (CTC), exchange current density, diffusion coefficient, electrical conductivity in SOEC. Analyzing temperature effect on parameter used in overpotential model is conducted for modeling of SOEC. cross-validation method is adopted for application of various MEA and evaluating feasibility of model. As a result, the study confirm that the numerical model of SOEC based on structured process of effectiveness evaluation makes performance prediction better.

Effect of Flow Direction on Temperature Uniformity in Solid Oxide Fuel Cell (고체산화물 연료전지의 유동방향에 따른 온도 균일성 영향)

  • Jeon, Dong Hyup;Shin, Dong-Ryul;Ryu, Kwang-Hyun;Song, Rak-Hyun
    • Transactions of the Korean Society of Mechanical Engineers B
    • /
    • v.41 no.10
    • /
    • pp.667-673
    • /
    • 2017
  • We investigated the temperature uniformity in an anode-supported solid oxide fuel cell, using the open source computational fluid dynamics (CFD) toolbox, OpenFOAM. Numerical simulation was performed in three different flow paths, i.e., co-flow, counter-flow, and cross-flow paths. Gas flow in a porous electrode was calculated using effective diffusivity while considering the effect of interconnect rib. A lumped internal resistance model derived from a semi-empirical correlation was implemented for the calculation of electrochemical reaction. The result showed that the counter-flow path displayed the most uniform temperature distribution.

The Intrinsic Safety Evaluation of Solar Photovoltaic Cell (태양전지셀의 본질안전 방폭성능 평가)

  • Lee, Chun-Ha;Jee, Seung-Wook;Kim, Si-Kuk
    • Journal of the Korean Institute of Illuminating and Electrical Installation Engineers
    • /
    • v.25 no.7
    • /
    • pp.49-54
    • /
    • 2011
  • Now the world will regulate the CO2 emission due to environmental issues. For an alternative plan photovoltaic system is watched. So, photovoltaic system is trend of big city and it is mandatory for renovation of construction. Oil & gas filling station existed in city is suitable to found the photovoltaic system. But the general photovoltaic system in oil & gas filling station is difficult to found because it is classified into hazardous area. This paper evaluates intrinsic safety evaluation of solar cell for making basic data to found for the photovoltaic system on hazardous area. The intrinsic safety characteristic is evaluated by short-circuit ignition test using IEC type spark ignition test apparatus and temperature rising test. The result of short-circuit ignition test, propane-air mixture gas is exploded on condition that 4 solar cells(9[V], 90[mA]) are connected serially under insolation 800[W/$m^2$]. So, if a larger solar module will be used at oil & gas filling station than we were tested, it needs explosion proof. As the result of rising temperature test, the temperature rising due to short circuit is not so much, but when the temperature rises due to radiant heat, it demands careful consideration for environmental influence.