• Title/Summary/Keyword: Cell size and density

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Characterization of CdS Thin Films for Compound Photovoltaic Applications by Atmospheres of Rapid Thermal Process (급속열처리 분위기에 따른 화합물 태양전지용 CdS 박막의 특성변화)

  • Park, Seung-Beum;Kwon, Soon-Il;Lee, Seok-Jin;Jung, Tae-Hwan;Yang, Kea-Joon;Lim, Dong-Gun;Park, Jae-Hwan;Song, Woo-Chang
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2008.11a
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    • pp.105-106
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    • 2008
  • Structural, optical and electrical properties of CdS films deposited by chemical bath deposition (CBD), which are a very attractive method for low-cost and large-area solar cells, are presented. Cadmium sulfide (CdS) is II-VI semiconductor with a wide band gap of approximately 2.42 eV. CdS films have a great application potential such as solar cell, optical detector and optoelectronics device. In this paper, effects of Rapid Thermal Process (RTP) on the properties of CdS films were investigated. The CdS films were prepared on a glass by chemical bath deposition (CBD) and subsequently annealed at standard temperature $(400^{\circ}C)$ and treatment time (10 min) in various atmospheres (air, vacuum and $N_2$). The CdS films treated RTP in $N_2$ for to min were showed larger grain size and higher carrier density than the other samples.

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Large-scale Culture of Plant Cell and Tissue by Bioreactor System

  • Son, Sung-Ho;Park, Sung-Mee;Park, Seung -Yun;Kwon, Oh-Woung;Lee, Yun-Hee;Paek, Kee-Yoeup
    • Journal of Plant Biotechnology
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    • v.1 no.1
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    • pp.1-7
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    • 1999
  • Large-scale cultures of plant cell, tissue, and organ have been achieved by using BTBB. When different sized BTBBs (5 L, 20 L, 100 L, 300 L, and 500 L) were tested for the culture of yew cells (Taxus cuspidata Sieb. et Zucc.), cell growth increment reached to 94.5% in SCV after 24 days of culture with 30% of inoculation cell density. However, there were some variations in the production of taxol and its derivatives among the BTBBs of different size. Approximate 4 ㎎/l of taxol and 84 ㎎/l of total taxanes were obtained by using a 500L BTBB after 6 weeks of culture. With a 20L BTBB, about 20,000 cuttings of virus-free potatoes (cv. Dejima) could be obtained by inoculating 128 explants and maintaining 8 weeks under 16 hr light illumination. The frequency of ex vitro rooting of the cuttings revealed as more than 99% under 30% shade. By incorporating two-stage culture process consisting of multiple bulblet formation in solid medium and bulblet development in liquid medium, mass propagation of lily through bioreactor seemed to be possible. In the case of 'Marcopolo', the growth of mini-bulblets in BTBB was nearly 10 folds faster than that of the solid medium. Time course study revealed that maximum MAR yield of ginseng (Panax ginseng C. A. Meyer) in a 5 L and 20 L BTBB after 8 weeks of culture was 500 g and 2.2 ㎏, respectively. By cutting the MAR once and/or twice during the culture, the yield of root biomass could be increased more than 50% in fresh weight at the time of harvest. With initial inoculum of 500 g of sliced MAR in a 500 L BTBB, 74.8 ㎏ of adventitious root mass was obtained after 8 weeks of culture. The average content of total ginseng saponin obtained from small-scale and/or pilotscale BTBBs was approximately 1% per gram dry weight. Based on our results, we suggest that large-scale cultures of plant cell, tissue, and organ using BTBB system should be quite a feasible approach when compared with conventional method of tissue culture.

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A New Moving Mobile Base Station (MMBS) Scheme for Low Power RMIMS Wireless System (PARTI: MMBS general issues, clystering and signalling Procedures) (저전력 RMIMS 무선 터미널을 위한 새로운 움직이는 이동 기지국 시스템 구조 (1부 : MMBS 일반사항, 클러스터링 및 신호절차))

  • 박수열;고윤호;유상조;김성대
    • The Journal of Korean Institute of Communications and Information Sciences
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    • v.24 no.12B
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    • pp.2298-2319
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    • 1999
  • In this paper, we propose a new moving mobile base station (MMBS) scheme for very low power and micro-size RMIMS (radio-interfaced micro information monitoring system) terminals. RMIMS terminals can be used in various application service areas such as pollution monitoring, environment surveillance, traffic monitoring, emergency monitoring (e.g., building, bridge, railroad breakdown), security monitoring (e.g., theft, alarm) and military application. For these applications based on wireless transmission technologies, sensor type RMIMS terminals must satisfy low cost and low power design (e.g., solar power, life limited battery) requirement. In RMIMS terminal design, this low power requirement limits transmission range of uplink or reverse link and means small cell size. Also these applications using RMIMS terminals may have a little bit non real-time traffic characteristic and low scattering density in service area.

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Preparation of Ni(OH)2 Hollow Spheres by Solvent Displacement Crystallization Using Micro-Injection Device (마이크로 주입장치를 이용한 용매치환결정화에 의한 중공상 수산화니켈 분말의 제조)

  • Kim, Seiki;Park, Kyungsoo;Jung, Kwang-Il
    • Journal of Powder Materials
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    • v.23 no.4
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    • pp.311-316
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    • 2016
  • $Ni(OH)_2$ hollow spheres have been prepared by solvent displacement crystallization using a micro-injection device, and the effect of process parameters such as concentration and the relative ratio of the injection speed of the precursor solution, which is an aqueous solution of $NiSO_4{\cdot}6H_2O$, to isopropyl alcohol of displacement solvent have been investigated. The crystal phases after NaOH treatment are in the ${\beta}-phase$ for all process parameters. A higher concentration of $NiSO_4{\cdot}6H_2O$ aqueous solution is injected by a micro-injection device and bigger $Ni(OH)_2$ hollow spheres with a narrower particle size distribution are formed. The crystallinity and hardness of the as-obtained powder are so poor that hydrothermal treatment of the as-obtained $Ni(OH)_2$ at $120^{\circ}C$ for 24 h in distilled water is performed in order to greatly improve the crystallinity. It is thought that a relative ratio of the injection speed of $NiSO_4{\cdot}6H_2O$ to that of isopropyl alcohol of at least more than 1 is preferable to synthesize Ni(OH)2 hollow spheres. It is confirmed that this solution-based process is very effective in synthesizing ceramic hollow spheres by simple adjustment of the process parameters such as the concentration and the injection speed.

Effect of KCN Treatment on Cu-Se Secondary Phase of One-step Sputter-deposited CIGS Thin Films Using Quaternary Target

  • Jung, Sung Hee;Choi, Ji Hyun;Chung, Chee Won
    • Current Photovoltaic Research
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    • v.2 no.3
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    • pp.88-94
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    • 2014
  • The structural, optical and electrical properties of sputter-deposited CIGS films were directly influenced by the sputtering process parameters such as substrate temperature, working pressure, RF power and distance between target and substrate. CIGS thin films deposited by using a quaternary target revealed to be Se deficient due to Se low vapor pressure. This Se deficiency affected the overall stoichiometry of the films, causing the films to be Cu-rich. Current tends to pass through the Cu-Se channels which act as the shunting path increasing the film conductivity. The crystal structure of CIGS thin films depends on the substrate orientation due to the influence of surface morphology, grain size and stress of Mo substrate. The excess of Cu was removed from the CIGS films by KCN treatment, achieving a suitable Cu concentration (referred as Cu-poor) for the fabrication of solar cell. Due to high Cu concentrations on the CIGS film surface induced by Cu-Se phases after CIGS film deposition, KCN treatment proved to be necessary for the fabrication of high efficiency solar cells. Also during KCN treatment, dislocation density and lattice parameter decreased as excess Cu was removed, resulting in increase of bandgap and the decrease of conductivity of CIGS films. It was revealed that Cu-Se secondary phase could be removed by KCN wet etching of CIGS films, allowing the fabrication of high efficiency absorber layer.

Characteristics of Pt, Pt-Ru and Pt-CeO2 Catalysts Supported on Carbon Nanotubes for Methanol Fuel Cell (탄소 나노튜브에 담지된 Pt, Pt-Ru 및 Pt-CeO2 메탄올 연료전지 촉매의 특성)

  • Hwang, Gui-Sung;Lee, Rhim-Youl
    • Korean Journal of Materials Research
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    • v.21 no.3
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    • pp.138-143
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    • 2011
  • Nanosized Pt, Pt-Ru and Pt-$CeO_2$ electrocatalysts supported on acid-treated carbon nanotube (CNT) were synthesized by microwave-assisted heating of polyol process using $H_2Cl_6Pt{\cdot}6H_2O$, $RuCl_3$, $CeCl_3$ precursors, respectively, and were characterized by XRD and TEM. And then the electrochemical activity of methanol oxidation for catalyst/CNT nanocomposite electrodes was investigated. The microwave assisted polyol process produced the nano-sized crystalline catalysts particles on CNT. The size of Pt supported on CNT was 7~12 nm but it decreased to 3~5 nm in which 10wt% sodium acetate was added as a stabilizer during the polyol process. This fine Pt catalyst particles resulted in a higher current density for Pt/CNT electrode. It was also found that 10 nm size of PtRu alloys were formed by polyol process and the onset potential decreased with Ru addition. Cyclic voltammetry analysis revealed that the $Pt_{75}Ru_{25}/CNT$ electrode had the highest electrochemical activity owing to a higher ratio of the forward to reverse anodic peak current. And the chronoamperemetry test showed that $Pt_{75}Ru_{25}$ catalyst had a good catalyst stability. The activity of Pt was also found to be improved with the addition of $CeO_2$.

Premalignant Lesions of Gallbladder Carcinoma and Treatment (담낭암 발생 관련 질환과 치료)

  • Yun, Sung-Su
    • Journal of Yeungnam Medical Science
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    • v.23 no.2
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    • pp.152-161
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    • 2006
  • Carcinoma of the gallbladder is an uncommon but highly malignant tumor with a poor five year survival rate. Early detection is very important for successful treatment because this tumor is very hard to cure in cases where it has advanced beyond the reach of surgical treatment. The purpose of this review was to evaluate risk factors for carcinoma of the gallbladder and determine the best management approach.. Solitary polys, more than one cm are considered to be predisposing factors for gallbladder carcinoma when they are found to be echopenic, sessile, and with a high cell density. Anomalous union of the pacreato-biliary duct(AUPBD) without a choledochal cyst is also considered to increase risk for gallbladder carcinoma. A polyps size of more than one cm and an AUPBD are indications for prophylactic cholecystectomy. The presence of gallstones is a well-established risk factor for the development of gallbladder carcinoma; risk appears to correlate with the stone size and the duration of chronic cholecystitis. Metaplastic changes of the gallbladder epithelium present with chronic cholecystitis and may indicate a premalignant lesion. Abnormal forms of cholecystitis such as xanthogranulomatous or a porcelain gallbladder also have malignant potential; cholecystoenteric fistula as well as bacterial infection of the gallbladder(typhoid, helicobacter species) also has malignant potential. In this review, the risk factors associated with carcinoma of the gallbladder are summarized with special attention to gallstones, polyps, AUPBD, and chronic inflammation.

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Characterization of Electrical Properties of Si Nanocrystals Embedded in a SiO$_{2}$ Layer by Scanning Probe Microscopy (Scanning Probe Microscopy를 이용한 국소영역에서의 실리콘 나노크리스탈의 전기적 특성 분석)

  • Kim, Jung-Min;Her, Hyun-Jung;Kang, Chi-Jung;Kim, Yong-Sang
    • The Transactions of the Korean Institute of Electrical Engineers C
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    • v.54 no.10
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    • pp.438-442
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    • 2005
  • Si nanocrystal (Si NC) memory device has several advantages such as better retention, lower operating voltage, reduced punch-through and consequently a smaller cell area, suppressed leakage current. However, the physical and electrical reasons for this behavior are not completely understood but could be related to interface states of Si NCs. In order to find out this effect, we characterized electrical properties of Si NCs embedded in a SiO$_{2}$ layer by scanning probe microscopy (SPM). The Si NCs were generated by the laser ablation method with compressed Si powder and followed by a sharpening oxidation. In this step Si NCs are capped with a thin oxide layer with the thickness of 1$\~$2 nm for isolation and the size control. The size of 51 NCs is in the range of 10$\~$50 m and the density around 10$^{11}$/cm$^{2}$ It also affects the interface states of Si NCs, resulting in the change of electrical properties. Using a conducting tip, the charge was injected directly into each Si NC, and the image contrast change and dC/dV curve shift due to the trapped charges were monitored. The results were compared with C-V characteristics of the conventional MOS capacitor structure.

Poly(Imide) Separator Functionalized by Melamine Phosphonic Acid for Regulating Structural and Thermal Stabilities of Lithiumion Batteries

  • Ye Jin Jeon;Juhwi Park;Taeeun Yim
    • Journal of Electrochemical Science and Technology
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    • v.15 no.3
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    • pp.365-372
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    • 2024
  • As the energy density of lithium-ion batteries (LIBs) continues to increase, various separators are being developed to with the aim of improving the safety performance. Although poly(imide) (PI)-based separators are widely used, it is difficult to control their pore size and distribution, and this may further increase the risk associated. Herein, a melamine phosphonic acid (MP)-coated PI separator that can effectively control the pore structure of the substrate is suggested as a remedy. After the MP material is embedded into the PI separator with a simple one-step casting process, it effectively clogs the large pores of the PI separator, preventing the occurrence of internal short circuits during charging. It is anticipated that the MP material can also suppress rapid thermal runaway upon cycling due to its ability to reduce the internal temperature of the LIB cell caused by the desirable endothermic behavior around 300℃. According to experiments, the MP-coated PI separator not only decreases the thermal shrinkage rate better than commercial poly(ethylene) (PE) separators but also exhibits a desirable Gurley number (109.6 s/100 cc) and electrolyte uptake rate (240%), which is unique. The proposed separator is electrochemically stable in the range 0.0-5.0 V (vs. Li/Li+), which is the typical working potential of conventional electrode materials. In practice, the MP-coated PI separator exhibits stable cycling performance in a graphite-LiNi0.83Co0.10Mn0.07O2 full cell without an internal short circuit (retention: 90.3%).

Refinement of Microstructures for Aluminum Piston through Ultrasonic Melt Treatment (초음파 용탕처리를 이용한 알루미늄 피스톤의 조직 미세화)

  • Lee, Sang-Hwa;Jung, Jae-Gil;Lee, Jung-Moo;Cho, Young-Hee;Yoon, Woon-Ha;Ahn, Yong-Sik;Yun, Dong-Chun;Lee, Jeong-Keun;Ryu, Kwan-Ho
    • Journal of Korea Foundry Society
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    • v.36 no.2
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    • pp.53-59
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    • 2016
  • The effects of ultrasonic melt treatment on the microstructures of aluminum piston were examined at five observation parts having different cooling rates. The microstructure of aluminum piston consisted of primary Si, eutectic Si, and various types of intermetallic compounds. Regardless of cooling rate, the ultrasonic melt treatment transformed dendritic eutectic cells to equiaxed eutectic cells and it decreased the sizes of eutectic Si and intermetallic compounds that exist at eutectic cell boundaries. In the absence of ultrasonic treatment, coarse primary Si particles were severely segregated and its size was increased with decreasing the cooling rate. The ultrasonic treatment decreased the size of primary Si particles from $25.5{\sim}31.0{\mu}m$ to $17.6{\sim}23.1{\mu}m$, depending on the cooling rate. In the presence of ultrasonic treatment, relatively fine primary Si particles were homogeneously distributed throughout the piston. In addition, the ultrasonic treatment increased the population density and area fraction of fine primary Si particles.