• Title/Summary/Keyword: Cell Decomposition

Search Result 242, Processing Time 0.026 seconds

Studies on decomposition of solvent for lithium-ion battery (리튬 이온 전지의 용매 분해 반응에 대한 연구)

  • Chung Kwang-il;Choi Byeong-doo;Kim Shin-Kook;Kim Woo-Seong;Choi Yong-Kook
    • Journal of the Korean Electrochemical Society
    • /
    • v.1 no.1
    • /
    • pp.28-32
    • /
    • 1998
  • The electrochemical behavior of film and charge-discharge capacity of Li-ion cell in 1 M $LiPF_6/EC:DME$ (1 : 1, by volume ratio) electrolyte solution was studied using chronopotentiometry, cyclic voltammetry, chronoamperometry, and impedance spectroscopy. The first irreversible capacity was higher than the second irrversible capacity because of solvent decomposition. Especially, passivation film that is electron insulating and ionic conducting were formed on the MPCF by solvent decomposition during the first charge. The solvated Li is co-intercalated with solvent into MPCF electrode. Part of the MPCF is expoliated during co-intercalation of solvent-Li. The MPCF ends up nonuniformly covered by a relatively thick layer of exfoliated particles embedded in a matrix of product by solvent decomposition.

Estimation of Halftone Cell Information by Analyzing Distribution of Halftone Dots and Refining Location of Their Spectral Peaks (해프톤 도트 분포 분석 및 주파수 피크 위치 정제에 의한 해프톤 셀 정보 추정)

  • 한영미;김민환
    • Journal of Korea Multimedia Society
    • /
    • v.4 no.2
    • /
    • pp.116-129
    • /
    • 2001
  • To improve the performance of the inverse halftoning, smoothing masks should be designed optimally by using the accurate information of halftone cells. In this thesis, the method of energy minimization is so defined as to determine the exact information of halftone cell. A heuristic search method is proposed to obtain efficiently the parameters of halftone cells which determine the minimum energy. A halftone-peak modeling method with several functions is proposed and used to get initial values of the parameters. The dimension decomposition technique is also adopted to speed up the search process of energy minimization. Several experiments show that the proposed method extracts correct location of the seed pixel of the halftone cell and the extracted information of the halftone cell can be used to get more exactly smoothed color images. The proposed method can be applied to extract the texture patterns, to separate channel images of a scanned color halftone image, and to extract the moire area in an image.

  • PDF

Investigation of Al-Ni Alloys Deposition during Over-discharge Reaction of Na-NiCl2 Battery

  • Kim, Jeongsoo;Jo, Seung Hwan;Park, Dae-In;Bhavaraju, Sai;Kang, Sang Ook
    • Journal of the Korean Electrochemical Society
    • /
    • v.19 no.3
    • /
    • pp.57-62
    • /
    • 2016
  • The over-discharging phenomena in sodium-nickel chloride batteries were investigated in relation to decomposition of molten salt electrolyte and consequent metal co-deposition. From XRD analysis, the material deposited on graphite cathode current collector was revealed to be by-product of molten salt electrolyte decomposition. In particular, the result showed that the Ni-Al alloys ($Al_3Ni_2$, $Ni_3Al$ and $Al_3Ni$) were electrochemically deposited on graphite current collectors in line with over-discharging behaviors. It is assumed that the $NiCl_2$ solubility in molten salt electrolytes leads to the co-deposition of Ni-Al alloys by increasing metal deposition potential above 1.6 V (vs. $Na/Na^+$). The cell tests have revealed that the composition of molten salt electrolytes modified by various additives makes a decisive influence on the over-discharging behaviors of the cells. It was revealed that NaOCN addition to molten salt electrolytes was advantageous to suppress over-discharge reactions by modifying the characteristics of molten salt electrolytes. NaOCN addition into molten salt electrolytes seems to suppress Ni solubility by maintaining basic melts. The cell using modified molten salt electrolyte with NaOCN (Cell D) showed relatively less cell degradation compared with other cells for long cycles.

Development of radar-based quantitative precipitation forecasting using spatial-scale decomposition method for urban flood management (도시홍수예보를 위한 공간규모분할기법을 이용한 레이더 강우예측 기법 개발)

  • Yoon, Seongsim
    • Journal of Korea Water Resources Association
    • /
    • v.50 no.5
    • /
    • pp.335-346
    • /
    • 2017
  • This study generated the radar-based forecasted rainfall using spatial-scale decomposition method (SCDM) and evaluated the hydrological applicability with forecasted rainfall by KMA (MAPLE, KONOS) in terms of urban flood forecasting. SCDM is to separate the small-scale field (convective cell) and large-scale field (straitform cell) from radar rainfield. And each separated field is forecasted by translation model and storm tracker nowcasting model for improvement of QPF accuracy. As the evaluated results of various QPF for three rainfall events in Seoul and Metropolitan area, proposed method showed better prediction accuracy than MAPLE and KONOS considering the simplicity of the methodology. In addition, this study assessed the urban hydrological applicability for Gangnam basin. As the results, KONOS simulated the peak of water depth more accurately than MAPLE and SCDM, however cannot simulated the timeseries pattern of water depth. In the case of SCDM, the quantitative error was larger than observed water depth, but the simulated pattern was similar to observation. The SCDM will be useful information for flood forecasting if quantitative accuracy is improved through the adjustment technique and blending with NWP.

Formulation of Rectal Supopositories of Omeprazole (오메푸라졸 함유 직장좌제의 제제설계)

  • 이창현;황성주;오세종;이계주
    • YAKHAK HOEJI
    • /
    • v.37 no.4
    • /
    • pp.370-382
    • /
    • 1993
  • In order for formulation of rectal containing OMZ, the OMZ suppositories were prepared using water-soluble base, PEG 4000 base and oil-soluble base, Witepsol H 15. Chemical stability of OMZ in suppositories was increased when Witepsol H 15 was used as a suppository base and arginine was added as a stabilizer. The decomposition of OMZ in suppository bases followed the first-order kinetics and their rate constants were 0.11 day $^{1}(t_{1/2}$=/6.25 days) for Witepsol H 15 suppository and 0.48 day $^{1}(t_{1/2}$=/1.43 days) for PEG 4000 suppository, respectively. On the other hand, the decomposition rate constants of Witepsol suppository and PEG suppository stabilized with arginine were 3.89$\times$10$^{-3}$(t$_{1/2}$=171.1 days) and 8.76$\times$10$^{-3}$ day $^{1}(t_{1/2}=79.9 days), respectively. Shelf-lives of the Witepsol and PEG suppositories stabilized with arginine were t$_{90%}$=291.8 days and t$_{90%}$=282.1 days at $35^{\circ}C$ and 75% RH, respectively. The dissolution test of OMZ suppositories was performed by rotating dialysis cell(RDC) method and the release rate constant was calculated by the simplified Higuchi's equation, Q'=K' t$^{1/2}$. Dissolution of OMZ from suppositories was augmented as arginine was added, particle size of OMZ was reduced and a suitable surfactant such as SLS was added. RDC method was more appropriate and available than Paddle method to evaluate the dissolution rate of lipophilic-base suppositoies. Arginine was found to be a very useful exipient for the enhancement of stability and dissolution of OMZ in suppositories.

  • PDF

Degradation of Membrane for PEM Fuel Cell with Hydrogen Peroxide (과산화수소에 의한 고분자전해질 연료전지 막의 열화)

  • Kim, Tae-Hee;Lee, Jung-Hun;Park, Kwon-Pil
    • 한국신재생에너지학회:학술대회논문집
    • /
    • 2006.11a
    • /
    • pp.438-442
    • /
    • 2006
  • The degradation of Nafion membrane by hydrogen peroxide was investigated in polymer electrolyte membrane fuel cell (PEMFC). Degradation tests were carried out in a solution of $10{\sim}30%$ hydrogen peroxide containing 4ppm $Fe^{2+}$ ion which is well known as Fenton's reagent at $80^{\circ}C$ for 48hr. Characterization of degraded membranes were examined through the IR, Water-uptake, Ion exchange capacity, mechanical strength and $H_2$ permeability. After degradation, C-F, S-O and C-O chemical bonds of membrane were broken by radical formed by $H_2O_2$ decomposition. Breaking of C-F bond which is the membrane backbone reduced the mechanical strength of Nafion membrane and hence induced pinholes, resulting in increase of $H_2$ crossover through the membrane. Also the decomposition of C-O and S-O, side chain and terminal bond of membrane, decreased the ion exchange capacity of the membrane.

  • PDF

Subspace Interference Alignment by Orthogonalization of Reference Vectors (참조 벡터의 직교화 방법을 이용한 부분공간 간섭 정렬)

  • Seo, Jong-Pil;Kim, Hyun-Soo;Lee, Yoon-Ju;Kwon, Dong-Seung;Kim, Ji-Hyung;Chung, Jae-Hak
    • The Journal of Korean Institute of Communications and Information Sciences
    • /
    • v.35 no.1A
    • /
    • pp.54-61
    • /
    • 2010
  • We propose a subspace interference alignment by orthogonalization of reference vectors. The proposed method improves the sum-rate capacity degradation due to the channel decomposition error and channel estimation error in the real environment. Using the proposed method, each cell uses the reference vector that is orthogonal to the adjacent cells. Then the residual interference produced by the channel decomposition error and the channel estimation error is decreased. The simulation results demonstrate that the proposed method achieves the enhanced sum-rate capacity.

IDEAL CELL-DECOMPOSITIONS FOR A HYPERBOLIC SURFACE AND EULER CHARACTERISTIC

  • Sozen, Yasar
    • Journal of the Korean Mathematical Society
    • /
    • v.45 no.4
    • /
    • pp.965-976
    • /
    • 2008
  • In this article, we constructively prove that on a surface S with genus g$\geq$2, there exit maximal geodesic laminations with 7g-7,...,9g-9 leaves. Thus, S can have ideal cell-decompositions (i.e., S can be (ideally) triangulated by maximal geodesic laminations) with 7g-7,...,9g-9 (ideal) 1-cells. Once there is a triangulation for a compact surface, the Euler characteristic for the surface can be calculated as the alternating sum F-E+V, where F, E, and V denote the number of faces, edges, and vertices, respectively. We also prove that the same formula holds for the ideal cell decompositions.

Electric power generation from treatment of food waste leachate using microbial fuel cell

  • Wang, Ze Jie;Lim, Bong Su
    • Environmental Engineering Research
    • /
    • v.22 no.2
    • /
    • pp.157-161
    • /
    • 2017
  • Simultaneous treatment of food waste leachate and power generation was investigated in an air-cathode microbial fuel cell. A TCOD removal efficiency of $95.4{\pm}0.3%$ was achieved for an initial COD concentration of 2,860 mg/L. Maximum power density ranged was maximized at $1.86W/m^3$, when COD concentration varied between 60 mg/L and 2,860 mg/L. Meanwhile, columbic efficiency was determined between 1.76% and 11.07% for different COD concentrations. Cyclic voltammetric data revealed that the oxidation peak voltage occurred at -0.20 V, shifted to about -0.25 V. Moreover, a reduction peak voltage at -0.45 V appeared when organic matters were exhausted, indicating that reducible matters were produced during the decomposition of organic matters. The results showed that it was feasible to use food waste leachate as a fuel for power generation in a microbial fuel cell, and the treatment efficiency of the wastewater was satisfied.