• Resources Recycling
• /
• v.11 no.1
• /
• pp.32-36
• /
• 2002

This study was conducted to compost the mixture of Pig manure, gypsum and fly ash. Initial moisture contents of sample A (Pig manure : saw dust = 6 : 4) and C (Pig manure : saw dust : gypsum : coal fly ash= 6 : 2 : 1 : 1) in the reactor were 64 and 50%. Also temperature and pH of samples in the reactor was nearly the same. Total Organic Carbon (TOC) concentration of sample A and C were about 5500, 2900 mg/kg respectively. This sample was needed a lot of time to mature as viewing cation exchange capacity (CEC) after experiment was over. However added with gypsum and coal fly ash in Process of Pig manure composting Process was suggested that gypsum and coal fly ash have a roles of additive agent.

• Journal of environmental and Sanitary engineering
• /
• v.21 no.4 s.62
• /
• pp.77-86
• /
• 2006

The water purification was very important in Korea which has not sufficient water resource and while adsorption method among the various methods to eliminate the water pollutants has been widely used by activated carbon. This study was conducted the basic experiment for hall distribution, pH, conductivity, electronic microscope, cation exchange and inorganic materials the adsorption capacity of Korean traditional charcoal which has similar characteristics to activated carbon of organic pollutants. As a result of observing Korean traditional charcoal with electronic microscope, it was found that it has porous structure, oak charcoal has circular structure, pine charcoal has square structure and bamboo charcoal has hexagonal structure, which has high void fraction per unit area because of its thin cell wall structure. As a result of experimenting hall distribution, hall distribution of bamboo high temperature charcoal is high as 0.269cc/g and has the greatest inorganic contents and cation exchange capacity(CEC) which are the important factor of chemical adsorption.

• Journal of the Korean Wood Science and Technology
• /
• v.7 no.1
• /
• pp.3-7
• /
• 1979

A bark comprises about 10 to 20 percents of a typical log by volume, and is generally considered as an unwanted residue rather than a potentially valuable resources. As the world has been confronted with decreasing forest resources, natural resources pressure dictate that a bark should be a raw material instead of a waste. The utilization of the largely wasted bark of genus Pinus, Quercus and Populus grown in korea can be enhanced by Knowing its chemical Properties. Specially, uses of bark in mulching, growing media and soil amendment can be enhanced by knowing pH and C.E.C values. In this paper, an investigative study is carried out on the pH-and C.E.C-values. The results may be summarized as follows: 1. Bark is acid in nature, and pH values of bark varying from 3.3 to 4.7, is lower than that of wood.pH value of Pinus is the lowest. 2. Cation exchange capacity of bark is greater than that of wood, silt loam soil, and wheat straw.CEC of bark is 45.7 meq/100gm in Pinus, 41.8 meq/100gm in populus, 37.8 meq/100gm in Quercus.

• Bulletin of the Korean Chemical Society
• /
• v.31 no.8
• /
• pp.2201-2206
• /
• 2010

To improve the separation property and stability of metal chelate Cu(II) column, three new kinds of multidentate aminocarboxy silica columns with cation-exchange properties were synthesized using glutamic acid (Glu), glutamic acidbromoacetic acid (Glu-BAA), glutamic acid-bromosuccinic acid (Glu-BSUA) as ligands and silica gel as matrix. The standard proteins were separated with prepared chromatographic columns. The stationary phases exhibited the metal chelate property after fixing copper ion (II) on the synthesized multidentate ligand silica columns. The binding capacity of immobilized metal ion was related with the dentate number of multidentate ligands. Chromatographic behavior of proteins and the leakage of immobilized metal ion on multidentate chelate Cu(II) columns were affected by the dentate number of multidentate ligands and competitive elution system directly. The results showed that quinquedentate Glu-BSUA-Cu(II) column exhibited better chromatographic property and stability as compared with tridentate Glu-Cu(II) column, tetradentate Glu-BAA-Cu(II) column and commonly used IDA-Cu(II) column.

• Korean Journal of Soil Science and Fertilizer
• /
• v.11 no.3
• /
• pp.161-174
• /
• 1979

A review was made on the effect of organic matter application on the chemical characteristics of soils such as pH, solubilities of minerals, and cation exchange capacity mainly at flooded rice soils. The review can be summarized as follows: 1. Application of organic material such as rice straw and compost in flooded rice soil leads to a temporary lowering of soil pH at the earlier stage of soil reduction, due to the production of various organic acids and carbonic acid. This temporary lowered pH is replaced with the production of alkaline substances such as ammonia as the reduction of soil proceeds. 2. Incorporation of organic materials intensifies the ferrous iron, dissolving various minerals, virtually to the increase in electrical conductivity of soils. 3. Organic materials also play an important role in dissolving soil minerals through the production of various chelating agents. 4. Application of soil organic matter significantly increases cation exchange capacity of soils. 5. Continuous application of rice straw or compost leads to the increase in soil organic matter content to some extent, up to the level of equilibrium. In soils low in organic matter the equilibrium level is attained with five years continuous application of compost. 6. The manner of chemical fertilizer application influences the accumulation of organic matter applied in soils. Low levels of fertilization lowers the accumulation while high levels of fertilization accerelates the accumulation.

• Journal of The Korean Society of Grassland and Forage Science
• /
• v.11 no.1
• /
• pp.22-29
• /
• 1991

This study was experimented to obtain the basic information on the changeable aspect and improvement of soil fertility in newly-reclaimed sloped land. Silage corn was cultivated under the six different treatments for 4 years. The relation between the amount or ratio of annual changes of soil physico-chemical properties and yield of silage corn were analyzed. Soil bulk density was decreased in 3rd year at topsoil, but that decreased in 4th year at subsoil. Soil organic matter also decreased in 2nd year at topsoil, and decreased continuously at subsoil. Bulk density and hardness of soil depths showed significant negative simple correlation with dry matter yield and cation exchange capacity showed positive. Correlation coefficient of chemical properties with dry matter yield were low. The range of annual changes of moisture percent, hardness and organic matter were wider than the other properties. The significantly different of physical properties were higher than the chemical properties, and those of topsoil were higher than subsoil. According to multiple regression between yield and physico-chemical properties of subsoil, bulk density and cation exchange capacity were in the greatest contribution at the variations, but bulk density was greatest at the ratios.

• Proceedings of the Korean Environmental Sciences Society Conference
• /
• 1999.10a
• /
• pp.221-223
• /
• 1999

The adsorption and leaching of organophosphorus pesticide, EPN are investigated in Namwon soil(black volcanic soil), Aewol soil(very dark brown volcanic soil) and Mureung soil(dark brown nonvolcanic soil) sampled in Cheju Island. The organic matter of Namwon soil, Aewol soil and Mureung soil is 19.8%, 6.2%, 2.4%, respectively. The cation exchange capacity of Namwon soil, Aewol soil and Mureung soil is 24.8 meq/100g, 13.0 meq/100g, 9.5 meq/100g, respectively. The Freundlich constant, K value, is 89.4, 26.9 and 9.25 for Namwon soil, Aewol soil and Mureung soil, respectively. The K value of Namwon soil with very high organic matter content and cation exchange capacity was the highest for Aewol soil and Mureung soil. The Freundlich constant, 1/n, show a high correlation with organic matter content, i.e., it is less than unity for organic matter rich soil of Namwon soil and greater than unity for organic matter poor soil of Mureung soil. The leaching of EPN is slower for Namwon soil with high K values, and faster for Mureung soil with low K values. The results of the study is demonstrated the potential of pollution for EPN have little leached into soil environment.

• Polymer(Korea)
• /
• v.27 no.1
• /
• pp.75-83
• /
• 2003

Dicyanate-clay nanocomposite has been prepared by a melt in-situ polymerization method for different modifiers and cation exchange capacity (CEC) values in order to study dispersion and mechanical property. Various dicyanate nanocomposites were prepared by using different MMT systems containing different intercalants which led to different initial gallery heights and packing density. Depending on compatibility between dicyanate and clays, the degree of dispersion varied. Dispersion of clay plates in dicyanate resin depended mainly on CEC and aliphatic chain length of modifier. The lower CEC and shorter aliphatic chain length of modifier gave the exfoliation structure. It was also found that the reactivity of intercalant with dicyanate resin was one of the key factors facilitating the intercalation/exfoliation process of dicyanate/MMT nanocomposites. Shear modulus of reaction-induced dicyanate nanocomposite was significantly increased.

• Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
• /
• v.8 no.3
• /
• pp.173-179
• /
• 2010

In a HLW repository, the buffer is exposed to an elevated temperature due to a radioactive decay and geochemical conditions for a long time and such a hydrothermal condition may cause a significant loss of its barrier function. This study carried out hydrothermal tests with a domestic smectite clay to investigate the changes in the expandibility, layer charge, and cation exchange capacity of the smectite. When the temperature and potassium concentration in solution was increased for the hydrothermal treatments, the expandibility decreased, the layer charge negatively increased, and the CEC also decreased.

• Applied Chemistry for Engineering
• /
• v.10 no.2
• /
• pp.218-224
• /
• 1999

Continuous ion exchange characteristics of the synthetic coolant contained Ni, Co and Ag ions of low concentration in acidic-oxidizing conditions have been studied to suggest the guideline for the optimum operation of mixed-bed demincralizer during the shutdown period of a pressurized water reactor (PWR). In the effect of the form of cation resins on the removal capacity of metal ions, the performance of a $H^+$-form resin was about 6% higher than that of a $Li^+$-form resin. Mixed-bed of cation and anion resins in comparison with nonmixed-bed of them, had no affected on the removal capacity of metal ions but very slightly increased the slope of breakthrough curves of metal ions. In the effect related to acidic-oxidizing conditions of the coolant, the addition of boric acid very slightly decreased the slope of breakthrough curves of metal ions, while the addition of hydrogen peroxide slightly decreased the removal capacity of metal ions.