• Title/Summary/Keyword: Cathode pressure

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Characterization of Nitrogen Gas Crossover in PEM Fuel Cell Stacks (고분자 연료전지 스택에서 질소 크로스오버 특성에 관한 연구)

  • Baik, Kyung-Don;Kim, Min-Soo
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.33 no.3
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    • pp.207-214
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    • 2009
  • Crossover of nitrogen from cathode to anode is inevitable in typical membranes used in PEM fuel cells. This crossovered nitrogen normally accumulates in the hydrogen recirculation system at anode side channels. Excessive buildup of nitrogen in the anode side lowers the relative hydrogen concentration and finally affects the performance of fuel cell stack. So it is very important to analysis the nitrogen gas crossover at various operating conditions. In this study, characterization of nitrogen gas crossover in PEM fuel cell stack was investigated. The mass spectroscopy (MS) has been applied to measure the amount of the crossovered nitrogen gas at the anode exit. Results show that nitrogen gas crossover rate was affected by current density, anode and cathode stoichiometric ratio and operating pressure. Current density, anode stoichiometric ratio and anode operating pressure do not affect nitrogen crossover rate but anode exit concentration of nitrogen. Cathode pressure and stoichiometric ratio largely affect the nitrogen crossover rate.

Laterally Encapsulated Cathode Structure for DC Plasma Display Panels

  • Esfahani, M.Mokhlespour;Mohajerzadeh, S.;Goodarzi, A.;Rouhi, N.;Tarighat, R.S.
    • 한국정보디스플레이학회:학술대회논문집
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    • 2005.07b
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    • pp.1233-1236
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    • 2005
  • We report a novel approach for encapsulating of cathode electrodes in DC plasma pixels. Anode and cathode electrodes are laterally placed on a single substrate. The encapsulated electrode minimizes the sputtering of the cathode without significantly altering the turn-on voltage-pressure characteristics. An abnormal glow in current-voltage characteristics is also observed.

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Optimization study on fuel cell cathode oxygen flow path for Unmanned Aerial Vehicle using computational visualization (전산 가시화를 통한 무인 항공기용 연료전지 양극 산소 유로 최적화 연구)

  • Jeon, Ji-A;Lee, Jae-Jun;Song, Young-Su;Kim, Min-Su;Kim, Gun Woo;Na, Youngseung;Rhee, Gwang Hoon
    • Journal of the Korean Society of Visualization
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    • v.17 no.1
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    • pp.85-92
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    • 2019
  • Numerical visualization is conducted to confirm the variation of flow characteristics and pressure drop by the shape of channels on the cathode flow path in hydrogen fuel cells for unmanned aerial vehicles(UAVs). Generally, a light-weight fan is commonly used rather than a heavy air compressor at UAVS. However, in case of blower fan, a large pressure drop in the flow path causes the blocking of the oxygen supply to the fuel cell. Therefore, the uniformity of flow inside the cathode has to be achieved by changing the shape of the cathode. The flow channel, the duct shape, and the diameter of the fan are changed to optimize the flow path. As a result, it is confirmed that the optimal flow path can decrease the velocity difference between the center and outer flow by 1.8%. However, It should be noted that the channel size can increase the pressure drop.

Study on high performance cathode on YSZ electrolyte for intermediate-temperature solid oxide fuel cells(IT-SOFC) (중온형 고체산화물 연료전지를 위한 YSZ 전해질에서의 고성능 공기극 연구)

  • Lee, Chang-Bo;Bae, Joong-Myeon
    • 한국신재생에너지학회:학술대회논문집
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    • 2006.11a
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    • pp.368-371
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    • 2006
  • [ $La_{0.8}Sr_{0.2}Co_{1-x}Mn_xO_3$ ] cathode as a high performance cathode on YSZ electrolyte was studied by analyzing impedance spectra. It was shown that cathode property of $La_{0.8}Sr_{0.2}Co_{1-x}Mn_xO_3$ is bet ter than that of$La_{0.8}Sr_{0.2}CoO_3$. At $700^{\circ}C$ in air environment, $La_{0.8}Sr_{0.2}Co_{0.4}Mn_{0.6}O_3$ cathode on CGO- layered YSZ electrolyte showed very low area specific resistance of $0.14{\Omega}cm^2$, which is low enough for intermediate-temperature sol id oxide fuel cells. This is because material properties of ionic conductivity and thermal expansion compatibility with electrolyte were optimized. Judging from activation energy and oxygen part i al pressure dependance of cathode property, it was noted that oxygen surface exchange kinetics is dominantly influential on cathode property in higher temperature region than $700^{\circ}C$ and oxygen self-diffusion in cathode material is more influential in lower temperature region.

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Pressure Loss Analysis of the 75 kW MCFC Stack with Internal Manifold Separator (75 kW 용융탄산염 연료전지 (MCFC) 스택 내 압력 손실 해석)

  • Kim, Beom-Joo;Lee, Jung-Hyun;Kim, Do-Hyeong;Kang, Seung-Won;Lim, Hee-Chun
    • Transactions of the Korean hydrogen and new energy society
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    • v.19 no.5
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    • pp.367-376
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    • 2008
  • To obtain the data of the pressure loss and differential pressure at the inside of the stack that was composed of 126 cells with 7,500 cm2 electrode area, 75kW molten carbonate fuel cell system has been operated. Computational fluid dynamics was applied to estimate reactions and thermal fluid behavior inside of the stack that was adopted with internal manifold type separator. The pressure loss coefficient K showed 72.29 to 84.01 in anode and 6.34 to 8.75 in cathode at low part of cells at the inside of 75 kW MCFC stack respectively. Meanwhile, the pressure loss coefficient of the higher part of cells at the interior of the stack showed 15.36 and 56.44 in anode and cathode respectively. These results mean that there is no big total pressure difference between anode and cathode at the inner part of 75 kW MCFC stack. This result will be reflected in 250kW MCFC system design.

Modeling of PEM Fuel Cell System-Sensitivity Analysis of System Efficiency with Different Main Operating Parameters of Automotive Fuel Cell System (PEM 연료전지 시스템 모델링-자동차용 연료전지 시스템의 주요 작동 변수 변경에 따른 시스템 효율 민감도 분석)

  • KIM, HAN-SANG;KANG, BYUNGGIL;WON, KWONSANG
    • Transactions of the Korean hydrogen and new energy society
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    • v.30 no.5
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    • pp.401-410
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    • 2019
  • The operating conditions greatly impact the efficiency and performance of polymer electrolyte membrane (PEM) fuel cell systems and must be properly managed to ensure better performance and efficiency. In particular, small variations in operating conditions interact with each other and affect the performance and efficiency of PEM fuel cell systems. Thus, a systematic study is needed to understand how small changes in operating conditions affect the system performance and efficiency. In this paper, an automotive fuel cell system (including cell stack and balance of plant [BOP]) with a turbo-blower was modeled using MATLAB/Simulink platform and the sensitivity analyses of main operating parameters were performed using the developed system model. Effects of small variations in four main parameters (stack temperature, cathode air stoichiometry, cathode pressure, and cathode relative humidity) on the system efficiency were investigated. The results show that cathode pressure has the greatest potential impact on the sensitivity of fuel cell system efficiency. It is expected that this study can be used as a basic guidance to understand the importance of achieving accurate control of the fuel cell operating conditions for the robust operation of automotive PEM fuel cell systems.

Oxygen Permeability Characteristics of the Multi-Cathode Type Dissolved Oxygen Sensor Using the Low Noise Measuring Circuit (저잡음화 계측회로에 의한 다음극형 용존산소센서의 산소투과특성)

  • Rhie, Dong-Hee;Kim, T.J.;Kim, Y.H.;Sung, Yung-Kwon
    • Proceedings of the KIEE Conference
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    • 1998.11c
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    • pp.764-766
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    • 1998
  • An evaluation method for oxygen permeable characteristics of the membrane covering to each cathode of multiple cathode - single anode type dissolved oxygen sensor, which has high reproducibility and is capable of measuring multiple components in solutions. For this purpose, a measuring circuit for the multiple cathode type DO sensor was designed to lower the noise signal by adapting a digital LPF to readout the sensor output accurately. Digital LPF is designed by setting up the transfer function to set the cutoff frequency to 10Hz, and the transfer function is programmed by C language, and then the filtering characteristics are evaluated with the simulation and experiments. Using this LPF added measuring circuit for the multiple cathode type DO sensor, we have obtained the calibration factor for each cathode to calibrate the variation of the output signals. The calibration factor was obtained by measuring the sensor output signal followed by oxygen partial pressure, using the same oxygen permeable membrane at each cathode of the multiple cathode type DO sensor.

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A study on the A.C. arc movement in a transverse A.C. magnetic field at atmospheric pressure (황축교류자계에 의한 대기중에서의 교류 아아크의 이동에 관한 연구)

  • 전춘생;엄기환
    • 전기의세계
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    • v.24 no.6
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    • pp.77-84
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    • 1975
  • This paper treats A.C. arc movement in a transverse A.C. magnetic field at atmospheric pressure with the purpose of selecting electrode materials and obtaining detailed data for design of A.C. air circuit breaker, plasma accelerator and plasma jet. Arc velocities in transverse magnetic field are measured by varying arc current, arc voltage, gap length, magnetic flux density and the erosion of electrode surface, which influence arc velocities. The main results are; 1)Arc velocities in transverse magnetic field have different values according to electrodes of various materials and decrease in a descending order of cold cathode, medium cathode and hot cathode. 2)Arc velocities in transverse magnetic field increases with arc current, arc voltage, gap length and magnetic flux densith and on the other hand decrease with the increase of electrode surface erosion. 3)D.C.arc velocity in D.C. magnetic field is higher than A.C. arc velocity in A.C. magnetic field of the same value.

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Cathode Power Development of Hall Thruster for Small Satellite using Microwave cathode (마이크로웨이브 음극을 이용한 소형 인공위성의 홀 추력기용 음극전원 개발)

  • Kang, Seokhyun;Choo, Wongyo;Choi, Junku;Jeong, Yunhwang;Kim, Younho;Kang, Seongmin;Kuninaka, Hitoshi;Cha, Hanju
    • Journal of the Korean Society for Aeronautical & Space Sciences
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    • v.42 no.11
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    • pp.974-980
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    • 2014
  • A power supply of cathode has been developed for hall-effect thruster for small satellite. A microwave cathode has been applied to the electric propulsion system and cathode power is necessary in oder to work securely. Anode current is varied by a flow rate controlled by anode tank pressure. Then cathode current has to be controled in proportion by anode current. So cathode power supply has been designed to offer a current proportional to anode current. Also cathode power has been tuned to work securely for cathode to emit more electron than anode within 0.03A. The function test of cathode power was performed by constructing an equivalent load for anode and cathode. It has been tested in a vacuum chamber in order to ensure a stable operation of the thruster. And it was confirmed that thruster normally has been operated in the space environment after the launch.

A study on the relationships between plasma parameters and magnetic field (플라즈마 파라메타와 자계의 상관관계에 관한 연구)

  • 김두환;장윤석;조정수;박정후
    • The Transactions of the Korean Institute of Electrical Engineers
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    • v.45 no.3
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    • pp.426-431
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    • 1996
  • It is well known that the understanding of the complex mechanism of magnetoplasma is closely related with understanding of the collective behavior of discharge plasma parameters such as the cathode-sheath potential, cathode-sheath thickness, electron temperature, electron density, and ambipolar diffusion. In this paper, some of the relationships between these plasma parameters and magnetic field is investigated experimentally with a Langmuir probe in the magnetoplasma generated by D.C diode system. It is found that when magnetic field is increased, cathode-sheath potential, cathode-sheath thickness, and ambipolar diffusion are decreased. In addition, peak ion density obtained as a parameter of ionic signal voltage by Faraday cup method is independent of magnetic field. (author). 9 refs., 11 figs.,1 tab.

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