• Title/Summary/Keyword: Cathode catalyst

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Fabrication and Characteristics of CNT-FEAs with Under-gate Structure

  • Noh, Hyung-Wook;Jun, Pil-Goo;Ko, Sung-Woo;Kwak, Byung-Hwak;Park, Sang-Sik;Lee, Jong-Duk;Uh, Hyung-Soo
    • 한국정보디스플레이학회:학술대회논문집
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    • 2005.07b
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    • pp.1470-1473
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    • 2005
  • We proposed new triode-type Field Emitter Arays using Carbon NanoTubes(CNT-FEAs) as electron emission sources at low electric fields. The CNTs were selectively grown on the patterned catalyst layer by Plasma-Enhanced Chemical Vapor Deposition (PECVD). In this structure, gate electrodes are located underneath the cathode electrodes and extracted gate is surrounded by CNT emitters. Furthermore, in order to control density of CNTs, we investigated effect of using rapid thermal annealing (RTA).

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Lithium Air Battery: Alternate Energy Resource for the Future

  • Zahoor, Awan;Christy, Maria;Hwang, Yun-Ju;Nahm, Kee-Suk
    • Journal of Electrochemical Science and Technology
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    • v.3 no.1
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    • pp.14-23
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    • 2012
  • Increasing demand of energy, the depletion of fossil fuel reserves, energy security and the climate change have forced us to look upon alternate energy resources. For today's electric vehicles that run on lithium-ion batteries, one of the biggest downsides is the limited range between recharging. Over the past several years, researchers have been working on lithium-air battery. These batteries could significantly increase the range of electric vehicles due to their high energy density, which could theoretically be equal to the energy density of gasoline. Li-air batteries are potentially viable ultra-high energy density chemical power sources, which could potentially offer specific energies up to 3000 $Whkg^{-1}$ being rechargeable. This paper provides a review on Lithium air battery as alternate energy resource for the future.

Nano Catalysts for Proton Exchange Membrane Fuel Cells

  • Kim, Su-Gil;Hwang, Seung-Jun;Im, Ji-Eun;Yu, Seong-Jong;Lee, Seung-Cheol;Im, Tae-Hun
    • Proceedings of the Materials Research Society of Korea Conference
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    • 2012.05a
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    • pp.71.1-71.1
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    • 2012
  • Proton Exchange Membrane Fuel Cells (PEMFCs) have been of great interest particularly in the automobile industries because of their high energy density and low pollutant emission. However, some of the issues such as, the necessarily high contents of Pt catalysts and their slow kinetics of cathode oxygen reduction reaction remain as obstacles in the commercialization of the PEMFC. In this presentation, after brief explanation on basic principles of PEMFC and its application to FC vehicles, recent researches to improve the activity and durability of Pt-based nano catalysts toward oxygen reduction will be introduced. It covers size and shape control of Pt nano particle, binary and ternary Pt-M alloys, novel core-shell nano structures of Pt, and a little bit about non-Pt catalysts. Strategies and methodologies for design and synthesis of novel catalysts will also be included.

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Cell Design for Mixed Gas Fuel Cell (혼합가스 주입형 연료전지를 위한 전지 디자인)

  • Park, Byung-Tak;Yoon, Sung Pil
    • Journal of the Korean Ceramic Society
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    • v.42 no.12 s.283
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    • pp.860-864
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    • 2005
  • In this study, we fabricated honeycomb type Mixed-Gas Fuel Cell (MGFC) which has advantages of stacking to the axial direction and increasing volume power density. Honeycomb-shaped anode with four channels was prepared by dry pressing method. Two alternative channels were coated with electrolyte and cathode slurry in order to make cathodic reaction sites and the others were filled with partial oxidation (POX) catalyst to increase fuel conversion. Furthermore we employed the sol-gel technique which can increase cell performance and decrease carbon coking.

Effects of Selective Growth on Electron-emission Properties of Conical-type Carbon Nanotube Field-emitters (원추형 기판 위에 탄소 나노튜브의 선택적 성장이 전계방출 특성에 미치는 영향)

  • Kim, Bu-Jong;Noh, Young-Rok;Park, Jin-Seok
    • Journal of the Semiconductor & Display Technology
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    • v.11 no.1
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    • pp.61-65
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    • 2012
  • In this study, for use of carbon nanotubes (CNTs) as a cold cathode of x-ray tubes, we examine the effects of selective growth of CNTs on their field emission properties and long-term stability. The selective growth of CNTs was performed by selectively etching the catalyst layer which was used for CNTs' nucleation. CNTs were grown on conical-type tungsten substrates using an inductively-coupled plasma chemical vapor deposition system. For all the grown CNTs, their morphologies and microstructures were analyzed by field-emission scanning electron microscope and Raman spectroscopy. The electron-emission properties of CNTs and the long-term stability of emission currents were measured and characterized according to the CNTs' growth position on the substrate.

Carbon Corrosion at Pt/C Interface in Proton Exchange Membrane Fuel Cell Environment

  • Choi, Min-Ho;Beom, Won-Jin;Park, Chan-Jin
    • Corrosion Science and Technology
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    • v.9 no.6
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    • pp.281-288
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    • 2010
  • This study examined the carbon corrosion at Pt/C interface in proton exchange membrane fuel cell environment. The Pt nano particles were electrodeposited on carbon substrate, and then the corrosion behavior of the carbon electrode was examined. The carbon electrodes with Pt nano electrodeposits exhibited the higher oxidation rate and lower oxidation overpotential compared with that of the electrode without Pt. This phenomenon was more active at $75^{\circ}C$ than $25^{\circ}C$. In addition, the current transients and the corresponding power spectral density (PSD) of the carbon electrodes with Pt nano electrodeposits were much higher than those of the electrode without Pt. The carbon corrosion at Pt/C interface was highly accelerated by Pt nano electrodeposits. Furthermore, the polarization and power density curves of PEMFC showed degradation in the performance due to a deterioration of cathode catalyst material and Pt dissolution.

Electrochemical Characteristic Analysis based on Various Electrode's Condition of a PEMFC (PEMFC내 가변적인 전극조건에 따른 전기화학적 특성분석)

  • Nam, Y.;Kim, J.H.;Choi, H.J.;Tak, Y.S.
    • Proceedings of the KIPE Conference
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    • 2017.07a
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    • pp.461-462
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    • 2017
  • 가장 대표적인 연료전지인 고분자 전해질 연료전지(PEMFC; polymer electrolyte membrane fuel cell)은 두 개의 전극으로 이루어지며, 각 전극(electrode)에 공급되는 수소(anode)와 공기(cathode)의 원활한 반응을 위해 촉매(catalyst)로서 백금(Pt)을 사용한다. 이 때, 촉매의 실험 조건에 따라 연료전지 두 전극의 반응이 달라지므로 촉매의 가변성 즉, 가변적인 전극 조건에 따른 전기화학적 특성이 면밀히 분석되어야 한다. 그러므로, 본 논문에서는 촉매의 변화에 기인한 가변적인 전극 특성에 따른 연료전지의 전기화학적 특성 분석을 실시하였다.

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Development of new cleaning technology using ionized water by electrolysis (전기분해 이온수를 이용한 세정기술 개발)

  • 변문기;백희원;조봉희;김영호
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1999.11a
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    • pp.617-620
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    • 1999
  • To reduce the consumption of chemicals and ultra pure water(UPW) in cleaning process used in device manufacturing, we proposed wet processes that use electrolytic ionized water(EIW), which is generated by electrolysis of a diluted electrolyte solution or UPW and systemically investicate the EIW\`s characteristics. EIW\`s pH values are increased in cathode chamber and decreased in anode chamber according to the electrolysis time and its varied ratio is reduced with time increasement. The variation of pH and ORP is increased accordin to the applied voltage until critical voltage. But more than that voltage, the variation is decreased because of ion\`s scattering effect. When electrolyte is added, the effects of electrolysis is increased because electrolyte acts as catalyst. But when the density of electrolyte is increased more than critical value, ion\`s flowage is obstructed and the effects of electrolysis is decreased.

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A study for development of high speed hard chrome plating solution (고속 경질 크롬 도금 용액 개발에 관한 연구)

  • 추현식;이홍로
    • Journal of the Korean institute of surface engineering
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    • v.25 no.5
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    • pp.263-269
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    • 1992
  • To enhancing efficiency of hard chrome plating solution more highly, cathode current efficiency were surveyed connected with hardness of deposits, surface morphology, TEM analysis and corrosion test of anode materials. Efficiency war increased up to 26% values by adding catalyst and two kind of additives. With given bath composition and 6$0^{\circ}C$, 60A/d$\m^2$ electrolosis conditionss bright and micro cracked deposits were well obtained, which showed HV 1000 values. From corrosion tests, anode materials such as Pb-Te (0.02%) and Pb-Ag(1%) showed most anti-corrosive results. Through SEM micrograph observations, ef-fects of additives on levelling, brightness and micro crack properties of hard chrome deposits could be con-firmed. Also, through TEM analysis the fact that deposits from crack free solution or high speed solution were more fine than from sargent solution could be confirmed.

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A Study on the RuO2 Electrode Catalyst Prepared by Colloidal Method (콜로이드법으로 합성한 RuO2 전극촉매의 연구)

  • PARK, JIN-NAM
    • Transactions of the Korean hydrogen and new energy society
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    • v.30 no.3
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    • pp.193-200
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    • 2019
  • $RuO_2$, $PtO_2$, and various $(Ru,Pt)O_2$ colloidal solution were prepared using modified Watanabe method. Electrodes were manufactured by dipping of Ni mesh into the colloidal solution. Manufactured electrodes were characterized by XRD, SEM, and EDS. $(Ru,Pt)O_2$ electrodes showed $RuO_2$ crystal structure and high roughness. The hydrogen evolution reaction (HER) activities were evaluated by Linear Sweep Voltammetry. 1Ru2Pt electrode showed similar activity with commercial electrode, HER potentials are -0.9 V for both.