• Title/Summary/Keyword: Catalytic burner

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Operating Characteristics of LNG burner for Steam Reforming of Natural Gas (천연가스 수증기개질 반응용 LNG 버너의 운전 특성)

  • Shin, Jang-Sik;Park, Jong-Won;Yang, Hye-Kyong;Lee, Seung-Young;Song, Bong-Hyun;Shin, Seock-Jae
    • 한국신재생에너지학회:학술대회논문집
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    • 2006.11a
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    • pp.477-480
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    • 2006
  • In this study, we investigated operating characteristics of the LNG burner for steam methane reforming. The developed LNG burner and catalytic reactor to supply an efficient heat transfer between the combustion gas and catalyst got a good response of various operating load within 5-7 minute and high efficiency for steam methane reforming as a conversion of methane over 90%. We calculated the volume of catalyst for $1Nm^3/hr$ steam LNG reforming as $211cc/(Nm^3/hr\;H_2)$ and got the operating condition and design data of the burner and steam reforming for LNG.

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Performance Evaluation for Fast Conversion from Urea to an Ammonia Conversion Technology with a Plasma Burner (플라즈마 버너를 적용한 요소수에서 암모니아로의 고속 전환 기술 성능 평가)

  • Jo, Sungkwon;Kim, Kwan-Tae;Lee, Dae Hoon;Song, Young-Hoon
    • Journal of Korean Society for Atmospheric Environment
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    • v.32 no.5
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    • pp.526-535
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    • 2016
  • Recently, fine dust in atmosphere have been considerably issued as a harmful element for human. Nitrogen oxide ($NO_x$) exhausted from diesel engines and power plants has been disclosed as a main source of secondary production of fine dust. In order to prevent exhausting these nitrogenous compounds into atmosphere, a treatment system with selective catalytic reduction (SCR) catalyst with ammonia as a reductant has been used in various industries. Urea solution has been widely studied to supply ammonia into a SCR catalytic reactor, safely. However, the conversion of urea solution to ammonia has several challenges, especially on a slow conversion velocity. In the present study, a fast urea conversion system including a plasma burner was suggested and designed to evaluate the performances of urea conversion and initial operation time. A designed lab-scale facility has a plasma burner, urea nozzle, mixer, and SCR catalyst which is for hydrolysis of isocyane. Flow rate of methane that is a fuel of the plasma burner was varied to control temperatures in the urea conversion facility. From experimental results, it is found that urea can be converted into ammonia using high temperature condition of above $400^{\circ}C$. In the designed test facility, it is found that ammonia can be produced within 1 min from urea injection and the result shows prospect commercialization of proposed technology in the SCR facilities.

Characteristics of Catalytically Supported Combustion for Gas Turbine Catalytic Combustor;Effects of the inlet shape of catalytic burner (가스터빈용 촉매 연소기를 위한 촉매-화염 복합 연소 특성연구;촉매버너 입구 형상의 영향)

  • Lee, Kyung-Won;Chung, Nam-Jo;Ryu, In-Soo;Cho, Sung-June;Seo, Yong-Seog;Kang, Sung-Kyu;Song, Kwang-Sup;Chun, Kwang-Min
    • 한국연소학회:학술대회논문집
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    • 2002.11a
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    • pp.71-79
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    • 2002
  • The characteristics of the catalytically supported combustion with Pd and Pd/Pt based catalyst using the bench-scaled high pressure combustor have been investigated up to 5atm. This study aimed to investigate combustion characteristics of the stable flame attached to the exit of catalyst bed and NOx emissions with respect to the position of axial and radial direction in the combustor. NOx emissions were increased along the axial distance after the catalyst bed exit and radially decreased from the center to the wall of the combustor. At the higher pressure, the NOx emission decreased slightly due to the lower flame temperature in the combustor at the high pressure.

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Design of LQR Controller for Thermal Management System of 5kW Solid Oxide Fuel Cell (5kW급 고체 산화물 연료전지 열관리 계통 LQR 상태 궤환 제어기 설계)

  • Jeong, Jin Hee;Han, Jae Young;Sung, Yong Wook;Yu, Sang Seok
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.39 no.6
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    • pp.505-511
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    • 2015
  • Solid oxide fuel cell operate at high temperature ($800{\sim}1000^{\circ}C$). High temperature have an advantage of system efficiency, but a weak durability. In this study, linear state space controller is designed to handle the temperature of solid oxide fuel cell system for proper thermal management. System model is developed under simulink environment with Thermolib$^{(R)}$. Since the thermally optimal system integration improves efficiency, very complicated thermal integration approach is selected for system integration. It shows that temperature response of fuel cell stack and catalytic burner are operated at severe non-linearity. To control non-linear temperature response of SOFC system, gain scheduled linear quadratic regulator is designed. Results shows that the temperature response of stack and catalytic burner follows the command over whole ranges of operations.

The Ejector Design and Test for 125 kW Class Molten Carbonate Fuel Cell System (125 kW급 용융탄산염 연료전지 시스템의 이젝터 설계 및 시험)

  • KIM, BEOMJOO;PARK, SOO-MAN;SONG, OH-SEOP
    • Transactions of the Korean hydrogen and new energy society
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    • v.29 no.2
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    • pp.139-147
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    • 2018
  • Korea Electric Power Research Institute (KEPCO RI) had developed molten carbonate fuel cell (MCFC) system since 1993. Finally, KEPCO RI developed and operated a 125 kW MCFC system in 2010. To make MCFC system compact, it is indispensable to install an ejector in this system where the anode off gas, the cathode off gas, and fresh air are mixed before flowing to the catalytic burner. KEPCO RI had developed various ejectors for MCFC system since 2006. The 125 kW MCFC system built with the developed ejector was operated successfully in Boryeong Thermal Power Plant in 2010. This 125 kW MCFC ejector was designed on the basis of the experimental results of 5 kW and 75 kW MCFC ejectors. The main goal of ejector design in our MCFC system is to maintain the entrainment ratio and the pressure between fuel cell stack and catalytic burner within the operating range. In this paper, the design results of the ejector are presented based on the 125 kW MCFC system operating conditions. In addition, a designed ejector was manufactured and installed in the MCFC system. As the fuel cell is under load operation, the pressure surrounding the ejector was measured to ensure that the fuel cell system is operating smoothly.

Trend of Nitrogen Oxide Reduction Technologies in Cement Industry (시멘트 산업에서의 질소산화물 저감 기술 동향)

  • Seo, JunHyung;Kim, YoungJin;Cho, KyeHong;Cho, JinSang;Han, KyungHo;Yoon, DoYoung
    • Resources Recycling
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    • v.29 no.6
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    • pp.114-124
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    • 2020
  • In the cement industry, NOx emission is recognized as an important problem, and NOx reduction technologies can be divided into process change, staged combustion, low NOx burner, selective non-catalytic reduction and selective catalytic reduction method. The operation of the selective non-catalytic reduction method, which is the most used in the cement industry, is expected to make it difficult to meet the emission standards to be strengthened in the future, and it is necessary to improve equipment such as SCR and secure technologies. Recently, we are developing technologies for simultaneous application of SNCR and SCR, dust and denitrification filter technology, and removal technology using NO oxidation.

Evaluation of NOx Reduction Efficiency and Emission Factor from Large Combustion Facilities in Seoul (서울지역 대형연소시설에서의 질소산화물 제거효율과 배출계수 산정)

  • 신진호;오석률;김정영;전재식;신정식
    • Journal of environmental and Sanitary engineering
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    • v.18 no.2
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    • pp.27-33
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    • 2003
  • This survey was performed to investigate the NOx emission factors at 3 Municipal Solid Waste Incinerators(MSWI) and 5 Power generation boilers in Seoul. The NOx concentrations were measured before and after control systems. The results were as follows. 1) The NOx reduction efficiencies of Selective Catalytic Reduction (SCR) using ammonia as reducing agent ranged from 53.7% to 89.9%. The NOx reduction efficiencies of SCR using methanol as reducing agent, Non- Selective Catalytic Reduction (NSCR) using ethanol as reducing agent and low-NOx burner were 20.8%, 29.1% and 24.7%, respectively. 2) The NOx emission factors at A-1, A-2 and A-3 facilities of MSWI were 0.786, 0.127 and 0.594 kg Nox/ton fuel, respectively. The factors of A-1 and A-3 facilities were higher than the average value of Korea. 3) The NOx emission factors at B-1, B-2, B-3, B-4 and B-5 facilities of Power generation boiler were 2.109, 0.726, 4.106, 8.378 and 5.168 kg Nox/ton fuel, respectively. The factors of B-4 and B-5 facilities were higher than the average value of Korea.

Parametric Study of an Integrated Steam Methane Reformer with Top-Fired Combustor (통합 수증기 개질 시스템의 작동 조건에 대한 수치적 연구)

  • Noh, Jung-Hun;Jung, Hye-Mi;Kim, Donghee;Um, Sukkee
    • 한국신재생에너지학회:학술대회논문집
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    • 2011.05a
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    • pp.156.1-156.1
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    • 2011
  • It is of great importance to predict operating parameter characteristics of an integrated fuel processor by the increased life-time and system performance. In this study, computational analysis is performed to gain fundamental insights on transport phenomena and chemical reactions in reformer which consists of preheating, steam reforming, and water gas shift reaction beds. Also, a top-fired burner locates inside of the reforming system. The combustor is providing thermal energy necessary for the steam reforming bed which is a endothermic catalytic reactor. Two-dimensional numerical model of the integrated fuel processing system is introduced for the analysis of heat and mass transport phenomena as well as surface kinetics and catalytic process. A kinetic model was developed and then computational results were compared with the experimental data available in the literature. Subsequently, parameter study using the validated steam methane reforming model was conducted by considering operating parameters, i.e. steam to carbon ratio and temperature.

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The Effects of Advanced Reburning with SNCR on NOx and CO Reduction (무촉매 환원법이 적용된 응용 재연소 방법에 의한 NOx와 CO의 저감 효과)

  • Lee Chang-Yeop;Kim Dong-Min;Baek Seung-Wook
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.30 no.8 s.251
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    • pp.788-795
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    • 2006
  • From the view of the environmental protection against the use of fossil fuels, the great of efforts have been exerted to find an effective method which is not only pollutant reduction but also high thermal efficiency. Reburning is a useful technology in reducing nitric oxide through injection of a secondary hydrocarbon fuel. In this paper, an experimental study has been conducted to evaluate the hybrid effects of reburning and selective non-catalytic reaction (SNCR) on $NO_x/CO$ reduction from oxygen-enriched LPG flame. Experiments were performed in flames stabilized by a co-flow swirl burner, which was mounted at the bottom of the furnace. Tests were conducted using LPG gas as main fuel and also as reburn fuel. The paper reported data on flue gas emissions, temperature distribution in furnace and various heat fluxes at the wall for a wide range of experimental conditions. Overall temperature in the furnace, heat fluxes to the wall and $NO_x$ generation were observed to increase by oxygen-enriched combustion, but due to its hybrid effects of reburning and SNCR, $NOx/CO$ concentration in the downstream has considerably decreased.

Process Modeling and Fuel Utilization Analyses of a 7 kW MCFC System using ASPEN PLUS (ASPEN PLUS를 이용한 7 kW 용융탄산염형 연료전지 시스템의 공정모사 및 연료 이용률 분석)

  • 강병삼;안교상;고준호;임희천
    • Journal of Energy Engineering
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    • v.8 no.1
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    • pp.85-94
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    • 1999
  • 전력연구원에서 수행 중인 7 kW 용융탄산염형 연료전지 시스템의 운전 조건과 일치하는 모델을 in-Line FORTRAN 블록을 이용하여 상용 소프트웨어인 ASPEN PLUS로 전산 모사한 결과와 가스 크로마토그래피를 이용하여 분석한 실험적인 값을 비교 분석한 결과 실험치와 거의 일치함을 보였다. 향후 대형 시스템에서 사용하게될 가스 recycle을 위해서 연료극, 공기극의 가스를 recycle할 때와 연료극 가스를 catalytic burner를 이용하여 recycle하였을 때 연료의 전체적인 시스템의 효율 변화를 살펴보았다. 이러한 결과는 용융탄산염 연료전지 대형 시스템의 설계에 중요한 자료가 될 것이다.

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