• Carbon letters
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• v.6 no.1
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• pp.41-46
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• 2005

Plasma carbon blacks of 20~30 nm diameter were synthesized by direct decomposition of natural gas using a hybrid plasma torch system with 50 kW direct current and 4 MHz of radio frequency. The insulating rector which inside diameter of 400 mm and length of 1500 mm, respectively was kept at 300~$400^{\circ}C$ during the preparation. The ultimate analysis of plasma carbon blacks reveals that the raw plasma carbon blacks contains a large quantity of volatile which is mainly consist of hydrogen. Therefore devolatilization of raw plasma carbon blacks were carried out at $900^{\circ}C$ for one hour under nitrogen atmosphere. The devolatilization leads to the decrease in electrical resistivity and surface oxygen functional groups of plasma carbon black significantly. In order to investigate the plasma carbon as a catalyst support, devolatilized plasma black at $900^{\circ}C$ (DPB) supported PtAu catalyst was synthesized by sodium boronhydride reduction method. Electrochemical measurements and direct formic acid fuel cell test indicated that catalytic activity of DPB supported PtAu catalyst for formic acid oxidation was similar to that of Vulcan XC-72 of commercial carbon black supported one.

• Journal of ILASS-Korea
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• v.20 no.3
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• pp.149-155
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• 2015

With increasing of GDP, the registration number of passenger cars has exceeded 20 million last year in Korea. Especially, the registration number of the diesel engine vehicles has been increasing. However, the WHO(World Health Organization) IARC (International Agency for Research on Cancer) has reported that diesel engine exhaust gas is an one of HAPs, which has carcinogenic for human, and they have designated it to Group 1. To solve this problem, exhaust gas from diesel engines has to be controlled. Thus, it has been controlling by European regulatory standard in Korea. On the other hand, in order to meet the enhanced emission regulations, all manufacturing company applied $NO_x$ control device to vehicles such as EGR (Exhaust Gas Recirculation), SCR (Selective Catalytic Reduction) and so on. However, these devices (EGR, SCR) were operated by difference reaction mechanism respectively, and the composition of exhaust gas would be differenced from that of them. In this study, it was conducted to evaluate variety characteristics on changing of exhaust gas composition by each $NO_x$ control device, and the heavy duty diesel trucks were chosen as experimental vehicles. From the result, it revealed that vehicles (with EGR) were discharged higher THC as 52.5% than that of others (with SCR). However, it did not followed that trend, in the case of CO; it was discharged as 57.2% lower than that of others (with SCR). In the future, these data would be used to apply to efficient $NO_x$ control device for meeting to EURO 6.

• Journal of Advanced Marine Engineering and Technology
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• v.36 no.6
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• pp.814-822
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• 2012

To improve the flow and mixing characteristics of marine SCR system, two different mixer including up-down and swirl type mixer were considered. The purpose of this study is to analyse turbulence intensity and uniformity index in detail and to improve the performance of SCR with respect to the mixer structure. The results showed that, the concentration uniformity index is improved by about 5% with the utilization of both mixers in the front of catalyst part. Although the RMS value and relative turbulence intensity increased after the up-down type mixer, it could observed that the value of two parameters decreased with the flow proceeding forward to the downstream. For the case of swirl type mixer, the decrease of RMS value and relative turbulence intensity were relatively smaller than that of up-down type mixer, and uniform distribution of relative turbulence intensity was observed. As a results, it could be concluded that the mixing effects and the distance of the two kinds of mixer were different.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.40 no.1
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• pp.1-7
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• 2016

A Urea-SCR(Selective Catalytic Reactor) system, which converts nitrogen oxides into nitrogen and water in the presence of a reducing agent, creates a major exhaust gas aftertreatment system for NOx reduction among other compounds. With regard to vehicle applications, a urea solution was chosen based on its eutectic composition of a 32.5wt% urea-water solution. An important advantage of this eutectic composition is that its melting point of $-11.7^{\circ}C$ is sufficiently low to avoid solidification in cold environments. However, the storage tanks must be heated separately in case of low ambient temperature levels to ensure a sufficient amount of liquid is available during scheduled start ups. In this study, therefore, a numerical investigation of three-dimensional unsteady heating problems analyzed to understand the melting processes and heat transfer characteristics including liquid volume fraction, temperature distributions, and temperature profiles. The investigations were performed using Fluent 6.3 commercial software that modeled coolant and electric heater models based on a urea solution. It is shown that the melting performance with the electric heater is higher than a coolant heater and is more efficient.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.34 no.7
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• pp.689-696
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• 2010

The Because of its high thermal efficiency, the direct injection (DI) diesel engine has emerged as a promising potential candidate in the field of transportation. However, the amount of nitrogen oxides ($NO_x$) increases in the local high-temperature regions and that of particulate matter (PM) increases in the diffusion flame region during diesel combustion. In the de-$NO_x$ system the Lean $NO_x$ Trap (LNT) catalyst is used, which absorbs $NO_x$ under lean exhaust gas conditions and releases it in rich conditions. This technology can provide a high $NO_x$-conversion efficiency, but the right amount of reducing agent should be supplied to the catalytic converter at the right time. In this research, the emission characteristics of a diesel engine equipped with a micro-reformer that acts as a reductants-supplying equipment were investigated using an LNT system, and the effects of the exhaust-gas temperature were also studied.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.32 no.11
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• pp.897-905
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• 2008

Selective catalytic reduction(SCR) is known as one of promising methods for reducing $NO_x$ emissions in diesel exhaust gases. $NO_x$ emissions react with ammonia in the catalyst surface of SCR system at working temperature of catalyst. In this study, to raise the reacting temperature when the exhaust gas temperature is too low, a heater is located at the bottom of SCR reactor. At an ambient temperature, ammonia is radially injected perpendicular to the exhaust gas flow at inlet pipe and uniformly mixed in the mixing area after being impinged against the wall. To predict the turbulent model inside the mixing area of SCR system, the standard ${\kappa}\;-\;{\varepsilon}$ model is applied. This work investigates numerically the effects of induced heat on the gaseous flow. The results show that the Taylor-$G{\ddot{o}}rtler$ type vortex is generated after the gaseous flow impinges the wall in which these vortices influence the temperature distribution. The addition of heat disturbs the flow structure in bottom area and then stretching flow occurs. Vorticity strand is also formed when heat is continuously increased. Constriction process takes place, however, when a further heat input over a critical temperature is increased and finally forms shed vortex which is disconnected from the vorticity strand. The strong vortex restricts the heat transport in the gaseous flow.

• Applied Chemistry for Engineering
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• v.26 no.6
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• pp.666-673
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• 2015

In this paper the selective reduction catalyst (SCR) for controlling the NOx at high temperature range was studied. XRD and FT-IR BET analysis was also performed to determine the structural properties and adsorption/desorption characteristics of the catalyst. In the case of anatase $TiO_2$ support, a negligible NOx conversion was observed, but the $W/TiO_2$ catalyst made using W as a active metal showed an excellent ability to remove NOx. In particular, the $W/TiO_2$ exhibited a rapid increase in the catalytic activity due to the presence of W for the NOx conversion compared to that of using the pure $TiO_2$ at a high temperature range over $400^{\circ}C$. In addition, the phenomenon of reduced reaction activity due to the heat shock for a long time was found to be suppressed.

• Journal of the Korean Society of Propulsion Engineers
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• v.9 no.4
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• pp.1-8
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• 2005

An experimental investigation of a microthruster that uses hydrogen peroxide as a monopropellant is described. The study comprises of preparation method of silver as a catalyst and performance evaluation of a mesoscale reactor. Reduction of silver in $H_2\;at\;500^{\circ}C$ resulted in the best reactivity of all the treatment method tested. A mesoscale reactor was built to find the optimum configuration for full decomposition of propellant. The catalyst bed was made of a glass wafer substrate sputtered with silver and had a length of 20 mm. We measured the conversion rate with varying feed rate of $H_2O_2$ and preheating temperature. With the feed rate of $H_2O_2$, the space time within the reactor varies as well. For the bed length of 20 mm, space time more than 480 s was required for full conversion.

• Journal of the Korean Chemical Society
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• v.56 no.5
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• pp.571-576
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• 2012

A sol-gel derived carbon composite electrodes (CCEs) were fabricated by mixing horseradish peroxidase (HRP), sol of tetraethoxysilane (TESO), and graphite powder. The HRP solution was added to the sol solution of TEOS, and then graphite powder was added to this mixture. The resulting carbon ceramic network effectively encapsulated HRP and shows a catalytic reduction starting at -0.2 V for $H_2O_2$. The optimum conditions for $H_2O_2$determination have been characterized with respect to the enzyme loading ratio and pH. The linear range and detection limit of $H_2O_2$ detection were from 0.2 mM to 2.2 mM and 0.035 mM, respectively. The common electroactive interferences such as ascorbic acid, acetaminophene, and uric acid were not affected upon the response to $H_2O_2$ at the HRP biosensor due to low detection potential.

• Journal of Hydrogen and New Energy
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• v.26 no.4
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• pp.339-346
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• 2015

The synthesis of Fischer-Tropsch (FT) oil is the catalytic hydrogenation of CO to give a range of products, which can be used for the production of high-quality diesel fuel, gasoline and linear chemicals. This studied catalyst was prepared Cobalt-supported alumina and silica by the incipient wet impregnation of the nitrates of cobalt, promoter and organic solvent with supports. Cobalt catalysts were calcined at $350^{\circ}C$ before being loaded into the FT reactors. After the reduction of catalyst has been carried out under $450^{\circ}C$ for 24h, FT reaction of the catalyst has been carried out at GHSV of 4,000/hr under $200^{\circ}C$ and 20atm. From these experimental results, we have obtained the results as following; In case of $SiO_2$ catalysts, the activity of 12wt% $Cobalt-SiO_2$ synthesized by organic solvent was about 2 or 3 times higher than the activity of 12wt% $Cobalt-SiO_2$ catalyst synthesized without organic solvent. In particular, the activity of the $Cobalt-SiO_2$ catalyst prepared in the presence of an organic solvent P was two to three times higher than that of the $Cobalt-SiO_2$ catalyst prepared without the organic solvent. Effect of Cr and Cu metal as a promoter was found little. 200 h long-term activity test was performed with a $Co/SiO_2$ catalyst prepared in the presence of an organic solvent of Glyoxal solution.