• Applied Biological Chemistry
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• v.48 no.2
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• pp.115-119
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• 2005

The catalytic hydrolysis reactivities of dinuclear nickel (II) complex, ${\mu}-aquapentaaqua[{\mu}-3,6-bis(6'-methyl-2'-pyridyl)pyridazine]chlorodinickel\;(II)$ trichloride trihydrate (APNT) for bis(p-nitrophenyl) phosphate (BNPP) as a DNA model compound were investigated. The dissociation constants of APNT were $pKa_1=7.9$ and $pKa_2=9.6$, respectively. The hydrolysis rate constant of BNPP compound by APNT was showed the rate enhancement of about 370,000 times in the case of none catalyst at pH 7.0 and $50^{\circ}C$. Based on the findings, we proposed the catalytic cycle for the hydrolysis of BNPP by APNT complex. The metal ions of dinuclear nickel (II) complex significantly enhance the transfer rate of phosphoryl group in the catalytic process and the water molecules as nucleophile and proton transfer agent act in different steps.

• Journal of Korea Water Resources Association
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• v.47 no.10
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• pp.891-906
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• 2014

This study suggests the hedging rule of MIP (Mixed Integer Programing) in counting the risk evaluation criteria of the objective function and constraints in order to provide the optimum operating rule in reservoir system as constraining water shortage as much as possible which may happen in the downstream control point of water supply in the aspect of water system management. The proposed model is applied to the Han-river reservoir system for two testing periods (Case I: Jan. 1993~Dec. 1997, Case II: Jan. 1999~Dec. 2003). The model based on the hedging rule with trigger volume, estimated in this study shows that in Case I, the monthly minimum discharge was $310.6{\times}10^6m^3$ in the single operation, $56.3{\times}10^6m^3$ in the joint operation, and $317.5{\times}10^6m^3$ in the hedging rule and also, in Case II, the monthly minimum discharge was found to be $204.2{\times}10^6m^3$ in the single operation, $111.2{\times}10^6m^3$ in the joint operation, and $243.7{\times}10^6m^3$ in the hedging rule. In conclusion, the hedging rule, proposed in this study can decrease vulnerability while guarantees reliability and resiliency.

• Journal of Korean Society on Water Environment
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• v.30 no.6
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• pp.596-604
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• 2014

This research has studied the physicochemical environmental factors and communities of epilithic diatom and phytoplanktons at Hongcheon river from December 2011 to September 2012. In case of TN, the result was hypertrophic, and for TP, it ranged from mesotrophic to eutrophic. As for BOD, Hongcheon river was rated level II or better, according to the water quality level; values were found to be below 3mg/L at most sites. Total of 83 and 114 taxa of epilithic diatom and phytoplanktons respectively, were found during the research. When assessed using the TSI, it ranged from oligomesotrophic to eutrophic. In case of DAIpo, it ranged from 64.1 to 99.5, and TDI ranged from 51.5 to74.0. These results signify good water quality, level B or better, for Hongcheon river. P-IBI was rated moderate to low, which showed higher pollution than other indices. Among the biological water quality measures analyzed in the Hongcheon river study, DAIpo best matches TDI and BOD, while TDI showed greater pollution. Therefore, P-IBI appears to be inappropriate when assessing the domestic small rivers and lakes.

• Journal of Korean Port Research
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• v.12 no.1
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• pp.95-104
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• 1998

Water pollution in a semi-enclosed sea area such as a bay due to stagnancy of water has been a serious water environmental problem. Recently, some kinds of new methods to activate the tidal exchange between an inner bay and an outer sea area by control of a tidal residual current have been proposed. However, these methods have several problems, that is, I). deterioration in a natural view due to building of huge structures, II). increase of risk of navigation in case of a submerged structure, III). limition of sea area where a tidal current can be controlled and IV). difficulty in removing those structures in case of occurrence of an unexpected impact on water environment. In this paper, a new method is proposed, which can solve all the above problems, to purify water quality in a semi-enclosed bay by creation and control of a pattern of a tidal residual current. The tidal residual current is controlled by unsymmetric structures, which change the properties of resistance according to the direction of flow, arranged on the sea bottom. In this study, several numerical and hydraulic experiments of tidal current and particle-tracking for various arrangements of bottom roughness in a semi-enclosed model bay were carried out. As a result of experiments, it becomes clear that it is possible to generate a new tidal residual current and to activate a tidal exchange by only operation of bottom roughness arrangement.

• Journal of Korean Society of Coastal and Ocean Engineers
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• v.20 no.5
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• pp.498-509
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• 2008

Reliability analyses of Level I, II and III for bearing capacity, overturning and sliding of quaywall are carried out to investigate their safety levels depending upon its failure modes, and sensitivity analyses of each design variable are performed to find their effects on safety levels of quaywall. Reliability indices was 1.416 for both level II and III for case study I, and with 2.201 and 1.880, respectively, for the case study II at the critical loading conditions. Thus we were able to know that Level II (FORM) approach is good enough to use in practical design. Generally, it was found that probabilities of failure of quaywall were higher for sliding and bearing capacity failure modes and lower for overturning failure mode. From sensitivity analyses, the most influential design variables to reliability index of quaywall were coefficient of friction, residual water pressure and resistance moment for the sliding, overturning and bearing capacity failure modes, respectively. Especially, the sensitivity of reliability index due to inertial force and dynamic water pressures, which include a large COV when earthquake occurs, did not change greatly.

• Korean Journal of Remote Sensing
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• v.39 no.6_2
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• pp.1565-1576
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• 2023

An atmospheric correction algorithm based on the radiative transfer model is required to obtain remote-sensing reflectance (R_rs) from the Geostationary Ocean Color Imager-II (GOCI-II) observed at the top-of-atmosphere. This R_rs derived from the atmospheric correction is utilized to estimate various marine environmental parameters such as chlorophyll-a concentration, total suspended materials concentration, and absorption of dissolved organic matter. Therefore, an atmospheric correction is a fundamental algorithm as it significantly impacts the reliability of all other color products. However, in clear waters, for example, atmospheric path radiance exceeds more than ten times higher than the water-leaving radiance in the blue wavelengths. This implies atmospheric correction is a highly error-sensitive process with a 1% error in estimating atmospheric radiance in the atmospheric correction process can cause more than 10% errors. Therefore, the quality assessment of R_rs after the atmospheric correction is essential for ensuring reliable ocean environment analysis using ocean color satellite data. In this study, a Quality Assurance (QA) algorithm based on in-situ R_rs data, which has been archived into a database using Sea-viewing Wide Field-of-view Sensor (SeaWiFS) Bio-optical Archive and Storage System (SeaBASS), was applied and modified to consider the different spectral characteristics of GOCI-II. This method is officially employed in the National Oceanic and Atmospheric Administration (NOAA)'s ocean color satellite data processing system. It provides quality analysis scores for R_rs ranging from 0 to 1 and classifies the water types into 23 categories. When the QA algorithm is applied to the initial phase of GOCI-II data with less calibration, it shows the highest frequency at a relatively low score of 0.625. However, when the algorithm is applied to the improved GOCI-II atmospheric correction results with updated calibrations, it shows the highest frequency at a higher score of 0.875 compared to the previous results. The water types analysis using the QA algorithm indicated that parts of the East Sea, South Sea, and the Northwest Pacific Ocean are primarily characterized as relatively clear case-I waters, while the coastal areas of the Yellow Sea and the East China Sea are mainly classified as highly turbid case-II waters. We expect that the QA algorithm will support GOCI-II users in terms of not only statistically identifying R_rs resulted with significant errors but also more reliable calibration with quality assured data. The algorithm will be included in the level-2 flag data provided with GOCI-II atmospheric correction.

• Journal of the Korean Ceramic Society
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• v.34 no.8
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• pp.861-869
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• 1997

In order to investigate the reaction in the system of anhydrite II-blast furnace slag, the paste hydration which made up with a liquid/solid ratio of 0.45 for 1, 3, 7, 14, 28days by the addition of accelerators to 10~30wt.% slag with natural gypsum calcined for 1hour at 500/$700^{\circ}C$ was studied by combined water determination, XRD, DTA, DSC and SEM. As a result of this experiment, it was found that hydration rate was faster in the system calcined at 50$0^{\circ}C$. Therefore the anhydrite was converted to calcium sulfate dihydrate in the hydration for 1day but the slag was not almost reacted. For the gypsum calcined at $700^{\circ}C$, the hydraton rate in the system of K2SO4 addition was faster than others in the earier period, but the activated effect of the system of Al2(SO4)3 addition was regarded as the highest over 3days. As the amount of slag was increased, they dydration rate was delayed and ettringite was observed in the case of K2SO4 system. However both Al2(SO4)3 and AlK(SO4)2 systems showed calcium sulfate dhydrate only as hydrated products.

• YAKHAK HOEJI
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• v.26 no.4
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• pp.231-237
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• 1982

The transformation kinetics between polymorphs of sulpiride and the effect of additives on the transformation kinetics were studied. The results could be summarized as follows. 1. Transformation kinetics of the polymorph form I to form II in water suspenion was first order type and transformation rate constant at $25^{\circ}C$ is $2.61{\times}10^{-2}min^{-1}$, the half life of form I was about 27 minutes and the activation energy for transformation was 21.35 Kcal/mole. 2. Glycerine and coloring agents increased the rate of transformation., In the case of polysorbate 80, the rate constant increased in proportion to the concentration of polyserbate 80. Simple syrup showed no effect 3n transformation kinetics.

• Journal of Environmental Policy
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• v.14 no.2
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• pp.3-25
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• 2015

Our goal is to verify how changes in water's hydraulic characteristics after urban regeneration stream can affect any possible transformation of its thermal environment. To that end, we analyzed changes in numerous physical characteristics the subject stream along with the meteorological factors and thermal environment affected by it. Cheonggyecheon was selected as our subject as it is a great example of successful urban regeneration stream. As for physical characteristics, we allocated Type I (0.0%) and Type II (20.2%), depending on the green coverage ratio. As for numerical characteristics, at the point of Ba in which the riffle ends, the water temperature fell by $0.2^{\circ}C$ and the flow increased from 0.7m/s to 0.9 m/s with the dissolved oxygen increasing from 0.5mg/L to 0.6mg/L. As for meteorological factors surrounding the subject stream, the temperature dropped from $1.1^{\circ}C$ to $1.4^{\circ}C$ on average and relative humidity increased from 6.6% to 8.7%. Furthermore, there was an irregular change in wind velocity. According to the result of the Wet Bulb Globe Temperature (WBGT), the change in the values of Type I and II inside and on the surface of the subject stream was negligible. The downstream temperature in Type I fell from $0.3^{\circ}C$ to $0.6^{\circ}C$ and by $0.8^{\circ}C$ in Type II. As for vertical cooling effect, the change of water level was 120cm in Type I and 140cm in Type II. As for horizontal cooling effects, the value of Type I was increased from the point of Ba where the riffle ends and the value of Type II was on a steady decline.

• Korean Journal of Ichthyology
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• v.28 no.1
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• pp.1-8
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• 2016

This study was conducted to investigate the physiological responses of sevenband grouper, Epinephelus septemfasciatus at low temperature condition in winter season. Water temperature was dropped from $12^{\circ}C$ to $5^{\circ}C$ by two different interval (interval I: $-1^{\circ}C/24h$ and interval II: $-1^{\circ}C/8h$). The experimental fishes were exposed for 9 days at each water temperature condition, and were observed survival rate. The blood sample was collected from fishes for analysis of cortisol, glucose, total protein (TP), and electrolytes ($Na^+$, $Cl^-$, $K^+$). Mortality of fish was not observed until $5^{\circ}C$. The mortality (12 individuals) began after 170 h and all fish were death after 174 h in interval I case, whereas the mortality (9 individuals) began after 72 h and all fish were death after 76 h in interval II case. Little different was observed in the physiological responses, but trend was similar between two intervals. The physiological metabolism of plasma cortisol and glucose were increased rapidly, and swimming ability and respiration response was faster at $7^{\circ}C$. This result means that the critical temperature of sevenband grouper was $7^{\circ}C$ at low water temperature condition.