• Fire Science and Engineering
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• v.34 no.4
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• pp.101-106
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• 2020

This study analyzed flame growth characteristics and carbonization patterns when floor materials were burned vertically using a needle flame produced for this study. It was found that PVC flooring was fire retardant and the area under direct flame contracted inward. Vertical combustion causes solidification in the form of a lump at the bottom and also generates soot in a pattern that progresses upwards. This study found that laminated flooring exhibited no fire retarding characteristics and that the laminated layer of its upper surface was destroyed by fire, causing irregular delamination. The carbonization ranges at the left and right sides were determined to be symmetrical. A vertical combustion test of a sample carpet showed that it exhibited no fire-retarding characteristics. It was observed that if heat accumulated in the carpet, the flame formed an ascending air current, and that when flammable materials were present around the flame, they further accelerated the diffusion of the flame. The carbonization pattern at the carpet surface exposed to direct flame revealed that the carpet surface had melted and had flown downwards and that many tiny holes formed on it.

• Journal of the Korean Institute of Illuminating and Electrical Installation Engineers
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• v.23 no.2
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• pp.161-167
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• 2009

Organic insulating materials which are utilized as insulating materials for the low voltage show unique carbonization characteristics when they are carbonized by a leakage current. Therefore the use of the carbonization characteristics makes it possible to examine the electrical fire which is caused by a leakage current flowing on the surface of the organic insulating material. In order to understand such carbonization characteristics, in this paper, experiments have been done to carbonize typical organic insulating materials such as phenol resin, PVC, and acrylic resin, and the carbonization patterns and the IR absorption spectrum of specimens have been analyzed. According to the analysis of the carbonization patterns, the phenol resin shows the so-called 'spider-leg' carbonization pattern due to a thermosetting property. In contrast to the phenol resin, the thermoplastic property makes it difficult to observe a clear carbonization pattern to verify carbonizing causes on the surfaces of PVC and acrylic resins. In this case, the IR absorption spectrum can be analyzed to examine the specimen carbonized by a leakage current. The analysis result shows that absorption peaks appear at the wave numbers of $3,400[cm^{-1}]$ and $1,618[cm^{-1}]$, which can be an important factor to verify the carbonizing causes.

• Korean Journal of Materials Research
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• v.23 no.1
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• pp.24-30
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• 2013

Today, the modification of carbon foam for high performance remains a major issue in the environment and energy industries. One promising way to solve this problem is the optimization of the pore structure for desired properties as well as for efficient performance. In this study, using a sol-gel process followed by carbonization in an inert atmosphere, hollow spherical carbon foam was prepared using resorcinol and formaldehyde precursors catalyzed by 4-aminobenzoic acid; the effect of carbonization temperature and re-immersion treatment on the pore structure and characteristics of the hollow spherical carbon foam was investigated. As the carbonization temperature increased, the porosity and average pore diameter were found to decrease but the compression strength and electrical conductivity dramatically increased in the temperature range of this study ($700^{\circ}C$ to $850^{\circ}C$). The significant differences of X-ray diffraction patterns obtained from the carbon foams carbonized under different temperatures implied that the degree of crystallinity greatly affects the characteristics of the carbon form. Also, the number of re-impregnations of carbon form in the resorcinol-formaldehyde resin was varied from 1 to 10 times, followed by re-carbonization at $800^{\circ}C$ for 2 hours under argon gas flow. As the number of re-immersion treatments increased, the porosity decreased while the compression strength improved by about four times when re-impregnation was repeated 10 times. These results imply the possibility of customizing the characteristics of carbon foam by controlling the carbonization and re-immersion conditions.

• Journal of the Korean Society for Marine Environment & Energy
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• v.17 no.4
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• pp.268-273
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• 2014

Experiments on carbonization were conducted using fish offal generated from fish market for the purpose of resource recycling. Elemental composition of fish offal and effect of carbonation temperature on the overall yield were investigated. Carbon and hydrogen contents of fish offal were 51.1% and 7.6%, respectively in view of elemental composition. Particularly, nitrogen and sulfur contents were as high as 9.8% and 1.0%, respectively. These values suggests that odor problem of fish offal can be serious. Comparing elemental composition of fish offal with other waste materials, it is thought that carbon and hydrogen contents are considerably high. These implies that thermal disposal will be the best option for final disposal method of fish offal. As a results of carbonization experiments on Mackerel, Hairtail, Croaker and mixed sample of Mackerel, Hairtail and Croaker, carbonization patterns were quite similar irrespective of fish species. Carbonization yield was varied significantly depending on carbonization temperature at the carbonization time of 5 minutes and 10 minutes. When the carbonization time was maintained longer than 30 minutes, yield variation depending on time variation at each temperature was insignificant. Thus, it can be concluded that effect of carbonization time on overall yield was minor when the carbonization time was maintained longer than 30 minutes. Primary vaporization in carbonization conducted at the temperature of $400^{\circ}C$ was minor. Thus, difference of yield between temperature of $500^{\circ}C$ and $400^{\circ}C$ was appeared greatly. It can be concluded that yield difference depending on carbonization temperature can be neglected if the carbonizing temperature exceed $600^{\circ}C$ and carbonizing time exceed 10 minutes at the same time.

• Fire Science and Engineering
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• v.32 no.5
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• pp.15-21
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• 2018

This study examined the growth characteristics and carbonization pattern when a fire occurs due to a flammable liquid sprinkled on a vinyl floor. When acetone was sprinkled on a floor, the flame reached its peak in approximately 0.2 s after it was ignited. The lower part of the flame showed a laminar pattern while the upper part showed a turbulent pattern. The pattern showed a turbulent pattern and generated white smoke. The combustion completed floor surface showed carbonization of a dim pore pattern. In the case of benzene, an intense flame was formed in approximately 0.6 s after ignition. The flame length was measured to be approximately 50 mm. When the flame became weak, a significant amount of black smoke was generated due to incomplete combustion. The combustion completed floor surface showed carbonization of a pour pattern and splash pattern. In the case of alcohol, an intense flame was formed in approximately 1.1 s after ignition. In addition, the depth of carbonization was significant where the flammable liquid was collected and a trace of carbonization was observed at the boundary of the flow path of the flammable liquid.

• Proceedings of the KIEE Conference
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• 2007.11a
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• pp.102-103
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• 2007

Recently, the dependence of the electric energy is increased in accordance with a growth of industry. Therefore, scientific investigation is needed for the security of electrical safety and the judgement of accident causes. Accordingly, this paper consist of the analysis for the carbonization patterns of phenolic resin and the mechanism. As the follows, spider-legs as a carbide are generated around the rods, when the electric current flows on the surface of phenolic resin. The IR absorption peak generated by the thermal effects is appeared at about $1720cm^{-1}$. As the case of Joule's heat, the crystal of a carbide is generated beca use of the rarefied oxygen. It's estimated that the formation of carbonization conductivity as the currents are easily flowed.

• Korean Journal of Materials Research
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• v.28 no.4
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• pp.208-213
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• 2018

Epitaxial ($11{\bar{2}}0$) a-plane GaN films were grown on a ($1{\bar{1}}02$) R-plane sapphire substrate with photoresist (PR) masks using metal organic chemical vapor deposition (MOCVD). The PR mask with striped patterns was prepared using an ex-situ lithography process, whereas carbonization and heat treatment of the PR mask were carried out using an in-situ MOCVD. The heat treatment of the PR mask was continuously conducted in ambient $H_2/NH_3$ mixture gas at $1140^{\circ}C$ after carbonization by the pyrolysis in ambient $H_2$ at $1100^{\circ}C$. As the time of the heat treatment progressed, the striped patterns of the carbonized PR mask shrank. The heat treatment of the carbonized PR mask facilitated epitaxial lateral overgrowth (ELO) of a-plane GaN films without carbon contamination on the R-plane sapphire substrate. Thhe surface morphology of a-plane GaN films was investigated by scanning electron microscopy and atomic force microscopy. The structural characteristics of a-plane GaN films on an R-plane sapphire substrate were evaluated by ${\omega}-2{\theta}$ high-resolution X-ray diffraction. The a-plane GaN films were characterized by X-ray photoelectron spectroscopy (XPS) to determine carbon contamination from carbonized PR masks in the GaN film bulk. After $Ar^+$ ion etching, XPS spectra indicated that carbon contamination exists only in the surface region. Finally, the heat treatment of carbonized PR masks was used to grow high-quality a-plane GaN films without carbon contamination. This approach showed the promising potential of the ELO process by using a PR mask.

• Fire Science and Engineering
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• v.24 no.5
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• pp.136-141
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• 2010

The purpose of this study is to examine the structure and heat generation mechanism of low voltage switches used to turn on or off the power supply to an indoor lighting system and investigate how the fixtures and movable contacts of the switches are damaged depending on the types of energy sources in order to secure the judgment base for expected PL disputes. Based on the Korean Standard (KS) testing method for incombustibility, this study applied a general flame to the switch. In addition, current was supplied to the switch using the PCITS (Primary Current Injection Test System). The ambient temperature and humidity were maintained at $22{\pm}2^{\circ}C$ and 40~60% respectively while performing the test. It is thought that the switch generated heat due to a defective connection of the wire and clip, insulation deterioration and defective contact of the movable contact, etc. The surface of the switch damaged by the general flame was uniformly carbonized. When the flame source was removed, the fire on the switch was extinguished naturally. From the result obtained by disassembling the switch carbonized by the general flame, it could be seen that fixtures and movable contacts remained in comparatively good shape but the enclosure, clip support, movable contact, indicating lamp, etc. showed carbonization and discoloration. In the case of the switch damaged by overcurrent, the clip connecting the wires, clip support, etc. showed almost no trace of damage, but the fixtures, movable contact, indicating lamp, etc. were severely carbonized. That is, the sections with high contact resistance were intensively damaged and showed a damage pattern indicating that carbonization progressed from the inside to the outside. Therefore, it is possible to judge the initial energy source by analyzing the characteristics of the carbonization pattern and the metal fixtures of damaged switches.

• Fire Science and Engineering
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• v.33 no.6
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• pp.126-131
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• 2019

Real-scale fire tests were performed on animal-origin foods using a gas stove with no overheating prevention device. When the animal-origin foods were ignited, a large quantity of white smoke and steam was generated from them; however, when they became dry and began to carbonize, a dark smoke was generated. Even after the gas stove was overheated for more than 5400 s, mackerel, pollack, chicken, etc., did not ignite. However, pork, beef, and tuna caught fire after 2643 s, 2819 s, and 6492 s of heating, respectively. The flame patterns of animal-origin foods were in the forms of a mixed laminar flow and a turbulent flow, and a halo pattern was produced. A sand glass form of the flame pattern was generated when a kitchen hood was operated, but a triangular flame pattern was produced when the kitchen hood was not operated. When the tuna in the pot was overheated, it spontaneously ignited after 6492 s, with the surface temperature of the kitchen hood rapidly rising to 464.5 ℃. Moreover, the temperature at the back of the pot, which was 6 cm away from the outer surface of the upper part of the pot, was 869 ℃ after 6660 s because of the radiant heat. The flame formed a sand glass pattern on the kitchen wall. When the kitchen hood was not operated, or when the flame grew lower than the height of the ceiling, a triangular pattern was formed.

• Fire Science and Engineering
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• v.25 no.6
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• pp.21-26
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• 2011

The purpose of this paper is to present the damage patterns of cellular phone (SCH_W830) batteries according to energy sources and have them utilized as data for the settlement of disputes between manufactures and consumers. The reliability was secured by maintaining the ambient temperature and humidity at $22{\pm}2^{\circ}C$ and 40~60 %, respectively. The voltage of the battery used for the tests was measured to be 4.18V between positive pole (+) and negative pole (-)(1), and 4.19 V between positive pole (+) and negative pole (-)(2). This study applied the Korean Industrial Standard (KS) to the flammability test of cellular phones due to a general flame applied to them and found that no damage occurred to the built-in battery even though the flame was applied to the cases of cellular phones for 30 seconds. From the results of immersing the cellular phones in the saline solution (NaCl, 0.9 %) for 180 seconds, it was found that there was a trace of carbonization and melting due to the heat caused by leaking current. It can be seen that when the cellular phones were heated for 70 seconds using a microwave oven (MWO), the areas containing the metal holder, recharging connector, antenna, etc., were melted and discolored and that other areas showed no particular problems. That is, while the external carbonization of cellular phones, built-in metals and dielectric materials, and damage and deformation of the battery terminal block, etc., occurred differently depending on the types of energy sources, the voltage showed comparatively constant characteristics. Therefore, it is thought to be possible to attribute the cause of damage to the battery by performing analysis taking into consideration comprehensively the characteristics of the flame spread pattern as well as the melting and deformation of metals.