• Title/Summary/Keyword: Carbonation process

Search Result 151, Processing Time 0.021 seconds

Production of SrCO3 from SrSO4 through the Black Ash Process (Black Ash법을 이용한 SrSO4로부터 SrCO3 제조)

  • Kang, Jungshin;Lee, Jin-Young
    • Resources Recycling
    • /
    • v.30 no.5
    • /
    • pp.49-56
    • /
    • 2021
  • In this study, using strontium sulfate (SrSO4) recovered from magnetite ore in Hongcheon, the Black Ash process was used to produce strontium carbonate (SrCO3). In the carbothermic reaction step, SrSO4 was reacted with carbon (C) at 1273 K under Ar gas atmosphere using a gas-tight quartz reactor to produce strontium sulfide (SrS). Afterward, water leaching of the residues produced from the carbothermic reaction at 353 K and carbonation of the leaching solution using sodium carbonate (Na2CO3) at 298 K were conducted to produce SrCO3. The results of this study demonstrate the feasibility of the production of SrCO3 via the Black Ash process using domestic magnetite ore containing strontium (Sr).

Alkali Recovery by Electrodialysis Process: A Review (전기투석 공정에 의한 알칼리 회수: 총설)

  • Sarsenbek Assel;Rajkumar Patel
    • Membrane Journal
    • /
    • v.33 no.3
    • /
    • pp.87-93
    • /
    • 2023
  • Electrodialysis (ED) is essential in separating ions through an ion exchange membrane. The disposal of brine generated from seawater desalination is a primary environmental concern, and its recycling through membrane separation technology is highly efficient. Alkali is produced by several chemical industries such as leather, electroplating, dyeing, and smelting, etc. A high concentration of alkali in the waste needs treatment before releasing into the environment as it is highly corrosive and has a chemical oxygen demand (COD) value. The concentration of calcium and magnesium is almost double in brine and is the perfect candidate for carbon dioxide adsorption, a major environmental pollutant. Sodium hydroxide is essential for the metal carbonation process which, is easily produced by the bipolar membrane electrodialysis process. Various strategies are available for its recovery, like reverse osmosis (RO), nanofiltration (NF), ultrafiltration (UF), and ED. This review discusses the ED process by ion exchange membrane for alkali recovery are discussed.

Evaluation of Penetrating and Reinforcing Agent for Preventing Deterioration of Concrete (표면 침투 보강제에 의한 콘크리트 열화 방지 성능 평가)

  • Cho, Myung-Sug;No, Jae-Myoung;Song, Young-Chul;Kim, Do-Gyum
    • Journal of the Korea Concrete Institute
    • /
    • v.19 no.4
    • /
    • pp.475-482
    • /
    • 2007
  • The property and applicability of the organic-inorganic synthesized penetrating and reinforcing agent, which is developed in order to improve durability of concrete structures and prevent deterioration that may occur as service years increased, are researched with experimental works. TEOS (tetra-ethoxyorthosilicate) and acrylate monomer are synthesized by the solution polycondensation method in order to formulate silicate with sol-gel process and improve durability of concrete. Additional substances such as isobutyl-orthosilicate is supplemented in order to improve the performance of the agent. After the developed organic-inorganic penetrating reinforcing agent penetrates, a flexible impact alleviating layer is formed with organic monomers as well as the agent strengthens concrete by filling up the internal pore of concrete with stable compounds after penetration. Penetrating and reinforcing agent can be applied as an effective life management method because it makes concrete more durable against the aging factors, such as chloride ion, carbonation, freezing-thawing, and compound aging.

Development of the FEED framework of the mineral carbonization pre-treatment system using systems engineering technique (시스템엔지니어링 기법을 이용한 광물탄산화 시스템 FEED 프레임워크 개발 방안에 관한 연구)

  • Kim, Jinil;Yeom, Choongsub;Ryu, BoHyun;Yoon, Munkyu;Kim, Joonyoung
    • Journal of Energy Engineering
    • /
    • v.27 no.1
    • /
    • pp.12-20
    • /
    • 2018
  • The FEED (Frond End Engineering Design) framework defines the activities and outputs to be performed at the FEED stage. In the meantime, many studies on FEED have been carried out, but most of them have slightly different opinions depending on experiences. It is important to define the FEED appropriately for the project and define the activities and outputs that are needed. It is also necessary to develop FEED processes on a solid basis, such as international system engineering process standards rather than experience. In this study, FEED is defined as suitable for the mineral carbonation system development project, and a method for developing the process and output to satisfy it is proposed based on the system engineering standard process.

Development of performance assessment criterion for structures of shield TBM tunnel (쉴드 TBM 터널의 구조물 성능 평가 기준 개발)

  • Seong, Joo-Hyun;Lee, Yu-Seok;Hong, Eun-Soo;Byun, Yo-Seph
    • Journal of Korean Tunnelling and Underground Space Association
    • /
    • v.17 no.5
    • /
    • pp.553-561
    • /
    • 2015
  • In this study, the performance assessment criterion for reasonable maintenance of shield TBM tunnel was presented. The performance assessment items such as crack, leakage, breakage, spalling, exfoliation/detachment, efflorescence, quality condition, exposure of steel, carbonation, faulting step, bolts condition, drainage condition, ground condition, contact section condition and conduit condition were selected by analyzing domestic and foreign performance assessment criterions and investigating segment lining deterioration cases through the site investigation and in-depth inspection analysis result on the shield TBM tunnel. In addition, the reasonable weight using AHP (Analytic Hierarchy Process) were estimated.

A Study on the Flame Resistance and Combustion Characteristics of MDF Plywood (MDF합판의 방염 및 연소특성에 관한 연구)

  • Kim, In-Beom
    • Korean Chemical Engineering Research
    • /
    • v.52 no.2
    • /
    • pp.256-260
    • /
    • 2014
  • Interior of the building is used as a MDF plywood if there is a fire in order to delay the ignition, flame retardant paint, flame retardant solution and flame retardant film are being handled by the flame retardant. Combustion characteristics anf flame retardant performance results can be summarized as follows: General film with a sample showed that short of the criteria in terms of carbonation area, and the results of flame retardant paint, flame retardant solution and flame retardant film products satisfied the criteria. Toxic gases generated in the combustion process results in a film samples using a high incidence of carbon monoxide and the creation of a smoke could be seen. This confirm that is estimated that result from incomplete combustion of PVC film that attach, and displays high toxicity index and hazard class relatively.

Influence of steel-fiber type and content on electrical resistivity of old-concrete

  • Uygunoglu, Tayfun;Topcu, Ilker Bekir;Simsek, Baris
    • Computers and Concrete
    • /
    • v.21 no.1
    • /
    • pp.1-9
    • /
    • 2018
  • Electrical resistivity is a property associated with both the physical and chemical characteristics of concrete. It allows the evaluation of the greater or lesser difficulty with which aggressive substances penetrate the concrete's core before the dissolution of the passive film process and the consequent reinforcement's corrosion begin. This work addresses the steel fiber addition to concrete with two types and various contents from 0% to 1.3%, correlating it with its electrical resistivity. To that effect, 9 different mixes of steel fiber reinforced concrete (SFRC) were produced. The electrical resistivity was evaluated on the on six years aged SFRC by direct measurement at different frequency from 0.1 kHz to 100 kHz. The results indicate that steel fiber content is strongly conditioned by the type and quantity of the additions used. It was also found that long type of fibers has more effect on decreasing the electrical resistivity of concrete than short fibers. Therefore, they increase the corrosion risk of concrete depending on fiber volume fraction and moisture percentage.

Efflorescence assessment using hyperspectral imaging for concrete structures

  • Kim, Byunghyun;Cho, Soojin
    • Smart Structures and Systems
    • /
    • v.22 no.2
    • /
    • pp.209-221
    • /
    • 2018
  • Efflorescence is a phenomenon primarily caused by a carbonation process in concrete structures. Efflorescence can cause concrete degradation in the long term; therefore, it must be accurately assessed by proper inspection. Currently, the assessment is performed on the basis of visual inspection or image-based inspection, which may result in the subjective assessment by the inspectors. In this paper, a novel approach is proposed for the objective and quantitative assessment of concrete efflorescence using hyperspectral imaging (HSI). HSI acquires the full electromagnetic spectrum of light reflected from a material, which enables the identification of materials in the image on the basis of spectrum. Spectral angle mapper (SAM) that calculates the similarity of a test spectrum in the hyperspectral image to a reference spectrum is used to assess efflorescence, and the reference spectral profiles of efflorescence are obtained from theUSGS spectral library. Field tests were carried out in a real building and a bridge. For each experiment, efflorescence assessed by the proposed approach was compared with that assessed by image-based approach mimicking conventional visual inspection. Performance measures such as accuracy, precision, and recall were calculated to check the performance of the proposed approach. Performance-related issues are discussed for further enhancement of the proposed approach.

Preparation and thermal properties of polyethylene-based carbonized fibers

  • Kim, Kwan-Woo;Lee, Hye-Min;Kim, Byoung Suhk;Hwang, Seon-Hwan;Kwac, Lee-Ku;An, Kay-Hyeok;Kim, Byung-Joo
    • Carbon letters
    • /
    • v.16 no.1
    • /
    • pp.62-66
    • /
    • 2015
  • In this study, carbonized fibers were prepared by using acidically cross-linked LDPE fibers. The surface morphologies of the carbonized fibers were observed by SEM. The effects of cross-linking process temperatures were studied using thermal analyses such as DSC and TGA. The melting and heating enthalpy of the fibers decreased as the cross-linking temperature increased. The cross-linked fibers had a carbonization yield of over 50%. From SEM results the highest yield of carbonized LDPE-based fibers was obtained by cross-linking at a sulfate temperature ($170^{\circ}C$). As a result, carbonation yield of the carbonized fibers was found to depend on the functions of the cross-linking ratio of the LDPE precursors.

A Study on the Effect of Initial Strength of Cement Paste Containing Fly Ash or Blast Furnace Slag on CO2 Curing Period (플라이 애쉬 및 고로슬래그 혼입 시멘트 페이스트의 CO2 양생 기간에 따른 초기강도의 영향에 대한 연구)

  • Han, Jae-Do;Lee, Han-Seung
    • Proceedings of the Korean Institute of Building Construction Conference
    • /
    • 2018.11a
    • /
    • pp.83-84
    • /
    • 2018
  • As the concentration of greenhouse gases in the atmosphere increases, the reduction of CO2 is gaining worldwide attention. In the construction industry, cement replacement materials such as fly ash and blast furnace slag were investigated to reduce CO2 emissions in cement production process. Precast concrete is used in the field after manufacturing in the factory in the form of pipes and bricks because of shortening construction period and cutting construction cost. According to the results of previous research, it is known that early CO2 curing in concrete using OPC or fly ash has an initial strength enhancement effect and can be used for precast concrete production. Therefore, the purpose of this study is to evaluate the strength improvement effect by confirming the initial strength improvement effect when blast furnace slag is mixed.

  • PDF