• Economic and Environmental Geology
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• v.55 no.4
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• pp.377-388
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• 2022

Laboratory-scale experiments were performed to identify the As removal mechanism of the residual slag generated after the mineral carbonation process. The residual slags were manufactured from the steelmaking slag (blast oxygen furnace slag: BOF) through direct and indirect carbonation process. RDBOF (residual BOF after the direct carbonation) and RIBOF (residual BOF after the indirect carbonation) showed different physicochemical-structural characteristics compared with raw BOF such as chemical-mineralogical properties, the pH level of leachate and forming micropores on the surface of the slag. In batch experiment, 0.1 g of residual slag was added to 10 mL of As-solution (initial concentration: 203.6 mg/L) titrated at various pH levels. The RDBOF showed 99.3% of As removal efficiency at initial pH 1, while it sharply decreased with the increase of initial pH. As the initial pH of solution decreased, the dissolution of carbonate minerals covering the surface was accelerated, increasing the exposed area of Fe-oxide and promoting the adsorption of As-oxyanions on the RDBOF surface. Whereas, the As removal efficiency of RIBOF increased with the increase of initial pH levels, and it reached up to 70% at initial pH 10. Considering the PZC (point of zero charge) of the RIBOF (pH 4.5), it was hardly expected that the electrical adsorption of As-oxyanion on surface of the RIBOF at initial pH of 4-10. Nevertheless it was observed that As-oxyanion was linked to the Fe-oxide on the RIBOF surface by the cation bridge effect of divalent cations such as Ca²⁺, Mn²⁺, and Fe²⁺. The surface of RIBOF became stronger negatively charged, the cation bridge effect was more strictly enforced, and more As can be fixed on the RIBOF surface. However, the Ca-products start to precipitate on the surface at pH 10-11 or higher and they even prevent the surface adsorption of As-oxyanion by Fe-oxide. The TCLP test was performed to evaluate the stability of As fixed on the surface of the residual slag after the batch experiment. Results supported that RDBOF and RIBOF firmly fixed As over the wide pH levels, by considering their As desorption rate of less than 2%. From the results of this study, it was proved that both residual slags can be used as an eco-friendly and low-cost As remover with high As removal efficiency and high stability and they also overcome the pH increase in solution, which is the disadvantage of existing steelmaking slag as an As remover.

• Journal of the Society of Disaster Information
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• v.9 no.4
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• pp.493-502
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• 2013

The purpose of this research is to estimate the drying shrinkage and durability of concrete using the fine river sand to utilize it actively as an alternative aggregate for concrete. For this purpose, the fine river sand samples were collected at the mid and down stream of main stream of Nakdong-River, and then the concrete specimens using the fine river sand were made according to strength level. After obtaining relation equation between compressive strength and cement-water ratio from the mix experiment result, the concrete specimens using different fine river sand were made for the specified concrete strength of 35MPa, and then their drying shrinkage and durability such as the resistance to freeze and thaw and carbonation were evaluated. It was observed from the test result that the durability of concrete using fine river sand was similar to that of concrete using reference sand, but the drying shrinkage of concrete using the fine river sand with small fineness was comparatively larger than that of concrete using reference sand.

• Journal of the Korea institute for structural maintenance and inspection
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• v.19 no.3
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• pp.22-29
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• 2015

In this study, we tested to develop and apply structural insulation performance improvement concrete to field, which had compressive strength in 24 MPa and thermal conductivity twice as much as normal concrete. After experiment about slump and air contents, combination product of Plain and calcined diatomite powder showed reduction of slump and air contents and combination product with micro foam cell admixture, we cannot find result of slump and air contents reduction. Unit weight of combination product with insulation performance improvement materials decreased more than that of Plain. In the test of compressive strength, compressive strength of insulation performance improvement concrete decreased more than that of Plain but was content with 24 MPa. thermal conductivity of insulation performance improvement concrete tended to decrease. Freezing and thawing resistance of insulation performance improvement concrete was similar to that of Plain. In carbonation resistance test, combination product with calcined diatomite powder showed the result which was similar to that of Plain. In carbonation resistance test, combination product with micro foam cell admixture showed a increase compared to that of Plain and length variation of combination product generally increased.

• Journal of the Korean Crystal Growth and Crystal Technology
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• v.29 no.5
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• pp.222-228
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• 2019

In this study, we carried out the experiment to prepare lithium carbonate powder through gas-liquid reactions with a lithium-containing solution and $CO_2$ gas using lithium hydroxide, lithium chloride, and lithium sulfate. Thermodynamically, the carbonation reaction of a lithium-containing solution showed that aqueous reaction of lithium hydroxide occurs spontaneously, but aqueous reactions of lithium chloride and lithium sulfate does not occur spontaneously. In the case of lithium hydroxide solution, the recovery rate of lithium carbonate was 69.8 % at room temperature ($25^{\circ}C$), and increased to 89.4 % at $60^{\circ}C$. In the case of lithium chloride and lithium sulfate solution, lithium carbonate could be prepared using sodium hydroxide as an additive, but the recovery rates were 19.2 % and 16.7 %, respectively.

• Journal of the Korea institute for structural maintenance and inspection
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• v.24 no.4
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• pp.18-25
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• 2020

The purpose of this study is to investigate the mechanical and carbon-capture properties of foam concrete containing stainless steel argon oxygen decarbonization(AOD) slag. AOD slag was used as a binder, and foam concrete having a foaming ratio of 69 ± 0.5 % and a slurry density of 573.2 to 578.6 kg / ㎥ was produced. In order to examine the effect of carbonation, blended specimen was cured by two types : normal curing and CO₂ curing. As a result of the experiment, the specimens incorporating AOD slag showed higher compressive strength than Plain after CO₂ curing. According to the analysis of the image of foam concrete, it was confirmed that the ST30 has a lower total pore volume and average pore size than plain, resulting in high compressive strength. The SEM analysis confirmed the formation of calcite by carbonation of AOD slag. Through the thermogravimetric analysis, the increase of CO₂ uptake was confirmed by the incorporation of AOD slag. Foam concrete has a higher porosity than normal concrete, so it is expected that carbon-capture performance can be improved by using a AOD slag.

• Journal of the Korean Recycled Construction Resources Institute
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• v.9 no.2
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• pp.135-142
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• 2021

In this work, multi-turn wings and guide plates are installed on recycled aggregate crushing devices to improve existing low recycled aggregate quality. Simulation analysis to evaluate the crushing efficiency of the new device shows enhanced crushing efficiency since the installation of guide plates shreds most of the inputs inside the crushing drum, and the multi-turn wings and guide plates induce rebound and circulation of the aggregate. Through this, the new device was found to be more economical and efficient than the existing recycled aggregate crushing device. Also, the amount of cement paste and mortar attached to the surface of the aggregate was smaller than that of the existing recycled aggregate, and it was found that the mechanical properties and elastic modulus deterioration were reduced. However, the carbonation resistance of concrete was not improved to the level of natural aggregates due to the remaining tiny cement paste and mortar on the surface of the new recycled aggregate. Therefore, it is deemed necessary to further research and experiment such as device improvement or binder development to reduce durability degradation of concrete mixed with new recycled aggregate.

• Proceedings of the Korea Concrete Institute Conference
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• 2002.05a
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• pp.767-772
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• 2002

Using the diffusion cell, a experimental study on the nitrogen permeability was performed with the various thickness of concrete. This is important with relating to the carbonation study because the study of $CO_2$ diffusivity needs to use thin concrete specimen. Experimental results show that the nitrogen permeability is few affected by concrete specimen's thickness. But, specimens with 1cm thickness have a high permeability and deviation relatively. Also, specimens with w/c ratio 0.40 have a low permeability than 0.58. Consequently, the 3cm thickness is the better stable than others but the 1cm thickness specimens will be stable in case having a lot of specimens.

• Proceedings of the Korea Concrete Institute Conference
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• 2005.05b
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• pp.197-200
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• 2005

In this study, for the establishment of the performance evaluation methods and the quality control standards of durability recovery method, the quantitative exposure data by long term exposure test under the coast is accumulated and analyzed Investigating and evaluating the result of exposure test at 30 month of exposure age under the coastal environment, carbonation and salt damage are not happened at all but the difference in electric potential are found. Therefore, it is considered that the reinforcement corrosion at replacement with repair material are caused by active-passive corrosion macrocells.

• Proceedings of the Korea Concrete Institute Conference
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• 2005.05b
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• pp.45-48
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• 2005

Self compacting concrete has the strong point in capability of concrete to be uniformly filled and compacted in every corners of formwork by its self-weight without vibration during placing. However, powder type self compacting concrete has the weak point in the heat of hydration, the drying shrinkage and the elastic property of concrete etc. Recently viscosity agent has been developed in order to overcome these weaknesses. In this study, self compacting concrete is made with viscosity agent based on polysaccharide derivative in order to develope the normal strength self compacting concrete. Slump flow, loss of slump flow and setting time are measured for comparison with normal concrete. Compressive strength, freezing and thawing test and carbonation test are conducted on normal and self compacting concrete using viscosity agent. In the experiment, we acquired good results in fresh and hardened self compacting concrete using viscosity agent based on polysaccharide derivative.

• Proceedings of the Korean Institute of Building Construction Conference
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• 2022.11a
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• pp.115-116
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• 2022

Large concrete mass members are commonly used as matte bases for skyscrapers. In general, Integral casting is preferred to secure construction convenience and durability quality rather than separate casting. However, there is a possibility that cracks may occur in the early stages due to the generation of a lot of hydration heat, and thus durability will decrease, so it is necessary to determine an appropriate mixture and verify it through experiments. The purpose of the study was to conduct a review on the durability of the optimal high-performance low-heating concrete combination derived through the experiment and to conduct a review analysis on the performance satisfaction and performance expression mechanism.