• Economic and Environmental Geology
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• v.50 no.4
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• pp.287-302
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• 2017

The carbonate rocks of the Daegi Formation are composed of the limestone at the upper and lower zones, and the dolomite at the middle zone, in which the upper zone has higher CaO content than others. The colors of carbonate rock in the Daegi Formation can be divided into five types; white, light brown, light gray, gray, and dark gray. The white to light gray colored rocks correspond to the high purity limestone with 53.15 ~ 55.64 wt. % CaO, and the light brown colored rocks contain 20.71 ~ 21.67 wt. % MgO. The bleaching of carbonate rocks are not related to CaO composition of the rocks, as light gray rocks tend to be higher in CaO content than those of the white rocks at the lower zone. The pelitic components are also occasionally increased in white limestone than light grey one. $Al_2O_3$ is one of the most difficult content to remove during hydrothermal processes, so the interpretation that the limestone is purified together with hydrothemral bleaching, has little merit. The wide range (over 16 ‰) of ${\delta}^{18}O_{SMOW}$, smaller variation (within 2 ‰) of ${\delta}^{13}C_{PDB}$ are apparent in both the upper and lower zones, which indicate the Daegi Formation had been affected overall by hydrothermal fluids. The K-Ar isotopic age of hydrothermal alteration in the GMI limestone mine is $85.1{\pm}1.7Ma$. Gradual change from grey through light grey to white limestone is accompaned by lower oxygen stable isotope values, which is major evidence that the hydrothermal effect is the main process of the bleaching. Although the Daegi Formation has suffered from hydrothermal activity and increase in whiteness, there is no clear evidence demonstrating the relationship between bleaching and high purity of limestone. The purification of limestone has nothing to do with the hydrothermal activity in this area. Instead, it should be considered that the change of sedimentary environment related to see-level fluctuation which can prevent deposition of pelitic components especially $Al_2O_3$ contrbuted to the formation of the high purity limestone in the upper zone of the Daegi Formation. Considering the evidences such as increase in CaO content of limestone by depth, gradual change from calcite to dolomite at the lower zones, and occurring the high purity limestone at the upper zone, the interpretation of sequence stratigraphic aspect to the formation of the high purity Daegi limestone appears to be more suitable than that of hydrothermal alteration origin.

• The Korean Journal of Petroleum Geology
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• v.1 no.1 s.1
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• pp.1-13
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• 1993

The diagenetic history of the carbonate rocks of the Mungok Formation near Machari area, Kangwondo, was investigated based on textural, isotopic, and chemical data. Paragenetic relationship among diagenetic minerals, coupled with their distinct geochemical contents, shows that the Mungok Formation have undergone several stages of diagenetic events: 1) shallow marine, 2) meteoric, 3) shallow to intermediate burial, and 4) deep burial diagenesis. Shallow marine diagenesis includes fibrous calcite cementation, micritization, and framboidal pyritization, and meteoric diagenesis involved dissolution and recrystallization of unstable allochems (both aragonite and HMC), syntaxial overgrowth on echinoderm fragments, and equant calcite cementation. During shallow to intermediate burial, idiotopic dolomite and chert formed, and xenotopic dolomitization took place before stylolitization of the rocks. After the rocks were deeply buried, saddle dolomitization, second stage of silicification, and dedolomitization occurred.

• The Journal of the Petrological Society of Korea
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• v.23 no.3
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• pp.261-272
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• 2014

Over the last three decades, advances in AMS (Accelerator Mass Spectrometry) and Noble Gas Mass Spectrometer make various application of terrestrial cosmogenic nuclides (CNs) to wide range of earth surface sciences possible. Dating techniques can be divided into three sub-approaches: simple surface exposure dating, depth-profile dating, and burial dating, depending on the condition of targeted surfaces. In terms of Korean landscape view, CNs dating can be applied to fluvial and marine terrace, alluvial fan, tectonic landform (fault scarp and faulted surfaces), debris landforms such as rock fall, talus, block field and stream, lacustrine and marine wave-cut platform, cave deposits, Pliocene basin fill and archaeological sites. In addition, in terms of lithology, the previous limit to quartz-rich rocks such as granite and gneiss can be expanded to volcanic and carbonate rocks with the help of recent advances in CNs analysis in those rocks.

• Economic and Environmental Geology
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• v.52 no.1
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• pp.107-118
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• 2019

Two assertions about the process the formation of the high-purity limestone in the Taebaeksan Basin, categorized into syngenetic and epigenetic origin, are verified on the basis of its oxygen-carbon stable isotopic characteristics. The carbonate rocks sampled from the selective six high-purity limestone mines and several outcrops in the Daegi formation are featured by various colors such as the gray, light gray and dark gray. They show a wide range of oxygen stable isotope ratios (4.5 ~ 21.6 ‰), but a narrow range of carbon stable isotope ratios (-1.1 ~ 0.8 ‰, except for vein calcite), which means that they had not experienced strong hydrothermal alteration. In addition, there is no difference in the range of the oxygen stable isotope ratios by mine and color, and it is similar to the range from surrounding outcrop samples. These results indicate that the effect of the hydrothermal alteration were negligible in the generation of high-purity limestone in deposit scale. Whereas, the carbonate rocks can be divided texturally into two groups on the basis of an oxygen isotope ratio; the massive-textured or well-layered samples (>15 ‰), and the layer-disturbed (or layer-destructed) and showing over two colors in one sample (<15 ‰). In the multi-colored samples, the bright parts are characterized by the very low oxygen stable isotope ratios, compared to the dark parts, implying the increase in brightness of the carbonate rocks could be induced by the interaction between hydrothermal fluid and rock. However, these can be applied in a small scale such as one sample and are not suitable for interpretation of the generation of high-purity limestone as a deposit scale. In particular, the high oxygen isotope ratios from the recrystallized white limestone suggest that hydrothermal fluids are also rarely involved during recrystallization process. In addition, the occurrences of the high-purity limestone orebody strongly support the high-purity limestone in the area are syngenetic rather than epigenetic; the high-purity limestone layers in the area show continuous and almost horizontal shapes, and is intercalated between dolomite layers. Consequently, the overall reinterpretation based on the sequential stratigraphy over the Taebaeksan basin would play an important role to find additional reserves of the high-purity limestone.

• Economic and Environmental Geology
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• v.53 no.4
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• pp.383-395
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• 2020

The stratigraphical position of the Haengmae Formation can provide clues towards solving the hot issue on the Silurian formation, also known as Hoedongri Formation. Since the 2010s, there have been several reports denying the Haengmae Formation as a lithostratigraphic unit. This study aimed to clarify the lithostratigraphic and chronostratigraphic significance of the Haengmae Formation. The distribution and structural geometry of the Haengmae Formation were studied through geologic mapping, and the correlation of relative geologic age and the absolute age was performed through conodont biostratigraphy and zircon U-Pb dating respectively. The representative rock of the Haengmae Formation is massive and yellow-yellowish brown pebble-bearing carbonate rocks with a granular texture similar to sandstone. Its surface is rough with a considerable amount of pores. By studying the mineral composition, contents, and microstructure of the rocks, they have been classified as pebble-bearing clastic rocks composed of dolomite pebbles and matrix. They chiefly comprise of euhedral or subhedral dolomite, and rounded, well-sorted fine-grained quartz, which are continuously distributed in the study area from Biryong-dong to Pyeongan-ri. Bedding attitude and the thickness of the Haengmae Formation are similar to that of the Hoedongri Formation in the north-eastern area (Biryong-dong to Haengmae-dong). The dip-direction attitudes were maintained 340°/15° from Biryong-dong to Haengmae-dong with a thickness of ca. 200 m. However, around the southwest of the studied area, the attitude is suddenly changed and the stratigraphic sequence is in disorder because of fold and thrust. Consequently, the formation is exposed to a wide low-relief area of 1.5 km × 2.5 km. Zircon U-Pb age dating results ranged from 470 to 449 Ma, which indicates that the Haengmae Formation formed during the Upper Ordovician or later. The pebble-bearing carbonate rock consisted of clastic sediments, suggesting that the Middle Ordovician conodonts from the Haengmae Formation must be reworked. Therefore, the above-stated evidence supports that the geologic age of the Haengmae Formation should be Upper Ordovician or later. This study revealed that the Haengmae Formation is neither shear zone, nor an upper part of the Jeongseon Limestone, and is also not the same age as the Jeongseon Limestone. Furthermore, it was confirmed that the Haengmae Formation should be considered a unit of lithostratigraphy in accordance with the stratigraphic guide of the International Commission on Stratigraphy (ICS).

• 한국해양학회지
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• v.30 no.5
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• pp.480-492
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• 1995

Petrographic investigation has been carried out to determine the composition of the beach sediments and the affecting factors which have controlled their compositional variations from Hyupjae, Aeweol, Iho, Samyang, Hamdeok, Sehwa, Pyoseon, Jungmun, and Hwasun areas along the coast of the Cheju Island. Average mean sizes of the beach sediments are Hyupjae 2.2ø, Aeweol 0.8ø, Iho 1.4ø, Samyang 2.4ø, Hamdeok 1.6ø, Sehwa 1.5ø, Pyoseon 2.1ø, Jungmun 0.4ø, and Hwasun 0.9ø, thus, aries from 0.4 to 2.4ø. The beach sediments from Pyoseon and Hwasun areas are poorly sorted, those from Aeweol and Jungmun areas are moderately sorted and those from the rest of the areas are moderately well sorted. While-colored beach sediments in Hyupjae, Aeweol, Hamdeok, Sehwa, and Pyoseon areas are mostly composed of calcareous shells (more than 85%) such as mollusk, red algae, benthic foraminiferas, etc., whereas volcanic rock fragment is the dominant component of the black-colored beach sediments in Iho, Samyang, and Hwasun areas. Especially, the relatively white-colored beach sediment in Jungmun area, which is on e of the carbonate-dominant areas, shows a higher content of rock fragments than the other carbonate-dominant areas. The beach sediments in Pyoseon area show a high content of carbonate intercalates. Considering the contributions by organisms according to grain size, grains with the size range of 1∼2ø are mostly composed of calcareous red algae fragments, and grains with the size range of 2∼3ø consist of mollusk fragments. It is also notable that bryozoan fragments comprise about 48% of the sediment in Samyang area with the size range of 0∼1ø. The composition of the beach sediments in Cheju Island appears o be controlled by the riverine supply rate of volcanic rock fragments, the lithology of the rocks distributed ear the beaches, the direction of alongshore currents, and the direction of storms, etc.. It is suggested that the beach sediments in Iho and Samyang areas show black color because of the higher supply rate of the volcanic rock fragments from the nearby rivers, whereas those in the rest of the areas show white color due to the relatively lower content of volcanic rock fragments and higher content of carbonate components transported from shallow marine environment. In Hwasun area, the content of volcanic rock fragments is high, and they are directly from the tuffaceous rocks distributed nearby. Also, the volcanic rock fragments in Jungmun area are transported not only from the rivers nearby but also from the nearby tuffs by storm activities. The beach sediment in Pyoseon area contains a high content of carbonate intercalates, which formed in the nearby shallow marine environment through marine cementation. This indicates that active marine cementation occurs in shallow marine environment near Pyoseon area.

• Economic and Environmental Geology
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• v.2 no.2
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• pp.53-67
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• 1969

Magnetite deposit of Pocheon Iron Mine is a contact replacement skarn deposit embedded in the carbonate rocks (limestone and dolomite) which are intruded by granite porphyry. The shape of ore bodies is sweet potato-like and/or irregular massive form; D-ore body, the biggest one is of $180m{\times}40m{\times}200m$ in size. The ore is in general of high grade. The location of the ore bodies is controlled by the fault which strikes north south and dips $60^{\circ}$ to $70^{\circ}$ to the west. A regular distribution of mineralized zones is recognized in order of outward (hanging wall side) from granite porphyry as follows: compact fine-grained skarn, limesilicates, magnetite ore body, marble, limesilicates, pyritized meta-sediments.

• The Journal of Engineering Geology
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• v.21 no.1
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• pp.79-85
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• 2011

We investigated the flow properties of groundwater in areas of carbonate rocks at Yeongwol and Jeongseon, Gangwon Province, based on measurements of hydraulic conductivity. Existing hydraulic conductivity data were compiled from 46 wells in the study area. These wells were sunk close to Golji stream and the Joyang and Dong rivers, which flow through the study area. The hydraulic conductivities range from 0.004 to 1.1 m/day, and show a gradually decreasing trend with decreasing well depth (y=-0.003x - 0.927, $r^2$=0.129). The study area was classified into zone A (< 0.1 m/day), zone B (0.1-1.0 m/day), and zone C (> 1 m/day) according to hydraulic conductivity. Zones A, B, and C make up 87% (n = 40), 11 % (n = 5), and 2% (n = 2) of the surface of the study area, respectively. Among the three zones, zone A contains few fractures whereas zone C contains many fractures. These results indicate that groundwater flow in carbonate regions is strongly influenced by the fracture network.

• The Journal of the Petrological Society of Korea
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• v.12 no.3
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• pp.135-153
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• 2003

In order to understand its origin and petrogenesis, petrochemical studies of major, trace elements, REE, and stable isotopes of oxygen and carbon from the Hongcheon Fe-REE deposits have been investigated. The Hongcheon Fe-REE deposit intruding into Precambrian metasedimentary rocks consists of magnetite, various carbonates such as ankerite, siderite, magnesite and strontianite, monazite, aegirine-augite, Na-amphibole, and sulfides. Compared with major elements abundances of typical ferro-carbonatites, the Hongcheon Fe-REE deposit is enriched in FeO and depleted in CaO with increasing of $SiO_2$, where $TiO_2$and $A1_2O_3$increased and CaO, FeO, MgO and $P_2O_5$ are slightly decreased, but those are rather scattered and their trends are somewhat ambiguous. V Ni, U and Rb slightly increasing with of $SiO_2$increase and scattering or no trends of other detected elements. Nb, Zr and Zn are depleted then the abundances of typical ferro-carbonatites (Woolley and Kempe, 1989). In rare earth elements a large enrichment of total REE (maximum 14.8 wt%) and LREE relative to chondrites and HREE depleted more then the values of ferro-carbontites therefore La/Lu ratios shows large abundances (max. 16,197). The results of stable isotopes of O and C from minerals of ankerite and strontianite and whole rocks represent studied rocks are from igneous carbonatitic melts. Although petrochemical characteristics of the Hongcheon Fe-REE deposits are somewhat different from normal ferro-carbonatites from the world, this discrepancy suggests another conclusion that petrochemical characteristic of the studied Fe-REE mineralized rocks are similar to those of phoscorites from Kovdor, Russia and Sokli, Finland showing the same petrochemical compositions described above.

• Journal of the Mineralogical Society of Korea
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• v.25 no.4
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• pp.221-231
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• 2012

Uljin cassiterite deposit had been known to be a pegmatitic origin derived from the Wangpiri (Buncheon) granitic gneiss of Precambrian period. Lithium ore also shows the same origin and its lithium bearing mineral was ascertained to be a taeniolite. But the presence of leucocratic granites which played the role of host rocks haven't been clearly designated yet in these provinces. Even though Bonghwa and Youngweol sericite deposits situated in the vicinities of Hambaeg syncline had been known to have their host rocks as Hongjesa Granites of Precambrian period and Pegmatitic migmatite of unknown age respectively. But younger leucocratic granites are characterized by more amounts of albite and sericite (muscovite-3T type) than those of the older granitic rocks which contain plenty of biotite and chlorites. Although the younger granites show rather higher contents of alkalies such as $Na_2O$ (0.13~8.03 wt%) and $K_2O$ (1.71~6.38 wt%), but CaO (0.05~1.21 wt%) is very deficient due to the albitization and greisenization. Manisan granite, which is assumed to be Daebo granite which intruded the Gyunggi Gneiss Complex was again intruded by leucocratic granite whose microclinized part changed into kaolins. Taebaegsan region shows a wide distribution of carbonate rocks which are especially favorable to the ore depositions. And the presence of alkali granites which formed in the later magmatic evolution are well known to be worthwhile to the prospections of various rare metals and REEs resources.