• Title/Summary/Keyword: Carbon tip

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Comparison of stabilities in carbon nanotubes grown on a submicron-sized tip in terms of various buffer and catalyst materials (미세크기 팁 위에 성장된 탄소 나노튜브의 완충막 및 촉매 금속에 따른 안정성 비교)

  • Kim, Jong-Pil;Kim, Young-Kwang;Park, Chang-Kyun;Park, Jin-Seok
    • Proceedings of the KIEE Conference
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    • 2008.07a
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    • pp.1224-1225
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    • 2008
  • The results of the experiment that was conducted on the electron emission property and the long-term stability of the emission current in various carbon nanotubes (CNTs)-based field emitters with a CNT/catalyst/buffer/W-tip configuration are presented herein. CNT-based field emitters were fabricated by varying the (TiN, Al/Ni/TiN) buffer layer and the (Ni, Co) catalyst material. This study aimed to elucidate how the buffer layers and catalyst materials affect the structural properties of CNTs and the long-term stability of CNT emitters. Raman spectroscopy, field emission SEM, and high-resolution TEM were used to analyze the crystalline structure, surface morphologies, and nanostructures of all the grown CNTs. X-ray photoelectron spectroscopy (XPS) was used to monitor the chemical bonds of all the buffer layers and catalysts. Electron emission measurement and a long-term (up to 40h) stability test were carried out using a compactly designed field emission measurement system.

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Study on the Cold Formability of Drawn Non-heat Treated Steels (신선 가공된 열처리 생략강의 냉간 성형성에 대한 연구)

  • 박경수;박용규;이덕락;이종수
    • Proceedings of the Korean Society for Technology of Plasticity Conference
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    • 2003.05a
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    • pp.307-310
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    • 2003
  • Non-heat treated steels are attractive in the steel-wire industry since the spheroidization and quenching-tempering treatment are not involved during the processing. In this study, three different steels such as dual phase steel, low-Si steel, and ultra low carbon bainitic steel were used to investigate their deformation resistance and forming limit. Deformation resistance was estimated by calculating the deformation energy and the forming limit was evaluated by measuring the critical strain revealing crack initiation at the notch tip of the specimens. The results showed that deformation resistance was the lowest in the low-Si steel, and the forming limit strain was the highest in the ultra low carbon bainitic steel.

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Carbon Nanotube Cartridge for the Fabrication of Nanotweezer (나노트위져 제작을 위한 탄소나노튜브 카트리지)

  • 최재성;이준석;강경수;곽윤근;김수현
    • Proceedings of the Korean Society of Precision Engineering Conference
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    • 2004.10a
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    • pp.146-150
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    • 2004
  • We researched carbon nanotube(CNT) cartridge as a CNT sample for the fabrication of nanotweezer which is composed of a couple of single CNT tip. Our CNT cartridge was made by dielectrophoretic methods, a kind of micromanipulation technique using electric field. Therein we intended to fabricate the CNT cartridge with just conventional function generators and a set of simple electrode. A knife edge and a flat metal electrode were employed as a couple of electrode, and these electrode pair faced each other with the gap. When the gap is filled with CNT suspension, we induced AC electric field into the gap. Then CNTs was attached on the sharp edge in knife edge by dielectrophoresis. This knife edge with attached CNTs is called as the CNT cartridge.

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Effects of Selective Growth on Electron-emission Properties of Conical-type Carbon Nanotube Field-emitters (원추형 기판 위에 탄소 나노튜브의 선택적 성장이 전계방출 특성에 미치는 영향)

  • Kim, Bu-Jong;Noh, Young-Rok;Park, Jin-Seok
    • Journal of the Semiconductor & Display Technology
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    • v.11 no.1
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    • pp.61-65
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    • 2012
  • In this study, for use of carbon nanotubes (CNTs) as a cold cathode of x-ray tubes, we examine the effects of selective growth of CNTs on their field emission properties and long-term stability. The selective growth of CNTs was performed by selectively etching the catalyst layer which was used for CNTs' nucleation. CNTs were grown on conical-type tungsten substrates using an inductively-coupled plasma chemical vapor deposition system. For all the grown CNTs, their morphologies and microstructures were analyzed by field-emission scanning electron microscope and Raman spectroscopy. The electron-emission properties of CNTs and the long-term stability of emission currents were measured and characterized according to the CNTs' growth position on the substrate.

Electrochemical Behaviors of PAN/Ag-based Carbon Nanofibers by Electrospinning

  • Park, Soo-Jin;Im, Se-Hyuk
    • Bulletin of the Korean Chemical Society
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    • v.29 no.4
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    • pp.777-781
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    • 2008
  • In this work, silver nanoparticles-containing polyacrylonitrile (PAN) solutions in N,N-dimethylformamide (DMF) were electrospun to be webs consisting of nanofibers. The inputted voltage and PAN content in the solution were fixed at 15 kV and 10 wt.% in DMF with 10 cm of tip-to-collector distance (TCD). The PAN/Ag nanofiber webs were stabilized by oxidation at 250 ${^{\circ}C}$ for 2 h in air and carbonized at 1000 ${^{\circ}C}$ for 2 h in $N_2$. The resultant diameter distribution and morphologies of the nanofibers were evaluated by scanning electron microscope analysis. The electrochemical behaviors of the nanofiber webs were also observed by cyclic voltammetry tests. It was found that the presence of silver nanoparticles in carbon nanofiber webs led to the increase of specific capacitance and the decrease of fiber diameters.

Carbon Nanofibers with Controlled Size and Morphology Synthesized with Ni-MgO Catalyst Treated by Mechanochemical Process

  • Fangli Yuan;Ryu, Ho-Jin;Kang, Yong-Ku;Park, Soo-Jin;Lee, Jae-Rock
    • Journal of the Semiconductor & Display Technology
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    • v.3 no.1
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    • pp.9-13
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    • 2004
  • Carbon nanofibers (CNFs) with uniform diameter and controlled size were prepared from catalytic decomposition of $\textrm{C}_{2}\textrm{H}_{2}$ with Ni-MgO catalyst treated by mechanochemical (MC) process. The properties of Ni catalyst, such as size, distribution and morphology, can be governed by tuning grinding time in MC process. As a result, size and structure of CNFs can be tailored. The effect of grinding time to the as-grown CNFs was studied. CNFs with diameter from 10-70 nm were synthesized. CNFs with bundle formation sharing one tip and twisted CNFs were also synthesized with catalyst treated by MC process.

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The Evaluation of Fracture Toughness of SMC Composite Material and Carbon/Epoxy Composite Material (SMC 복합재료와 Carbon/Epoxy 복합재료의 파괴인성평가)

  • 최영근;이유태;이태순
    • Journal of Ocean Engineering and Technology
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    • v.7 no.1
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    • pp.25-32
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    • 1993
  • In composite materials, the fracture perpendicular to the fiber direction usually shows a non-linear behavior accompannying blunting and plastic deformation around the crack tip. In this study, the fracture thoughness in random short fiber SMC composite material and Carbon/Epoxy composite material is estimated by the A.M.(Area Method) and the G.L.M.(Generalized Locus Method) which can determine a stable total energy release rate(G$_T$) not only in highly elghly elastic material but also in highly non-linear materials.

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A novel hemispherical microbond specimen for evaluating the interfacial shear strength of single fiber composite (복합재료의 계면 전단강도를 평가하기 위한 새로운 반구형 미소접합 시험편)

  • Park, Joo-Eon;Choi, Nak-Sam
    • Composites Research
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    • v.21 no.2
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    • pp.25-30
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    • 2008
  • A hemispherical microbond specimen adhered onto single carbon fiber has been proposed for evaluating the interfacial shear strength between epoxy and carbon fiber. Hemispherical microbond specimens showed low interfacial shear strength data and its small standard deviation as compared with the droplet one, which seemed to be caused by the reduction of the meniscus effects and of the stress concentration in the region contacting with the tip of pin hole. In comparison with the droplet specimen the hemispherical specimen showed the shear stress distribution similar to the cylindrical one in that low stress concentration arose around the contacting region. Average interfacial shear strength obtained by the hemispherical ones represented a good correlation with the hardness of the epoxy matrix.

Delamination behavior of multidirectional laminates under the mode I loading (모드 I 하중조건하에 있는 다방향 적층 복합재료의 층간파괴거동)

  • Choi, Nak-Sam;Kinloch, A.J.
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.22 no.3
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    • pp.611-623
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    • 1998
  • The delamination fracture of multidirectional carbon-fiber/epoxy laminates under the Mode I condition has been studied using the modified beam analysis for a fracture mechanics approach. It was found that the variation of fracture energy $G_IC$ with increasing length of the propagating crack exhibited a minimum for the pure interlaminar fracture and a maximum for the intraply fracture,i.e. a rising "R-curve", which was strongly affected by the degree of fiber bridging and crack-tip splitting arising in the global delamination. The maximum $G_IC$ value was significantly dependent on such types of delamination as no crack jumping, crack jumping into the adjacent ply and edge-delamination. It was shown also that the value of "effective flexural modulus" estimated from the modified beam analysis increased much with the development of fiber bridging behind the crack tip.ehind the crack tip.

Behavior of Initiation and Propagation of Fatigue Crack under Periodic Overstressing (In the case of Fatigue Limit Stresses) (과대, 과소 응력하에서의 피로크랙 발생거동 (피로한도 응력을 중심으로))

  • 송남홍;원시태
    • Transactions of the Korean Society of Mechanical Engineers
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    • v.15 no.6
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    • pp.1839-1851
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    • 1991
  • Fatigue crack behavior is studied through the two-level rotary bending test with the deep non-through radial holed notch specimens of low carbon steels(SM22C). The main factors investigated are the effects of the damage zone size around crack tip and phenomena of closing or opening of the crack tip. Obtained results are summarized as follows. Fatigue crack behavior in second level stressing slightly lower than fatigue limit is closely related to the size of damage zone produced by the first level stress higher than fatigue limit and to the phenomena of crack closing and opening for the second level stress. The non-propagating crack limit condition depends upon the crack length l$_{1}$ propagated under the first level stress and the magnitude of second level stress .sigma.$_{2}$ lower than the fatigue limit. The non-propagating crack limit condition is expressed by following eq. $\sigma_2^{6.1}{\times}l_{1}=7.35{\times}10^{6}[(kg_{f}mm^{6.1}(mm)]$