• Title/Summary/Keyword: Carbon reduction program

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Effect of pH and Temperature on the Electrochemical Reduction of Carbon Dioxide by Carbon Monoxide Dehydrogenase (일산화탄소탈수소화효소를 이용한 이산화탄소의 전기화학적 환원에 미치는 pH와 온도의 영향)

  • Shin, Jun-Won;Kim, You-Sung;Lee, Sang-Hee;Lee, Sang-Phil;Lee, Ho-Jun;Lim, Mi-Ran;Song, Ji-Eun;Shin, Woon-Sup
    • Journal of the Korean Electrochemical Society
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    • v.10 no.4
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    • pp.265-269
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    • 2007
  • The effects of experimental variables for the electrochemical reduction of carbon dioxide by Carbon Monoxide Dehydrogenase (CODH) were investigated. It shows the pH optimum at 6.3 where the feasibility of electro-chemical reduction and the stability of CODH compromise each other. The optimum temperature for the reduction was at $60^{\circ}C$ where the enzyme shows the optimum activity although the solubility of carbon dioxide decreases as increasing temperature.

A Study on Improvement and Effect of Carbon Point Program for Residential Buildings in Daegu (대구광역시 주거 건축물의 이산화탄소 배출 감축을 위한 탄소포인트제의 효과 및 개선방향에 관한 연구)

  • Yeo, Myung-Kil;Jeon, Gyu-Yeob;Hong, Won-Hwa;Cho, Woong-Ho
    • Journal of the Korean housing association
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    • v.23 no.4
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    • pp.11-18
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    • 2012
  • The amount of energy consumption in the buildings is approximately 20% of domestic energy consumption. The Carbon Point Program have been published on reduction of greenhouse gas emission in buildings under the paradigm of 'Low Carbon Green Growth'. This study focuses on the effect of 'Carbon Point Program' for residential buildings in Daegu. The amount of electricity and waterwork consumption and information of households were investigated to analyse the effect of carbon point program. The samples are situated in Deagu and are apartment in Bukgu and Suseonggu. The $CO_2$ emission is analysed by factors of energy resource and household organization between before participating and after participating in Carbon Point Program. The participation type has a difference of voluntary participation in Suseonggu and passive participation in Bukgu. Based on this investigation, average amount of $CO_2$ emission was reduced from voluntary participation households but all of them did not. To promote the effect of Carbon Point Program, this study proposes that needing the plans to raise will and activity of reducing carbon and to help participation which have disadvantage against achieving reduction.

System Dynamics Application for the Evaluation of Greenhouse Gases Reduction Policy (시스템다이내믹스 기법을 이용한 온실가스 감축정책 평가)

  • Jang, Namjung;Kim, Min-Kyong;Yang, Go-Su
    • Korean System Dynamics Review
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    • v.14 no.1
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    • pp.55-68
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    • 2013
  • It is necessary to evaluate the greenhouse gases (GHGs) reduction policy by central and regional governments to set up the suitable GHG emissions measures. Quantitative, qualitative and synthetic methods have been adopted by previous researches to estimate GHG reduction policy. However, these methods mostly focused on the results of the reduction policy, rather than understanding and fixing the integrated structures of GHG emissions. In this research, System Dynamics(SD) was applied to 1 million green homes program, self-carfree-day system and carbon point program. The results showed that SD analyses could be appliable for the estimation of GHG reduction policy by developing the feedback loops and dynamic simulation model. SD can be consider as a supplementary tool to estimate the GHG reduction policies through the recognition of the structure in complex real system.

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Effect of Electrode Materials and Applied Potential in Electrocatalytic Reduction of Carbon Dioxide by Carbon Monoxide Dehydrogenase (일산화탄소탈수소화효소를 이용한 이산화탄소의 전기화학적 환원에 미치는 전극재료와 전위의 영향)

  • Shin, Jun Won;Kim, You-Sung;Song, Ji-Eun;Lee, Sang-Hee;Lee, Sang-Phil;Lee, Ho-Jun;Lim, Mi-Ran;Shin, Woon-Sup
    • Journal of the Korean Electrochemical Society
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    • v.11 no.3
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    • pp.165-169
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    • 2008
  • The effect of reduction of carbon dioxide by CODH(Carbon Monoxide Dehydrogenase) was compared on glassy carbon and gold working electrodes. In case of gold electrode, the choice of the optimum applied potential is very important since $H_2$ evolution can be mixed with $CO_2$ reduction. On the other hand, efficient $CO_2$ reduction was observed up to -650 mV vs. NHE on glassy carbon in neutral solution due to the larger overpotential for $H_2$ evolution on glassy carbon surface than that on gold surface. The optimum potential for $CO_2$ reduction was found to be $-570{\sim}600\;mV$ vs. NHE. The current efficiency of $CO_2$ to CO decreased dramatically at more negative potential according to the activity of enzyme decrease and the hydrogen evolution.

Synthesis of Nitrogen-doped Carbon Nanofibers for Oxygen Reduction Reaction (산소환원반응 촉매용 질소 도핑된 탄소나노섬유의 제조)

  • An, Geon-Hyoung;Lee, Eun-Hwan;Ahn, Hyo-Jin
    • Journal of Powder Materials
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    • v.23 no.6
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    • pp.420-425
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    • 2016
  • N-doped carbon nanofibers as catalysts for oxygen-reduction reactions are synthesized using electrospinning and carbonization. Their morphologies, structures, chemical bonding states, and electrochemical performance are characterized. The optimized N-doped carbon nanofibers exhibit graphitization of carbon nanofibers and an increased nitrogen doping as well as a uniform network structure. In particular, the optimized N-doped carbon nanofibers show outstanding catalytic activity for oxygen-reduction reactions, such as a half-wave potential ($E_{1/2}$) of 0.43 V, kinetic limiting current density of $6.2mAcm^{-2}$, electron reduction pathways (n = 3.1), and excellent long-term stability after 2000 cycles, resulting in a lower $E_{1/2}$ potential degradation of 13 mV. The improvement in the electrochemical performance results from the synergistic effect of the graphitization of carbon nanofibers and the increased amount of nitrogen doping.

How does Voluntary Carbon Disclosure (VCD) Induce Changes in Carbon Performance? With the Role of Management Capability

  • Kim, Seonae;Kim, Jong Dae
    • Journal of Environmental Science International
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    • v.30 no.10
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    • pp.863-877
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    • 2021
  • While there a growing interest in Voluntary Carbon Disclosure (VCD), comparatively little is discussed whether the improved quality of voluntary carbon disclosure can lead to subsequent changes in a company's carbon reduction performance. Drawing on companies under the Korean Emission Trading Scheme (ETS) with the contents analysis of their sustainable reports, the present research seeks to address the existing knowledge gaps in the current literature on environmental disclosure. Findings empirically show that an increase in the voluntary carbon disclosure score is positively transformed into changes in carbon performance and further develop that the effect of voluntary carbon disclosure on carbon performance varies depending on changes in management capability with the moderation effect.

An Evaluation of Net-zero Contribution Regarding Hydrogen Energy Conversion in Urban Building and Transport Sector (도시의 건물 및 수송 부문에서의 수소에너지 전환에 따른 탄소중립 기여도 평가)

  • SO JEONG JANG;RAE SANG PARK;YOUNG HOON CHOI;YONG WOO HWANG
    • Transactions of the Korean hydrogen and new energy society
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    • v.34 no.2
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    • pp.100-112
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    • 2023
  • This study evaluated the contribution of carbon neutrality by calculating the carbon reduction amount and reduction intensity targeting the hydrogen pilot city and applying it to the carbon neutral reduction target. In the building sector, the reduction amount for 2030 was 10.8% on average. In addition, by 2050, the contribution to carbon neutrality of plan A was 14.1% on average, and the contribution to carbon neutrality of plan B was 15.1% on average. In the 2030 reduction amount of the transportation sector, the contribution to carbon neutrality was 138.4% on average. In addition, by 2050, the contribution to carbon neutrality in plan A was 82.5% on average, and the contribution to carbon neutrality in plan B was 74.9%. From the above research results, additional carbon reduction is possible when creating a hydrogen city, so it will be used as a basis of city-level carbon neutral model. It will also be used as a basis for technology development and investment promotion for various hydrogen supply methods in the future.

Synthesis of Nitrogen Doped Protein Based Carbon as Pt Catalysts Supports for Oxygen Reduction Reaction (산화환원반응용 백금 촉매 지지체를 위한 질소 도핑된 단백질계 탄소의 제조)

  • Lee, Young-geun;An, Geon-hyeong;Ahn, Hyo-Jin
    • Korean Journal of Materials Research
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    • v.28 no.3
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    • pp.182-188
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    • 2018
  • Nitrogen (N)-doped protein-based carbon as platinum (Pt) catalyst supports from tofu for oxygen reduction reactions are synthesized using a carbonization and reduction method. We successfully prepare 5 wt% Pt@N-doped protein-based carbon, 10 wt% Pt@N-doped protein-based carbon, and 20 wt% Pt@N-doped protein-based carbon. The morphology and structure of the samples are characterized by field emission scanning electron microscopy and transmission electron micro scopy, and crystllinities and chemical bonding are identified using X-ray diffraction and X-ray photoelectron spectroscopy. The oxygen reduction reaction are measured using a linear sweep voltammogram and cyclic voltammetry. Among the samples, 10 wt% Pt@N-doped protein-based carbon exhibits exellent electrochemical performance with a high onset potential of 0.62 V, a high $E_{1/2}$ of 0.55 V, and a low ${\Delta}E_{1/2}=0.32mV$. Specifically, as compared to the commercial Pt/C, the 10 wt% Pt@N-doped protein-based carbon had a similar oxygen reduction reaction perfomance and improved electrochemical stability.

Investigation of Korean Forest Carbon Offset Program : Current Status and Cognition of Program Participants (산림탄소상쇄제도의 사업참여자 인식 및 현황 분석)

  • Sa, Yejin;Woo, Heesung;Kim, Joonsoon
    • Journal of Korean Society of Forest Science
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    • v.111 no.1
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    • pp.165-176
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    • 2022
  • To raise awareness of carbon reduction in climate change, the Korea Forest Service has developed and adopted a forest carbon offset program, which aims to reduce carbon levels based on forest management. However, to maintain the forest carbon offset program, challenges such as the lack of a forest monitoring system to manage and maintain the program, must be faced. In this context, we investigated the limitations of conducting forest carbon offset programs using a number of interview techniques, including in-depth interview and questionnaire survey methods. The questionnaire surveys were developed based on the results of a literature review along with a preinterview and in-depth survey of the people in charge of the forest carbon offset program. The Irving Seidman technique was adopted for the in-depth interviews. Additionally, descriptive and frequency analyses were conducted to identify the characteristics of perception. Lastly, logistic regression was used to identify the limiting factors that affect the willingness to perform forest carbon offset monitoring activity. Results showed that the project managers or people in charge of the forest carbon offset program lacked expertise in forest carbon offset programs, which negatively affected their willingness to perform monitoring activity. Additionally, the study revealed a number of limiting factors that hindered the monitoring of forest carbon offset projects. Improving understanding using the approaches presented in this study may contribute to increasing the benefits associated with the forest carbon offset program in South Korea.

Carbon Emission Analysis Considering Demand Response Effect in TOU Program (TOU 프로그램의 DR 효과를 고려한 탄소 배출 분석)

  • Kim, Young-Hyun;Kwag, Hyung-Geun;Kim, Jin-O
    • The Transactions of The Korean Institute of Electrical Engineers
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    • v.60 no.6
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    • pp.1091-1096
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    • 2011
  • Currently, the concern about the environment is the issue all over the world, and in particular, carbon emissions of the power plants will not be able to disregard from the respect of generation cost. This paper proposes DR (demand response) as a method of reducing carbon emissions and therefore, carbon emissions cost. There are a number of studies considering DR, and in this paper, the effect of DR is focused on the side of carbon emission reduction effect considering Time-Of-Use (TOU) program, which is one of the most important economic methods in DSM. Demand-price elasticity matrix is used in this paper to model and analyze DR effect. Carbon emissions is calculated by using the carbon emission coefficient provided by IPCC (Intergovernmental Panel on Climate Change), and generator's input-output characteristic coefficients are also used to estimate carbon emission cost as well as the amount of carbon emissions. Case study is conducted on the RBTS IEEE with six buses. For the TOU program, it is assumed that parameters of time period partition consist of three time periods (peak, flat, off-peak time period).