• Title/Summary/Keyword: Carbon nanotube (CNT)

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Parametric Characterization of Zinc Oxide Nanostructures Forming Three-Dimensional Hybrid Nanoarchitectures on Carbon Nanotube Constructs (산화아연 나노구조의 탄소나노튜브와의 혼성구조 형성 특성 연구)

  • Ok, Jong G.
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.39 no.6
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    • pp.541-548
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    • 2015
  • We study the structural and functional characteristics of zinc oxide (ZnO) nanostructures that are grown on carbon nanotube (CNT) constructs via step-wise chemical vapor deposition (CVD). First, we optimize the CVD process to directly grow ZnO nanostructures on CNTs by controlling the growth temperature below $600^{\circ}C$, where CNTs can be sustained in a ZnO-growing oxidative atmosphere. We then investigate how the morphology and areal density of ZnO nanostructures evolve depending on process parameters, such as pressure, temperature, and gas feeding composition, while focusing on the effect of underlying CNT topology on ZnO nucleation and growth. Because various types of ZnO nanostructures, including nanowires, nanorods, nanoplates, and polycrystalline nanocrystals, can be conformally formed on highly conductive CNT platforms, this electrically addressable three-dimensional hybrid nanoarchitecture may better meet a wide range of nanoelectronic application-specific needs.

Laser Patterning of Vertically Grown Carbon Nanotubes (수직성장된 탄소나노튜브의 선택적 패터닝)

  • Chang, Won Seok
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.36 no.12
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    • pp.1171-1176
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    • 2012
  • The selective patterning of a carbon nanotube (CNT) forest on a Si substrate has been performed using a femtosecond laser. The high shock wave generated by the femtosecond laser effectively removed the CNTs without damage to the Si substrate. This process has many advantages because it is performed without chemicals and can be easily applied to large-area patterning. The CNTs grown by plasma-enhanced chemical vapor deposition (PECVD) have a catalyst cap at the end of the nanotube owing to the tip-growth mode mechanism. For the application of an electron emission and biosensor probe, the catalyst cap is usually removed chemically, which damages the surface of the CNT wall. Precise control of the femtosecond laser power and focal position could solve this problem. Furthermore, selective CNT cutting using a femtosecond laser is also possible without any phase change in the CNTs, which is usually observed in the focused ion beam irradiation of CNTs.

Study on Performance Comparison in Carbon Nanotube Embedded Electrospun Membranes for Particulate Matter Removal (탄소나노튜브가 첨가된 전기방사 멤브레인의 미세입자 제거 성능 비교에 관한 연구)

  • Gu, Minkyung;kim, Dongwan;Han, Sangil
    • Korean Chemical Engineering Research
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    • v.56 no.1
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    • pp.56-60
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    • 2018
  • There have been a lot of study to improve the performance of membrane filters as the removal of particulate matter has been of great interest due to the negative effects. Among the membrane fabrication techniques, the electrospinning technique is the most promising because it can produce uniform fibers ranging from nano to micrometer size. The electrospun membranes will greatly improve the filtration performance due to the high ratio of surface area to volume and the high porosity. In the present study, polystyrene (PS) and cellulose acetate (CA) polymers were used to produce the membranes with carbon nanotube (CNT), showing the filtration performances were improved with the optimal amounts of CNT.

Mechanical and Thermal Properties of Epoxy Composites Reinforced Fluorinated Illite and Carbon Nanotube (불소화 일라이트 및 탄소나노튜브 강화 에폭시 복합재의 기계적 및 열적 특성)

  • Lee, Kyeong Min;Lee, Si-Eun;Kim, Min Il;Kim, Hyeong Gi;Lee, Young-Seak
    • Applied Chemistry for Engineering
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    • v.27 no.3
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    • pp.285-290
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    • 2016
  • To improve properties of epoxy composites, surfaces of the illite and carbon nanotube (CNT) were treated by fluorine gas. The fluorinated illite and CNT were then characterized by X-ray photoelectron microscopy (XPS) and the mechanical and thermal properties of their composites were evaluated. The tensile and impact strengths and thermal stability of the composites increased upto about 59%, 18% and 124%, respectively compared to those of the neat epoxy. Improvements of mechanical and thermal properties in the composites were attributed that the fluorination of illite and carbon nanotube helps to enhance the dispersion in epoxy resin and interfacial interaction between them.

Thermal effects on nonlinear dynamic characteristics of polymer-CNT-fiber multiscale nanocomposite structures

  • Ebrahimi, Farzad;Habibi, Sajjad
    • Structural Engineering and Mechanics
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    • v.67 no.4
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    • pp.403-415
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    • 2018
  • In the present study, nonlinear dynamic response of polymer-CNT-fiber multiscale nanocomposite plate resting on elastic foundations in thermal environments using the finite element method is performed. In this regard, the governing equations are derived based on Inverse Hyperbolic Shear Deformation Theory and von $K{\acute{a}}rm{\acute{a}}n$ geometrical nonlinearity. Three type of distribution of temperature through the thickness of the plate namely, uniform linear and nonlinear are considered. The considered element is C1-continuous with 15 DOF at each node. The effective material properties of the multiscale composite are calculated using Halpin-Tsai equations and fiber micromechanics in hierarchy. The carbon nanotubes are assumed to be uniformly distributed and randomly oriented through the epoxy resin matrix. Five types of impulsive loads are considered, namely the step, sudden, triangular, half-sine and exponential pulses. After examining the validity of the present work, the effects of the weight percentage of SWCNTs and MWCNTs, nanotube aspect ratio, volume fraction of fibers, plate aspect, temperature, elastic foundation parameters, distribution of temperature and shape of impulsive load on nonlinear dynamic response of CNT reinforced multi-phase laminated composite plate are studied in details.

Gassensing characteristics of carbon nanotube gas sensor using a diaphragm structure (다이아프램 구조를 이용한 탄소나노튜브 가스 센서의 가스감응특성)

  • Kim, Sung-Woon;Han, Chun-Jae;Cho, Woo-Sung;Ju, Byeong-Kwon;Cho, Hyun-Seob;Kim, Young-Cho
    • Proceedings of the KAIS Fall Conference
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    • 2006.05a
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    • pp.203-206
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    • 2006
  • The sensor consists of a heater, an insulating layer, a pair of contact electrodes, and CNT-sensing film on a micromachined diaphragm. The heater plays a role in the temperature change to modify sensor operation. Gas sensor responses of CNT-film to $NO_2$ at room temperature are reported. The sensor exhibits a reversible response with a time constant of a few minutes at thermal treatment temperature of $130^{\circ}C$.

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Vacuum In-line Sealing Technology of the Screen-printed CNT-FEA

  • Kwon, Sang-Jik;Kim, Tae-Ho;Shon, Byeong-Kyoo;Cho, Euo-Sik;Lee, Jong-Duk;Uh, Hyung-Soo;Cho, Sung-Hee;Lee, Chun-Gyoo
    • Journal of Information Display
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    • v.4 no.3
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    • pp.6-11
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    • 2003
  • We have fabricated a carbon nanotube field emission display (CNT-FED) panel with a 2-inch diagonal size by using a screen printing method and vacuum in-line sealing technology. The sealing temperature of the panel was around 390$^{\circ}C$ and the vacuum level was obtained with 1.4x$10^{-5}$torr at the sealing. When the field emission properties of a fabricated and sealed CNT-FED panel were characterized and compared with those of the unsealed panel which was located in a test chamber of vacuum level similar with the sealed panel. As a result, the sealed panel showed similar I-V characteristics with unsealed one and uniform light emission with very high brightness at a current density of 243 ${\mu}A/cm^2$, obtained at the electric field of 10 V/${\mu}m$.

Analysis of the Robot for Detection of Improvised Explosive Devices and a Technology for the CNT based Detection Sensor (급조 폭발물(IED) 제거 로봇의 개발비용 분석 및 카본나노튜브 기반 탐지센서기술에 관한 연구)

  • Kwon, Hye Jin
    • Journal of the Semiconductor & Display Technology
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    • v.17 no.1
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    • pp.54-61
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    • 2018
  • In this study, two aspects were analyzed about the robot for removal of explosive devices. First, the cost analyses were performed to provide a reasonable solution for the acquirement of the system. It is processed by an engineering estimate method and the process was consisted of two ways : a system development expense and a mass production unit price. In additions, the resultant cost analyses were compared between the cases excluding and including a mines detection system. As results, in the case of the acquirement of the robot system for removal of explosive devices, it is recommended that the performance by improving the mines detection ability should be considered preferentially rather than the cost because the material cost for the mines detection system is negligible compared to the whole system cost. Second, as a way for improving the system performance by the mine detection function, the carbon nanotube (CNT) based sensor technology was studied in terms of sensitivity and simple productivity with presenting its preliminary experimental results. The detection electrodes were formed by a photolithography method using a photosensitive CNT paste. As results, this method was shown as a scalable and expandable technology for the excellent mines detection sensors.

Suppressing Effect of Hydrogen Evolution by Oxygen Functional Groups on CNT/ Graphite Felt Electrode for Vanadium Redox Flow Battery (탄소나노튜브/흑연펠트 전극의 산소작용기를 활용한 바나듐 레독스 흐름 전지의 수소발생 억제 효과)

  • Kim, Minseong;Ko, Minseong
    • Journal of Surface Science and Engineering
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    • v.54 no.4
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    • pp.164-170
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    • 2021
  • Vanadium redox flow batteries (VRFB) have emerged as large-scale energy storage systems (ESS) due to their advantages such as low cross-contamination, long life, and flexible design. However, Hydrogen evolution reaction (HER) in the negative half-cell causes a harmful influence on the performance of the VRFB by consuming current. Moreover, HER hinders V2+/V3+ redox reaction between electrode and electrolyte by forming a bubble. To address the HER problem, carbon nanotube/graphite felt electrode (CNT/GF) with oxygen functional groups was synthesized through the hydrothermal method in the H2SO4 + HNO3 (3:1) mixed acid solution. These oxygen functional groups on the CNT/GF succeed in suppressing the HER and improving charge transfer for V2+/V3+ redox reaction. As a result, the oxygen functional group applied electrode exhibited a low overpotential of 0.395 V for V2+/V3+ redox reaction. Hence, this work could offer a new strategy to design and synthesize effective electrodes for HER suppression and improving the energy density of VRFB.

Interfacial Evaluation of Single-Carbon Fiber/Phenolic and Carbon Nanotube-Phenolic Composites Using Micromechanical Tests and Electrical Resistance Measurements (미세역학시험법과 전기저항 측정을 이용한 탄소섬유/페놀수지 및 탄소나노튜브-페놀수지 복합재료의 계면특성 평가)

  • Wang, Zuo-Jia;Kwon, Dong-Jun;Gu, Ga-Young;Park, Jong-Kyoo;Lee, Woo-Il;Park, Joung-Man
    • Journal of Adhesion and Interface
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    • v.11 no.4
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    • pp.149-154
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    • 2010
  • Interfacial evaluation was investigated for single-carbon fiber/phenolic and carbon nanotube (CNT)-phenolic composites by micromechanical technique and electrical resistance measurement combined with wettability test. Compressive strength of pure phenol and CNT-phenolic composites were compared using Broutman specimen. The contact resistance of CNT-phenolic composites was obtained using a gradient specimen by two and four-point methods. Surface energies and wettability by dynamic contact angle measurement were measured using Wilhelmy plate technique. Since hydrophobic domains are formed as heterogeneous microstructure of CNT in the surface, the dynamic contact angle exhibited more than $90^{\circ}$. CNT-phenolic composites exhibited a higher apparent modulus than neat phenolic case due to better stress transferring effect. Work of adhesion, $W_a$ between single-carbon fiber and CNT-phenolic composites exhibited higher than neat phenolic resin due to the enhanced viscosity by CNT addition. It was consistent with micro-failure patterns in microdroplet test.