• Proceedings of the Korean Society of Precision Engineering Conference
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• 2009.06a
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• pp.867-868
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• 2009

• Journal of the Korean Chemical Society
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• v.66 no.3
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• pp.251-255
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• 2022

• Journal of the Korean Vacuum Society
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• v.17 no.5
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• pp.473-480
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• 2008

We have investigated the optimal growth conditions of carbon nanotubes (CNTs) using the chemical vapor deposition and the Ni nanoparticle arrays. The diameter of the CNT is shown to be controlled down to below 20 nm by changing the size of Ni particle. The position and size of Ni particles are controlled continuously by using wafer-scale compatible methods such as lithography, ion-milling, and chemical etching. Using optimal growth conditions of temperature, carbon feedstock, and carrier gases, we have demonstrated that an individual CNT can be grown from each Ni nanoparticle with almost 100% probability over wide area of $SiO_2/Si$ wafer. The position, diameter, and wall thickness of the CNT are shown to be controlled by adjusting the growth conditions.

• Smart Structures and Systems
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• v.31 no.6
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• pp.545-559
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• 2023

Nanoparticle strips (NPS) are widely used as external reinforcers for two-way reinforced concrete slabs. However, the Structural Health Monitoring (SHM) of these slabs is a very important issue and was evaluated in this study. This study has been done analytically and numerically to optimize the placement of sensors. The properties of slabs and carbon nanotubes as composite sheets were considered isotopic and orthotropic, respectively. The nonlinear Finite Element Method (FEM) approach and suitable optimal placement of sensor approach were developed as a new MATLAB toolbox called DECOMAC by the authors of this paper. The Suitable multi-objective function was considered in optimized processes based on distributed ECOMAC method. Some common concrete slabs in construction with different aspect ratios were considered as case studies. The dimension and distance of nano strips in retrofitting process were selected according to building codes. The results of Optimal Sensor Placement (OSP) by DECOMAC algorithm on un-retrofitted and retrofitted slabs were compared. The statistical analysis according to the Mann-Whitney criteria shows that there is a significant difference between them (mean P-value = 0.61).

• Bulletin of the Korean Chemical Society
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• v.28 no.11
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• pp.2056-2060
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• 2007

A successful combination of “oxygen-assisted chemical vapor deposition (CVD) process” and Co catalyst nanoparticles to grow highly pure single walled carbon nanotubes (SWNTs) was demonstrated. Recently, it was reported that addition of small amounts of oxygen during CVD process dramatically increased the purity and yield of carbon nanotubes. However, this strategy could not be applied for discrete Fe nanoparticle catalysts from which appropriate yields of SWNTs could be grown directly on solid substrates, and fabricated into field effect transistors (FETs) quite efficiently. The main reason for this failure is due to the carbothermal reduction which results in SiO2 nanotrench formation. We found that the oxygen-assisted CVD process could be successfully applied for the growth of highly pure SWNTs by switching the catalyst from Fe to Co nanoparticles. The topological morphologies and p-type transistor electrical transport properties of the grown SWNTs were examined by using atomic force microscope (AFM), Raman, and from FET devices fabricated by photolithography.

• Journal of the Korean Chemical Society
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• v.64 no.1
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• pp.49-53
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• 2020

• Composites Research
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• v.29 no.4
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• pp.223-229
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• 2016

SiC nanoparticles were used to increase flexural properties of polymer matrix. This study was to manufacture huge concentration SiC nanoparticle/epoxy composites and to evaluate the dispersion. During mixing SiC nanoparticle and epoxy, 20 wt% SiC nanoparticle in total composites was used with both stirrer and sonication equipment together. Mixing speed and dispersion were improved with the method by using both stirrer and sonication equipment at the same time via mechanical test and FE-SEM. Based on the results, modeling of SiC nanoparticle dispersion could be established. Ultimately, unidirectional carbon fiber reinforced composites was manufactured using 20 wt% SiC nanoparticle/epoxy. Mechanical property of CFRP using dual stirrer and sonication mixing method was better than composites by single sonication mixing method.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.16 no.10
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• pp.6439-6444
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• 2015

With increasing concern about global warming, CCS (Carbon dioxide capture and storage) has attracted much attention as a promising technology for reducing $CO_2$ emission. It is necessary to develop the cost-effective absorbents materials in order to rapid commercialize CCS technologies. In this work, he study for the promotion of absorption rate in $CO_2$ capture system using metal nanoparticle were investigated. Three kinds of metal nanoparticle, cobalt, zinc, and nickel, were prepared by wet and dry method and effect of preparation method on the absorption rate of $CO_2$ were compared. Among the tested using pH method, nickel nanoparticle prepared by wet method showed the most significant improvement of $CO_2$ absorption rate. In case that metal nanoparticle is applied to CCS process, it is expected to be more efficient in $CO_2$ capture process due to reduce the size of absorption tower.

• Advances in nano research
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• v.6 no.4
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• pp.357-375
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• 2018

Two dimensional (2D) atomic layered nanomaterials exhibit some of the most striking phenomena in modern materials research and hold promise for a wide range of applications including energy and biomedical technologies. Graphene has received much attention for having extremely high surface area to mass ratio and excellent electric conductivity. Graphene has also been shown to maximize the activity of surface-assembled metal nanoparticle catalysts due to its unique characteristics of enhancing mass transport of reactants to catalysts. This paper specifically investigates the strategy of pre-formed nanoparticle self-assembly used for the formation of various metal nanoparticles supported on graphene families such as graphene, graphene oxide, and reduced graphene oxide and aims at understanding the interactions between ligand-capped metal nanoparticles and 2D nanomaterials. By varying the functional groups on the ligands between alkyl, aromatic, amine, and alcohol groups, different interactions such as van der Waals, ${\pi}-{\pi}$ stacking, dipole-dipole, and hydrogen bonding are formed as the 2D hybrids produced.

• Journal of Korean Society of Occupational and Environmental Hygiene
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• v.20 no.3
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• pp.184-191
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• 2010

Although the usage of nanomaterials including carbon nanotubes (CNTs) has increased in various fields, scientific researches on workers' exposures and controls of these materials are very limited. The purpose of this study was to compare the airborne nanoparticles concentrations from two university laboratories conducting experiments of CNTs growth based on containment of thermal chemical vapor deposition (CVD). Airborne nanoparticle concentrations in three metrics (surface area concentration, particle number concentration, and mass concentrations) were measured by task using three direct reading instruments. In a laboratory where CVD was not contained, the surface area concentration, number concentration and mass(PM$_1$) concentration of airborne nanoparticles were 1.5 to 3.5 times higher than those in the other laboratory where CVD was confined. The ratio of PM$_1$ concentration to total suspended particles(TSP) in the laboratory where CVD was not confined was about 4 times higher than that in the other laboratory. This indicates that CVD is a major source of airbone nanoparticles in the CNTs growth laboratories. In conclusion, researchers performing CNTs growth experiments in these laboratories were exposed to airborne nanoparticles levels higher than background levels, and their exposures in a laboratory with the unconfined CVD were higher than those in the other laboratory with the confined CVD. It is recommended that in the CNTs growth laboratories adequate controls including containment of CVD be implemented for minimizing researchers' exposures to airborne nanoparticles.