Browse > Article

Comparison of Airborne Nanoparticle Concentrations between Carbon Nanotubes Growth Laboratories based on Containment of CVD  

Ha, Ju-Hyun (Department of Occupational Health and Safety Engineering, Inje University)
Shin, Yong-Chul (Department of Occupational Health and Safety Engineering, Inje University)
Publication Information
Journal of Korean Society of Occupational and Environmental Hygiene / v.20, no.3, 2010 , pp. 184-191 More about this Journal
Abstract
Although the usage of nanomaterials including carbon nanotubes (CNTs) has increased in various fields, scientific researches on workers' exposures and controls of these materials are very limited. The purpose of this study was to compare the airborne nanoparticles concentrations from two university laboratories conducting experiments of CNTs growth based on containment of thermal chemical vapor deposition (CVD). Airborne nanoparticle concentrations in three metrics (surface area concentration, particle number concentration, and mass concentrations) were measured by task using three direct reading instruments. In a laboratory where CVD was not contained, the surface area concentration, number concentration and mass(PM$_1$) concentration of airborne nanoparticles were 1.5 to 3.5 times higher than those in the other laboratory where CVD was confined. The ratio of PM$_1$ concentration to total suspended particles(TSP) in the laboratory where CVD was not confined was about 4 times higher than that in the other laboratory. This indicates that CVD is a major source of airbone nanoparticles in the CNTs growth laboratories. In conclusion, researchers performing CNTs growth experiments in these laboratories were exposed to airborne nanoparticles levels higher than background levels, and their exposures in a laboratory with the unconfined CVD were higher than those in the other laboratory with the confined CVD. It is recommended that in the CNTs growth laboratories adequate controls including containment of CVD be implemented for minimizing researchers' exposures to airborne nanoparticles.
Keywords
nanomaterials; carbon nanotubes; airborne nanoparticle; laboratory; containment;
Citations & Related Records
연도 인용수 순위
  • Reference
1 Coleman JN, Khan U, Blau WJ, Gun'ko YK. Small but strong: a review of the mechanical properties of carbon nanotube-polymer composites. Carbon, 2006;44:1624-1652   DOI   ScienceOn
2 Han JH, Lee EJ, Lee JH, So KP, Lee YH et al. Monitoring multiwalled carbon nanotube exposure in carbon nanotube research facility. Inhalation Toxicology, 2008;20:741-749   DOI   ScienceOn
3 남기석, 탄소나노튜브의 합성과 응용. NICE, 2005;23(1):54-62
4 과학기술부. 나노기술영향평가 보고서, 2005.
5 Monteiro-Riviere N, Nemanich R, Inman A, Wang Y, Riviere J. Multi-walled carbon nanotube interactions with human epidermal keratinocytes. Toxicology Letters, 2005;155(3):377-384   DOI   ScienceOn
6 Subcommittee on Nanoscale Science, Engineering, and Technology(NEST), Committee on Technology(CT), National Science and Technology Council: The National Nanotechnology Initiative Strategic Plan, National Nanotechnology Coordination Office(NNCO), U.S. Government, Arlington, VA, 2004.
7 Takagi AH, Hirose A, Nishimura T, Fukumori N, Ogata A et al. Induction of mesothelioma in p53+/- mouse by intraperitoneal application of multi-wall carbon naanotube. Journal of Toxicological Sciences, 2008;33(1):105-116   DOI   ScienceOn
8 Warheit DB, Laurence BR, Reed KL, Roach DH, Reynolds GAM et al. Comparative pulmonary toxicity of single-wall carbon nanotubes in rats Journal of Toxicological Sciences, 2003;77:117-125   DOI
9 Lam CW, James JT, McCluskey R. and Hunter RL. Pulmonary toxicity of single-wall carbon nanotubes in mice 7 and 90 days after intratracheal instillation. Toxicological Sciences, 2004;77:126-134
10 Maynard AD, and Michelson E. Nanotechnology Consumer Products Inventory, Woodrow Wilson International Center for Scholars, 2005.
11 National Institute for Occupational Safety and Health (NIOSH). NIOSH Safty and Health Topic: Nanotechnology. Available from http://www.cdc.gov/niosh/topics/nanotech/ on August, 2010.
12 Paik SY, Zalk DM, Swuste P. Application of pilot control banding tool for risk level assessment and control of nanoparticle exposures. Annals of Occupational Hygiene, 2008;52(6):419-428   DOI   ScienceOn
13 Poland CA, Duffin R, Kinloch I, Maynard A, Wallace WAH et al. Carbon nanotubes introduced into the abdominal cavity of mice show asbestos-like pathogenicity in a pilot study. Nature Nanotechnology, 2008;3:423-428   DOI   ScienceOn
14 Baughman RH, Zakhidov AA, de Heer WA. Carbon nanotubes-the route toward applications. Science, 2002;297(5582):787-792   DOI   ScienceOn
15 Garcia EJ, Hart AJ, Wardle BL, Slocum AH. Fabrication of composite microstructures by capillarity-driven wetting of aligned carbon nanotubes with polymers. Nanotechnology, 2007;18:165602   DOI   ScienceOn
16 Hart AJ, Slocum AH. Rapid growth and flow-mediate nucleation of millimeter-scale aligned carbon nanotubes from a thin-film catalyst. Journal of Physical Chemistry B, 2006;110:8250-8257   DOI   ScienceOn
17 Bello D, Hart AJ, Ahn K, Hallock M, Yamamoto N et al. Particle exposure levels during CVD growth and subsequent handling of vertically-aligned carbon nanotube films. Carbon, 2008;46:974-981   DOI   ScienceOn
18 Dresselhaus M, Dresselhaus G, Avouris P. Carbon Nanotubes: Synthesis, Structure, Properties, and Applications, NY. Springer, 2001.
19 최붕기, 김경호, 소대섭, 유일재. 나노기술의 영향에 관한 연구동향. KIC News, 2007;10(1):48-71
20 Ajayan PM, Tour JM. Nanotube composites. Nature, 2007;447:1066-1068   DOI   ScienceOn