• Title/Summary/Keyword: Carbon nanofiber

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Patch-type large strain sensor using elastomeric composite filled with carbon nanofibers

  • Yasuoka, Tetsuo;Shimamura, Yoshinobu;Todoroki, Akira
    • International Journal of Aeronautical and Space Sciences
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    • v.14 no.2
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    • pp.146-151
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    • 2013
  • Carbon nanofibers (CNFs) are electrically conductive. When CNFs are used as fillers in resin, this electrical conductivity can be yielded without adversely affecting the mechanical properties of the resin. When an elastomer is adopted as the resin, a conductive elastomer can then be produced. Due to its flexibility and conductive properties, a large strain sensor based on changes in resistivity may be produced, for strain sensing in flexible structures. In this study, a patch-type large strain sensor using resistivity change in a CNF/elastomer composite was proposed. The measurement limits of the sensor were investigated experimentally, and the limit was found to be 40%, which greatly exceeded the limits of conventional metal-foiled strain gages. Also, the proposed CNF/elastomer large strain sensor can be used to measure flexible materials, while conventional strain gages cannot be used to measure such strains.

Structure and field emission properties of carbon-nitrogen (CN) nanofibers obtained by hot isostatic pressure (Hot isostatic pressure을 이용한 CN nanofiber의 구조 및 전계방출 특성)

  • Lee, Yang-Doo;Blank, V.D.;Batov, D.V.;Buga, S.G;Nahm, Sahn;Lee, Yun-Hi;Ju, Byeong-Kwon
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2003.04a
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    • pp.84-87
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    • 2003
  • Carbon-nitrogen (CN) nanofibers have been produced using a water cooled hot isostatic pressure (HIP) apparatus. The CN nanofibers were grown in random with the diameter of about 100-150nm and length over $10{\mu}m$. Emission properties of CN nanofibers were investigated for spacing, between anode and cathode, variation. Then turn-on fields about $1.4V/{\mu}m$. The time reliability and light emission test were carried out for above 100 hours. We suggest that CN nanofibers can be possibly applied to high brightness flat lamp because of low turn-on field and time reliability.

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Structure and Electron Emission Properties of CN Nanostructures Obtained by HIP Apparatus (HIP에 의해 합성된 CN nanostructures의 구조 및 전계방출 특성)

  • 오정근;이양두;문승일;양석현;이윤희;김남수;주병권
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.16 no.8
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    • pp.723-730
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    • 2003
  • The CN(carbon nitrogen) nanofibers were formed by HIP(high isostatic pressure) process. From the field emission measurement, CN nanofibers shows an excellent characteristics of emitter, better than CNTs and carbon nanofibers. The structures obtained can be divided into three groups : bamboo-like fibers, corrugated structures and bead necklace-like fib res. Emission properties of CN nanofibers were investigated for spacing, between anode and cathode, variation. Turn-on fields was 1.4 v/$\mu\textrm{m}$. The time reliability and light emission test were carried out for about 100 hours. We suggest that CN nanofibers can be possibly applied to the high brightness flat lamp because of low turn-on field and time reliability

Thermal, Frictional and Wear Behavior of Carbon Nanofiber/Poly(methyl methacrylate) Composites (탄소나노섬유/폴리(메틸 메타크릴레이트) 복합재료의 열적 및 마찰 마모 거동 연구)

  • Park Soo-Jin;Im Se-Hyuk;Lee Jae-Rock;Rhee John-M.
    • Polymer(Korea)
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    • v.30 no.5
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    • pp.385-390
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    • 2006
  • In this work, the effect of carbon nanofiber (CNF) on thermal properties, and friction and wear behavior of CNF/PMMA composites were examined. While thermal properties of the composites were investigated with differential scanning calorimetry, thermograyimetric analyzer, and dynamic mechanical analyzer friction and wear behaviors were examined using a friction and wear tester. The glass transition temperature (Tg), integral procedural decomposition temperature (IPDT), storage modulus (E'), and tan ${\delta}$ appeared at higher temperatures with increasing CNF content, which were probably attributed to the presence of strong interactions between the carbonaceous fillers and the PMMA resins matrix. The wear loss in the composites decreased at 0.1 wt% CNF and then increased with 5-10 wt% CNF content. This was due to the existence of large aspect ratio CNF in PMMA which led to an alignment of PMMA chains and an increase of mechanical interlocking, resulting in the formation of crosslinked structures between CNF and PMMA in the composite.

Self-Sensing and Interfacial Property of Carbon Nanofiber/Epoxy Composites with Different Aspect Ratios (형상비가 다른 탄소나노섬유/에폭시 복합재료의 자체 감지능 및 계면특성)

  • Jang, Jung-Hoon;Kim, Pyung-Gee;Kim, Sung-Ju;Wang, Zuo-Jia;Park, Joung-Man;Yoon, Dong-Jin
    • Journal of Adhesion and Interface
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    • v.9 no.1
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    • pp.3-8
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    • 2008
  • Self-sensing was evaluated for carbon nanofiber (CNF)/epoxy composites with two different aspect ratios via electro-micromechanical technique and wettability test. Volumetric electrical resistance was measured to evaluate the comparative dispersion degree indirectly and it decreased due to the increase of electric contacts with increasing CNF concentration. The dispersion degree was evaluated indirectly by calculating coefficient of variation (COV) of volumetric electrical resistance. The CNF type A with a high aspect ratio showed better self-sensing than the case of CNF type B with a short aspect ratio. The CNF type B/epoxy composite showed little self-sensing at a concentration higher than 2 vol% probably due to poor dispersion. The apparent modulus of CNF type B was higher than that of CNF type A due to the orientation effect and the high surface area. The thermodynamic work of adhesion was consistent with the result of apparent modulus.

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Bonding Behavior of Carbon Black/Nylon 66 Hybrid Nanofiber Webs via Microwave Heating (카본블랙/나일론 66 혼합 나노섬유웹의 마이크로파에 의한 접착거동)

  • Shin, Dong-Ho;Joo, Chang-Whan
    • Proceedings of the Korean Fiber Society Conference
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    • 2003.10b
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    • pp.114-117
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    • 2003
  • Conventional heating the heat source cause the molecules to react from the surface toward the center so that successive layers of molecules heat in turn. The product surfaces may be in danger of over heating by the time heat penetrates the material. Microwave, however, produce a volume heating effect. All molecules are set in action at the same time. It also evens temperature gradients and offers other important benefits such as selective heating. (omitted)

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Characteristics of Photoresist-derived Carbon Nanofibers for Li-ion Full Cell Electrode

  • Kim, Hwan-Jun;Joo, Young-Hee;Lee, Sang-Min;Kim, Chang-Il
    • Transactions on Electrical and Electronic Materials
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    • v.15 no.5
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    • pp.265-269
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    • 2014
  • Carbon nanofiber electrode has been fabricated for energy storage systems by the electrospinning of SU-8 precursor and subsequent pyrolysis. Various parameters including the applied voltage, the distance between syringe tip and target collector and the flow rate of the polymer affect the diameter of SU-8 electrospun nanofibers. Shrinkage during pyrolysis decreases the fiber diameter. As the pyrolysis temperature increases, the resistivity decreases dramatically. Low resistivity is one of the important characteristics of the electrodes of an energy storage device. Given the advantages of carbon nanofibers having high external surface area, electrical conductivity, and lithium intercalation ability, SU-8 derived carbon nanofibers were applied to the anode of a full lithium ion cell. In this paper, we studied the physical properties of carbon fiber electrode by scanning transmission microscopy, thermal gravimetric analysis, and four-point probe. The electrochemical characteristics of the electrode were investigated by cyclic voltammogram and electrochemical impedance spectroscopy plots.

Fabrication of Biomass Based Polyethylene Furoate Nanofiber by Electrospinning (전기방사법을 이용한 바이오매스 유래 polyethylene furoate 나노섬유 제조에 관한 연구)

  • Choi, Hyun-Jin;Kim, Sun Hee;Kim, Beak-Jin;Kim, Sang Bum
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.15 no.6
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    • pp.4024-4031
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    • 2014
  • Nanofibers have attracted significant interest in many industrial fields because their high surface area and porosity. In addition, the continued use of petrochemical based polymers has caused the depletion of oil resources and accelerated the greenhouse effect by the emission of carbon dioxide. Therefore, biomass-based polymer has become a very important environmentally friendly alternative. In this study, nanofibers were fabricated by an electrospinning process using biomass based PEF(polyethylene furoate) prepared by the polymerization of 2,5-furandicaboxylic acid and ethylene glycol. Furthermore, the electrospun nanofiber was strongly affected by various parameters, such as the solvent, polymer concentration and electric field. In conclusion, nanofibers with an average fiber diameters of 200 - 700 nm could be prepared at polymer concentration of 15 wt% using HFIP, and their fiber diameter increased with increasing electric field.

Study on the Electrospun Nanofiber Fabrication and Alignment of the Functionalized CNT Reinforced Polymer (전기방사 방법을 사용한 기능화된 탄소나노튜브 강화 고분자 수지 나노섬유 제조에 관한 연구)

  • Yoon Yu-Hwan;Park Joo-Hyuk
    • Proceedings of the Korean Society of Precision Engineering Conference
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    • 2005.06a
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    • pp.680-685
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    • 2005
  • Multi-walled carbon nanotubes were purified by using the nitric acid after the mechanical cutting, which carboxylic group might be introduced into the surface of nanotubes. To enhance the dispersion of CNTs, carboxylic groups were substituted in the reaction with octadecyl amine containing a long alkyl group. Nanofibers were manufactured by electrospinning, the solution that mixed with PMMA and ODA-fuctionalized CNTs in dimethyl formamide and dispersed with ultrasonication. Diameter and alignment of nanofibers with various electrospinning parameters, such as the CNT and PMMA concentration in solution, the applied voltage, and the distance to the collector were investigated. As a result, the nanofiber diameter was increased with the increment of PMMA concentration, whereas it was reduced as the applied voltage and the spinning distance was increased. The spinning area became smaller with the distance. The nanofibers were formed without the defect on surface and well aligned in a specific concentration of PMMA and nanotubes.

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