• Title/Summary/Keyword: Carbon ignition

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Numerical Study on Ignition Delay Time of CH4 as CO/H2 Addition in MILD Combustion (MILD 연소 환경에서 CO/H2 첨가에 따른 CH4의 점화 지연 시간의 해석적 연구)

  • Kim, Donghee;Huh, Kang Y.;Lee, Youngjae
    • Journal of the Korean Institute of Gas
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    • v.25 no.2
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    • pp.1-12
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    • 2021
  • MILD(Moderate or Intense Low-oxygen Dilution) combustion has attracted attention as the clean thermal energy technology due to the lower emissions of unburnt carbon and NOx. MILD combustion aims to enlarge the combustion reaction zone using the spontaneous ignition phenomenon of the reactants. In this study, the ignition delay time of CH4 according to the initial temperature of reactants and the addition of CO, H2 was investigated using a numerical approach. Ignition delay time became shorter as the increases of initial temperature and H2 addition. But, CO addition to the fuel increase the ignition delay time. In case of H2 addition to the fuel, the ignition delay time decreased because the higher fraction of HO2 promotes the decomposition of methyl radical(CH3) and produce OH radical. However, in case of CO addition to the fuel, ignition delay time inceased because a high proportion of HCO consumes H radical. There was no significant effect of HCO on the reduction of ignition delay time. Also, the increase rates of NO emissions by the addition of CO and H2 were approximately 7% and 1%, respectively. A high proportion of NCO affects the increase in NO production rate.

A Study on the Function of Organic Admixture in Fly Ash Substituting Fresh Concrete (플라이애쉬를 혼합(混合)한 굳지않은 콘크리트에 있어서 유기혼화제(有機混和劑)의 기능(機能)에 관한 연구(研究))

  • Moon, Han Young;Sea, Joung Woo
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.8 no.2
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    • pp.117-124
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    • 1988
  • From the test results of the adsorption characteristics of AE admixture, it was shown that the adsorption of AE admixture on fly ash was mearly completed in 30 minutes and the higher was ignition loss, the larger the quantity of saturation adsorption. Because most of the ignition loss of the fly ash was due to the unburned carbon, it could be said that the unburned carbon is the main reason of reduction of air content in AE concrete. On the other hand, in the case of superplasticizer, the amount of saturation adsorption in fly ash was lower than in cement and the same result was obtained in the dispersive effect. But, when using superplasticizer in fly ash substituting concrete, the fludity in the concrete was not decreased.

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Effect of pre-post injection timing of diesel fuel for naval vessel on the combustion and emission characteristics in an optically-accessible single cylinder diesel engine (단기통 디젤엔진에서 함정용 디젤유의 전·후 분사시기가 연소 및 배출가스 특성에 미치는 영향)

  • Lee, Hyungmin
    • Journal of Advanced Marine Engineering and Technology
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    • v.38 no.7
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    • pp.868-876
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    • 2014
  • The objective of this study is focused on the analyzing combustion, carbon monoxide and hydrocarbon emission characteristics of marine diesel oil, utilized for naval propulsion engine, with varying pre-post injection timing of an optically accessible single cylinder engine. And also the combustion process is analyzed by means of a high speed camera visualization. On the result of retarding pre-injection timing toward main injection timing, the mean effective pressure and maximum pressure of combustion chamber are increased; however, the heat release rate is decreased. Furthermore, the emission rates of carbon monoxide and hydrocarbon are reduced in this case. In hence, when a post-injection timing is advanced, the mean effective pressure and maximum pressure are increased, because the combustion has been performed under the high temperature and high pressurized environment during main injection time, and the emission rates of carbon monoxide and hydrocarbon are increased. From the experimental results, it considered that retarding of pre-injection timing affects to shorten the ignition delay of main injection clearly, and to raise the flame intensity comparing to the advanced state. The ignition delay during post-injection is not appeared at any post-injection time, but the flame intensity has been weakened gradually according to the retarding of post-injection timing.

An Experimental Study on the Spontaneous Ignition of Flaxseed Oil and Olive Oil Adsorbed on Towels (타올에 흡착된 아마인유와 올리브유의 자연발화에 대한 실험적 연구)

  • Kim, Kyoung-Su;Choi, Yu-Jung;Choi, Jae-Wook
    • Journal of the Society of Disaster Information
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    • v.18 no.2
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    • pp.324-332
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    • 2022
  • Purpose: In order to conduct a spontaneous ignition test in which a fire occurs in the absence of an ignition source due to the oil adsorbed on the towel. A phenomenon in which spontaneous ignition occurs when adsorbed to fibers using flaxseed oil, which is drying oil and olive oil, which is non-drying oil, is tested through an experiment. Method: After placing the sample container in the experimental device, observe the change in the central temperature of the sample, and when the central temperature rises above the set temperature and a fire occurs, it is judged as "ignition", and the experiment is stopped after checking the maximum value of the central temperature of the sample,When the central temperature of the sample was maintained similar to the set temperature, it was judged as "non-ignition" and the experiment was stopped. Result: In the towels with adsorbed flaxseed oil, the temperature in the sample container increased rapidly and combustion occurred in sheets 5, 10, and 15. Olive oil is a non-drying oil, does not ignite because it is difficult to dry because carbon is a single bond and it is difficult to bond with oxygen. Conclusion: It was confirmed that the more the amount of towel adsorbed to the drying oil, flaxseed oil, the longer the time to reach the set temperature and the occurrence of ignition.

A Study on the Explosion Riskiness with Flying of Activated Carbon (활성탄의 부유중 폭발 위험성에 관한 연구)

  • 김정환;현성호;이창우;함영민
    • Fire Science and Engineering
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    • v.12 no.3
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    • pp.3-9
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    • 1998
  • We investigated the weight loss according to temperature using TGA in order to find the thermal hazard of brand-new activated-carbon and disused activated-carbon dusts, and the properties of dust explosion in variation of the specific surface area of their dust with the same particle size. Using hartman's dust explosion apparatus which estimate dust explosion by electric ignition after making dust disperse by compressed air, dust explosion experiments have been conducted by varying concentration and size of activated carbon dust. The explosion pressure of both activated carbon increased as the specipic surface area increased. The results indicated that brand-new activated-carbon of which specific surface area was larger three to four times than that of disused activated-carbon was much easier of dust explosion.

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Combustion and Exhaust Emission Characteristics by the Change of Intake Air Temperature in a Single Cylinder Diesel Engine (단기통 디젤엔진에서 흡기온도변화에 따른 연소 및 배기특성)

  • Shin, Dalho;Park, Suhan
    • Transactions of the Korean Society of Automotive Engineers
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    • v.25 no.3
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    • pp.336-343
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    • 2017
  • Intake air conditions, such as air temperature, pressure, and humidity, are very important parameters that influence engine performance including combustion and emissions characteristics. The purpose of this study is to investigate the effects of intake air temperature on combustion and exhaust emissions characteristics in a single cylinder diesel engine. In this experiment, an air cooler and a heater were installed on the intake air line and a gas flow controller was installed to maintain the flow rate. It was found that intake air temperature induced the evaporation characteristics of the fuel, and it affects the maximum in-cylinder pressure, IMEP(indicated mean effective pressure), and fuel consumption. As the temperature of intake air decreases, the fuel evaporation characteristics deteriorate even as the fuel temperature has reached the auto-ignition temperature, so that ignition delay is prolonged and the maximum pressure of cylinder is also reduced. Based on the increase in intake air temperature, nitrogen oxides(NOx) increased. In addition, the carbon monoxide(CO) and unburned hydrocarbons(UHC) increased due to incomplete fuel combustion at low intake air temperatures.

Hydrogen Gas Production from Methane Reforming Using Oxygen Enriched Compression Ignition Engine (산소부화 압축착화기관을 이용한 메탄으로부터 수소 생산)

  • Lim, Mun-Sup;Hong, Sung-In;Hong, Myung-Seok;Chun, Young-Nam
    • Journal of Korean Society for Atmospheric Environment
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    • v.23 no.5
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    • pp.557-562
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    • 2007
  • The purpose of this paper is to investigate the reforming characteristics and maximum operating condition for the hydrogen production by methane reforming using the compression ignition engine induced partial oxidation. An dedicated compression engine used for methane reforming was decided operating range. The partial oxidation reforming was investigated with oxygen enrichment which can improve hydrogen production, compared to general reforming. Parametric screening studies were achieved as $O_2/CH_4$ ratio, total flow rate, and intake temperature. When the variations of $O_2/CH_4$ ratio, total flow rate, and intake temperature were 1.24, 208.4 L/min, and $400^{\circ}C$, respectively, the maximum operating conditions were produced hydrogen and carbon monoxide. Under the condition mentioned above, synthetic gas were $H_2\;22.77{\sim}29.22%,\;CO\;21.11{\sim}23.59%$.

A STUDY ON THE FLAMMABILITY OF NON-FLAME-RETARDANT AND FLAME-RETARDANT MATERIALS BY USING CONE CALORIMETER

  • Yanai, Eiji;Suzuki, Takeshi;Yamada, Tokiyoshi
    • Proceedings of the Korea Institute of Fire Science and Engineering Conference
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    • 1997.11a
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    • pp.85-92
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    • 1997
  • Flammability of non-flame-retardant and flame-retardant materials was studied by using cone calorimeter Also, relations between the results obtained by using cone calorimeter and those obtained by the flammability test of japanese fire Service Law were examined. The results are as follows: 1) The ignition time of the molten specimens is relatively long, whereas the ignition time of the non-molten specimens is short. None of remarkable difference of the ignition time has been found between non-flame-retardant and flame-retardant materials specimens. 2) The peak heat release rates of flame-retardant materials are smaller than those of non-flame- retardant materials. 3) The carbon monoxide and smoke evolved from flame-retardant materials generate much more than those evolved from non-flame-retardant materials. 4) Even if flame-retardant materials are passed by the flammability test of Japanese Fire Service Law, they burn easily under external radiative heating condition.

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Improvement of Thermal Efficiency and Emission by Lean Combustion in a Boosted Spark-Ignition Engine Fueled with Syngas (합성가스 스파크점화 과급 엔진에서 희박 연소를 통한 열효율 및 배기 개선)

  • Park, Hyunwook;Lee, Junsun;Jamsran, Narankhuu;Oh, Seungmook;Kim, Changup;Lee, Yonggyu;Kang, Kernyong
    • Journal of ILASS-Korea
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    • v.26 no.1
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    • pp.40-48
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    • 2021
  • Lean combustion was applied to improve the thermal efficiency and emission in a single-cylinder, spark-ignition engine fueled with syngas. Under naturally aspirated conditions, the lean combustion significantly improved the thermal efficiency compared to the stoichiometric combustion, mainly due to the reduction in heat transfer loss. Intake air boost was applied to compensate the low power output of the lean combustion. The gross indicated power of 24.8 kW was achieved by increasing the intake pressure up to 1.6 bar at excess air ratio of 2.2. The nitrogen oxides showed near zero level, but the carbon monoxide emission was significant.

Crossover Temperature and Ignition Delay Time of Diluted Hydrogen-Air Mixtures (희석된 수소-공기 혼합기의 크로스오버 온도와 점화지연시간)

  • Dong Youl, Lee;Eui Ju, Lee
    • Journal of the Korean Society of Safety
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    • v.37 no.6
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    • pp.18-24
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    • 2022
  • Hydrogen is a clean fuel and is used in many applications in power systems such as fuel cells. It has unique properties such as wide flammability, high burning velocity, and difficulty to liquefy, which lead to critical safety issues. Fire and explosion are the most frequently occurring accidents and one of the major reasons is autoignition. In the ignition process, the chemistry of hydrogen combustion depends mainly on radical pools, and the temperature at which chain-branching and terminating rates are equal is called the crossover temperature. This study addresses the homogeneous autoignition of diluted hydrogen-air mixtures to investigate the effects of dilution on the crossover temperature to prevent explosions in the future. The new criterion for crossover temperature is introduced by only hydrogen radicals to adjust more simply. The detailed calculations indicate that the crossover temperatures are low at high dilutions of carbon dioxide and nitrogen because the concentrations of active radicals are reduced when an inert gas is added. This result is expected to contribute to hydrogen safety and realize a hydrogen society in the future.