• Title/Summary/Keyword: Carbon formation

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A Review on Microbialites: a Korean Perspective (미생물암에 대하여: 한국적 관점)

  • Lee, Jeong-Hyun
    • The Journal of the Petrological Society of Korea
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    • v.24 no.4
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    • pp.291-305
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    • 2015
  • Microbialites are defined as rocks formed by microbial organisms. After their first appearance around 3.5 billion years ago, microbialites occur in various depositional environments throughout geological periods. Microbial organisms form microbialites by trapping and binding detrital sediments and/or precipitating carbonate cements, resulting in formation of various microstructures and mesostructures. Four major types of microbialites are distinguished based on their mesostructures: stromatolite, thrombolite, dendrolite, and leiolite. In the geological records, occurrences of microbialites are influenced by calcium carbonate saturation of seawater and interaction of microbialites with metazoans. Stromatolites mainly flourished during the Precambrian, and diminished as level of atmospheric carbon dioxide declined. On the other hand, thrombolites, mainly formed by calcified microbes, began to flourish from the Neoproterozoic. As metazoans diversified in the Phanerozoic, proportion of the microbialites within sedimentary record declined. Since then, microbialites only occasionally flourished during the Phanerozoic, such as shortly after mass-extinction events. In the Korean Peninsula, microbialites occur in the Neoproterozoic Sangwon System, the Early Paleozoic Joseon Supergroup, and the Cretaceous Gyeongsang Supergroup, which form different shapes according to their age and depositional environments. By performing detailed studies on these Korean microbialites, it is possible to understand how microbes affected geological records and sedimentary environments, as well as their interaction with other organisms.

Characterization and Identification of an Agar-Degrading Motile Bacteria Strain (Agar를 분해하는 swarming 박테리아 균주의 특성과 동정)

  • Kang, Sung-Wan;Yoo, Ah-Young;Yu, Jong-Earn;Kang, Ho-Young
    • Journal of Life Science
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    • v.22 no.2
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    • pp.259-265
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    • 2012
  • A bacterial strain, CK214, exhibiting high motility on an LB agar (1.5%, w/v) surface was isolated from the environment. The formation of unusual agar shrinking around colonies on agar plates was observed. The strain grew on minimal media containing pure agar as a sole carbon source. The cell-free culture supernatant of CK214 generated a reduced form of sugar in the in vitro reaction with the use of pure agar as a substrate, suggesting the secretion of an agar-degrading enzyme. The CK214 strain showed swarming motility on the solid media containing a wide range of concentrations of agar (0.5, 1.0, 1.5, 2.0% w/v). Various tests, including Gram staining, API analysis, and phylogenetic analysis based on 16S rDNA sequences identified that the CK214 strain was a G(+) rod-shaped bacterium grouped in genus Paenibacillus. Electron microscopic analysis demonstrated that the P. CK214 strain is peritrichously flagellated. Through transposon random mutagenesis, several agar-degrading activity defective mutants (ADMs) were generated. These mutants will be used in the future experimentation for the study of the correlation between agar-degrading activity and motility.

An Evaluation of Environmental-Control Function on Forest Using GIS (GIS를 활용한 산림녹지의 환경조절적 기능 평가)

  • Lee, Woo-Sung;Jung, Sung-Gwan
    • Journal of the Korean Association of Geographic Information Studies
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    • v.14 no.4
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    • pp.102-115
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    • 2011
  • The purpose of this study is to establish the evaluation model through the systematic process of selecting the indicators and to evaluate the environmental-control function on forest using GIS in Deagu for the sustainable forest planning. The 35 indicators as basic items were selected by literature review and those were squeezed into the 29 indicators through expert brainstorming. Also, the 8 indicators to evaluate environmental-control function were selected by the first survey and the 5 final indicators such as carbon sink, temperature decrease, wind formation, water circulation, air purification were determined by MCB analysis using the second survey. The evaluation model was established through the weight of each indicator by AHP analysis using the third survey. According to the result of evaluating the environmental-control function on forest, the functions around the top area of Mt. Ap, Mt. Biseul, Mt. Palgong had more than 66 scores. On the other hand, the functions around Mt. Waryong and forest of Chilgok in Buk-gu had less than 40 scores. It is necessary to improve the function through the sustainable restoration and management in case of forest that the environmental-control function was lower. Furthermore, these results will be able to be utilized as basic data in order to establish the preservation area and control development area at the urban, environmental, and forest planning.

Dimethyl Carbonate Synthesis by Methanol Oxidative Carbonylation (메탄올 산화 카르보닐화에 의한 디메틸카보네이트 합성)

  • Nam, Jeong-Kwang;Cho, Deug-Hee;Suh, Jeong-Kwon;Kim, Seong-Bo
    • Korean Chemical Engineering Research
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    • v.49 no.5
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    • pp.530-534
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    • 2011
  • The synthesis of dimethyl carbonate by liquid phase oxidative carbonylation of methanol was studied under batch reaction system. Reaction factors such as effect on various metals, anion containing in copper catalyst, temperature, carbon monoxide and oxygen molar ratio and copper content were investigated. In particular $CuCl_2{\cdot}2H_2O$ showed the excellent of the methanol conversion 65.2%, DMC selectivity 96.6% reaction condition under 1.0 g, $150^{\circ}C$, MeOH/CO/$O_2$=0.2/0.215/0.05 (molar ratio). $CuCl_2$ led to corrosion of the reactor. Thus, a new catalyst system using supports was investigated to resolve these corrosion problem. Influence on various supports were examined and copper catalyst supported on zeolite Y showed the most excellent activity on the formation of dimethyl carbonate. The amount of Fe dissolved during the reaction using ICP-AES (Inductively Coupled Plasma-Atomic Emission Spectrometer) was compared with catalysts, calcined Cu/zeolite Y showed the lower value below 5% than $CuCl_2-2H_2O$.

Fabrication of Hydrogel and Gas Permeable Membranes for FET Type Dissolved $CO_{2}$ Sensor by Photolithographic Method (사진식각법을 이용한 FET형 용존 $CO_{2}$ 센서의 수화젤막 및 가스 투과막 제작)

  • Park, Lee-Soon;Kim, Sang-Tae;Koh, Kwang-Nak
    • Journal of Sensor Science and Technology
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    • v.6 no.3
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    • pp.207-213
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    • 1997
  • A field effect transistor(FET) type dissolved carbon dioxide($pCO_{2}$) sensor with a double layer structure of hydrogel membrane and $CO_{2}$ gas permeable membrane was fabricated by utilizing a $H^{+}$ ion selective field effect transistor(pH-ISFET) with Ag/AgCl reference electrode as a base chip. Formation of hydrogel membrane with photo-crosslinkable PVA-SbQ or PVP-PVAc/photosensitizer system was not suitable with the photolithographic process. Furthermore, hydrogel membrane on pH-ISFET base chip could be fabricated by photolithographic method with the aid of N,N,N',N'-tetramethyl othylenediarnine(TED) as $O_{2}$ quencher without using polyester film as a $O_{2}$ blanket during UV irradiation process. Photosensitive urethane acrylate type oligomer was used as gas permeable membrane on top of hydrogel layer. The FET type $pCO_{2}$ sensor fabricated by photolithographic method showed good linearity (linear calibration curve) in the range of $10^{-3}{\sim}10^{0}\;mol/{\ell}$ of dissolved $CO_{2}$ in aqueous solution with high sensitivity.

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Physiology characteristics of genus Hypocrea isolated at oyster mushrooms of the shelf cultivation (균상재배 느타리버섯에서 분리한 Hypocrea속 균의 생리적 특성)

  • Lee, Chan-Jung;Moon, Ji-Won;Cheong, Jong-Chun;Kong, Won-Sik;Jhune, Chang-Sung
    • Journal of Mushroom
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    • v.13 no.1
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    • pp.68-73
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    • 2015
  • Hypocrea disease is the most severe disease of oyster mushroom cultivation in Korea. Physiological and ecological studies were performed on the pathogens (Hypocrea spp.) to obtain basic information for developing the integrated disease management system. Fourteen isolates of Hypocrea were collected from oyster mushroom house in five areas. Pathogenic fungi causing disease of oyster mushroom were identified as Hypocrea sp. based on morphological characteristics and pathogenicity. Two isolates (H-1, H-12) showed the fastest growth at $15^{\circ}C$ but four isolates (H-8, H-9, H-13, H-14) showed slower growth than those of other isolates at $20^{\circ}C$ and $25^{\circ}C$. Stroma with ascocarps and ascospore were produced on PDA under fluorescent light. The five isolates produced stroma with ascocarps and ascospores. Formation of fruiting body of strains H-14 of Hypocrea were the best out of all the strains on the potato dextrose agar (PDA). Also, fruiting bodies and ascospores were completely produced under fluorescent light. The growth of the isolates was correlated with total carbon content. The stroma of the isolates was formed mainly in histidine and asparagine treatment and especially in histidine-70 and asparagine-100 treatment. In the test of pathogenicity, after and before spawning showed very fast incidence of disease.

Characteristics and Fabrication of Thermal Oxidized-SnO2 (SnO2 열산화감지막의 제작 및 특성)

  • Kang, Bong-Hwi;Lee, Duk-Dong
    • Journal of Sensor Science and Technology
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    • v.11 no.6
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    • pp.342-349
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    • 2002
  • New formation technique of metal oxide sensing film was proposed m this paper. Silicon wafer with Pt electrodes was used as a substrate for depositing metal Sn film. Metal Sn was deposited in the state of not continuous film but only island state. The samples were prepared to obtain the optimal condition of metal Sn deposition. The resistances of deposited Sn onto Pt electrodes amounted to $1\;k{\Omega}$, $5\;k{\Omega}$, $10\;k{\Omega}$ and $50\;k{\Omega}$, respectively. Also The sample with $1,500\;{\AA}$ thickness of Sn was prepared m order to compare sensing properties between conventional type and proposing type. After deposition of metal Sn, $SnO_2$ was formed by thermal oxidation method for 3 hrs. in $O_2$ ambient at $700^{\circ}C$. Surface morphology, crystal structure and surface roughness of oxidized-sensing film were examined by SEM, XRD, and AFM, respectively. From the results of these analyses, the optimal deposition condition of Sn was that the Pt electrode resistance became $10\;k{\Omega}(300\;{\AA})$. Also, the sensing characteristics of fabricated sensing film for various concentrations of butane, propane and carbon monoxide gases were measured at he operating temperatures of $250^{\circ}C$, $300^{\circ}C$ and $350^{\circ}C$, respectively. Although catalyst as not added to the sensing film, it has exhibited the high sensitivity to all the test gases.

Absorption Properties of Carbon Dioxide in Aqueous 2-Amino-2-methyl-1-propanol Solution (2-Amino-2-methyl-1-propanol 수용액에 대한 이산화탄소의 흡수특성에 관한 연구)

  • Park, Sang Hyun;Kim, Sung Hyun;Min, Byung Moo
    • Applied Chemistry for Engineering
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    • v.9 no.1
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    • pp.107-114
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    • 1998
  • The solubilities of $CO_2$ in 20wt% and 30wt% aqueous AMP solution were obtained from experiments at 40, 50, 60, 70, $80^{\circ}C$. Using the modified Kent-Eisenberg model, equilibrium constants and correlations were determined from the regression of experimental results of 30wt% aqueous AMP solution. There were good agreements between the predicted $CO_2$ solubilities in 20wt% aqueous AMP solution and experimented values. The prediction was conducted at the condition in the literature and the predicted values calculated from the model and correlations which were obtained from this work agree well with the prediction from Deshmukh-Mather model. Thus, the modified Kent-Eisenberg model and correlated equations suggested by this work, resonably well represent vapor-liquid equilibrium of $CO_2$ with aqueous AMP solution. The calculation of chemical species concentration in the liquid phase was performed uslng equilibrium model and from this calculation, we confirm that good absorption capacity is due to the formation of unstable carbamate. Heat of solution(${\Delta}Hs$) was calculated from the solubility data using the Gibbs-Helmholtz equation.

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Modified Atmosphere Storage for Extending Shelf Life of Oyster Mushroom and Shiitake (환경가스조절 저장방법을 이용한 느타리버섯과 표고버섯의 유통기간 연장)

  • Han, Dae-Seok;Ahn, Byung-Hak;Shin, Hyun-Kyung
    • Korean Journal of Food Science and Technology
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    • v.24 no.4
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    • pp.376-381
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    • 1992
  • In order to study the effect of modified atmosphere storage on extending shelf life of mushrooms, oyster mushroom and Shiitake were wrapped with polyethylene film (PE, $50\;{\mu}m$), and stored at $0.5^{\circ}C$. Mushrooms packed with conventional hardboard box (4kg) lost marketability within $5{\sim}6$ days due to weight loss, shrinkage, browning, spore formation and/or mycellium growth. PE-packing could prevent or retard the deterioration of the mushrooms in the aspects of appearance, texture, discoloration, and microbial contamination. This situation can be best characterized by the reduced respiration rate resulted from the elevated level of carbon dioxide and the reduced level of oxygen in the bag. Although the appearance of the oyster mushroom was maintained for one month, its shelf life was limited to 15 days because of tissue softening. Discoloration of the pileus of shiitake mushroom appears to be the most important factor to determine its marketability. For example, extension of shelf life of Dongo was limited to 15 days, principally due to the browning of the pileus. Shelf life of Hawgo whose color of the pileus changed little over the experimental period, however, could be extened to more than one month.

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Effect of By-Product Gypsum Fertilizer on Methane Gas Emissions and Rice Productivity in Paddy Field

  • Park, Jun-Hong;Sonn, Yeon-Kyu;Kong, Myung-Suk;Zhang, Yong-Seon;Park, Sang-Jo;Won, Jong-Gun;Lee, Suk-Hee;Seo, Dong-Hwan;Park, So-Deuk;Kim, Jang-Eok
    • Korean Journal of Soil Science and Fertilizer
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    • v.49 no.1
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    • pp.30-35
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    • 2016
  • Rice cultivation in paddy field affects the global balance of methane ($CH_4$) as a key greenhouse gas. To evaluate a potential use of by-product gypsum fertilizer (BGF) in reducing $CH_4$ emission from paddy soil, $CH_4$ fluxes from a paddy soil applied with BGF different levels (0, 2, 4 and $8Mg\;ha^{-1}$) were investigated by closed-chamber method during rice cultivation period. $CH_4$ flux significantly decreased (p<0.05) with increasing level of BGF application. $8Mg\;ha^{-1}$ of BGF addition in soil reduced $CH_4$ flux by 60.6% compared to control. Decreased soil redox potential (Eh) resulted in increasing $CH_4$ emission through a $CO_2$ reduction reaction. The concentrations of dissolved calcium (Ca) and sulfate ion (${SO_4}^{2-}$) in soil pore water were significantly increased as the application rate of BGF increased and showed negatively correlations with $CH_4$ flux. Decreased $CH_4$ flux with BGF application implied that ${SO_4}^{2-}$ ion led to decreases in electron availability for methanogen and precipitation reaction of Ca ion with inorganic carbon including carbonate and bicarbonate as a source of $CH_4$ formation under anoxic condition. BGF application also increased rice grain yield by 16% at $8Mg\;ha^{-1}$ of BGF addition. Therefore, our results suggest that BGF application can be a good soil management practice to reduce $CH_4$ emission from paddy soil and to increase rice yield.