• Journal of Hydrogen and New Energy
• /
• v.26 no.5
• /
• pp.499-506
• /
• 2015

Recently the Korean government announced its decision to select the $3^{rd}$ proposal, which targets reducing $CO_2$ by 37% of the BAU level by 2030, for the Intended Nationally Determined Contribution (INDC). According to this proposal, natural gas (or equivalent gas) combined cycle (NGCC) are suggested as alternatives for conventional pulverized coal (PC). In this study, we analyzed the environmental, economic, and energy mixing aspects of synthetic natural gas combined cycle(SNGCC) using NETL material (2011~2012 version) and other domestic materials (2014 version). We found the following conclusions: 1) Considering carbon capture and storage (CCS) integration, $CO_2$ emission factors of SNGCC and supercritical PC are the same. However, 60% of $CO_2$ from SNGCC is produced as high pressure and high purity (99%) gas, making it highly suitable for CCS, which is now strongly supported by the government. 2) Based on the economic analysis for SNGCC using domestic materials and comparison with NGCC, it was found that the settlement price of SNGCC was 30% lower than that of NGCC.

• Journal of Welding and Joining
• /
• v.9 no.2
• /
• pp.44-50
• /
• 1991

The use of high tensile steel plates is increasing in the fabrication of ship and offshore structures. The softening region which has lower yield stress than base metal is located to prevent cracking in the conventional high tensile steel. Also, thermo mechanical control process(TMCP) steel with low carbon equivalent has the softening region which occurs in the heat affected zone when high heat input weld is carried out. The softening region in the high tensile steel gives rise to serious effect on structural strength such as tensile strength, fatigue strength and ultimate strength. In order to make a reliable structural design using high tensile steel plates, the influence of the softening on plate strength should be evaluated in advance. In the previous paper, the authors discussed the ultimate compressive strength of 50HT steel square plates with softening region. In this paper, the ultimate compressive strength with varying the yield stress of softening region and the aspect ratio of the plate is investigated by using the elasto-plastic large deformation finite element method.

• Computers and Concrete
• /
• v.25 no.2
• /
• pp.155-166
• /
• 2020

In this work, the buckling and vibrational behavior of the composite beam armed with single-walled carbon nanotubes (SW-CNT) resting on Winkler-Pasternak elastic foundation are investigated. The CNT-RC beam is modeled by a novel integral first order shear deformation theory. The current theory contains three variables and uses the shear correction factors. The equivalent properties of the CNT-RC beam are computed using the mixture rule. The equations of motion are derived and resolved by Applying the Hamilton's principle and Navier solution on the current model. The accuracy of the current model is verified by comparison studies with others models found in the literature. Also, several parametric studies and their discussions are presented.

• Bulletin of the Korean Chemical Society
• /
• v.20 no.7
• /
• pp.791-795
• /
• 1999

The crystal structure of a cyclopropane sorption complex of dehydrated fully Ca (2+) -exchanged zeolite X, Ca46Si100Al92O384· 30C3H6 (a = 24.988(4) Å), has been determined by single-crystal X-ray diffraction techniques in the cubic space group Fd3 at 21(1)℃. The crystal was prepared by ion exchange in a flowing stream of 0.05M aqueous Ca(NO3)2 for four days, followed by dehydration at 460℃ and 2×10 (-6) Torr for two days, and exposure to 100 Torr of cyclopropane gas at 21(1)℃. The structure was determined in this atmosphere and refined to the final error indices R1 = 0.068 and R2 = 0.082, with 373 reflections for which I > 3σ (I). In this structure, Ca 2+ ions are located at two crystallographic sites. Sixteen Ca 2+ ions fill the octahedral sites I at the centers of the hexagonal prisms (Ca-O = 2.412(9)Å). The remaining 30 Ca 2+ ions are at sites Ⅱ; each extends 0.46Å into the supercage (an increase of 0.16Å upon C3H6 sorption) where it coordinates to three trigonally arranged framework oxygens at 2.311(8)Å. Each of the 30 cyclopropane molecules was found to complex to Ca 2+ ions at site II by the induced dipole interaction (Ca-C = 2.99(4)Å). All carbon atoms in each cyclopropane molecule are equivalent and equidistant from Ca 2+ ions at site II with which they are associated.

• Bulletin of the Korean Chemical Society
• /
• v.19 no.10
• /
• pp.1095-1099
• /
• 1998

The crystal structure of an acetylene sorption complex of dehydrated fully Mn(Ⅱ)-exchanged zeolite X, Mn46Si100Al92O384·30C2H2 (a=24.705(3) Å) has been determined by single-crystal X-ray diffraction techniques. The structure was solved and refined in the cubic space group Fd3 at 21(l) ℃. The complex was prepared by dehydration at 380 ℃ and 2 x 10-6 Torr for 2 days, followed by exposure to 300 Torr of acetylene gas for 2 h at 24 ℃. The structure was refined to the final error indices, R1=0.060 and R2=0.054 with 383 reflections for which I > 3σ(Ⅰ). In the structure, Mn2+ ions are located at two different crystallographic sites; sixteen Mn2+ ions at site I are located at the centers of the double six rings and thirty Mn2+ ions are found at site Ⅱ in the supercage, respectively. Each of these latter Mn2+ ions is recessed ca. 0.385(2) Å into the supercage from its three-oxygen plane. Thirty acetylene molecules are sorbed per unit cell. Each Mn2+ ion at site Ⅱ lies on a threefold axis in the supercage of the unit cell, close to three equivalent trigonally arranged zeolite framework oxygen atoms (Mn(Ⅱ)-O=2.135(9) Å) and symmetrically to both carbon atoms of a C2H2 molecules. At these latter distances, the Mn(Ⅱ)-C interactions are weak (Mn(Ⅱ)-C=2.70(5) Å), probably resulting from electrostatic attractions between the divalent cations and the polarizable π-electron density of the acetylene molecules.

• Computers and Concrete
• /
• v.20 no.6
• /
• pp.671-682
• /
• 2017

In this research, seismic response of pipes is examined by applying nanotechnology and piezoelectric materials. For this purpose, a pipe is considered which is reinforced by carbon nanotubes (CNTs) and covered with a piezoelectric layer. The structure is subjected to the dynamic loads caused by earthquake and the governing equations of the system are derived using mathematical model via cylindrical shell element and Mindlin theory. Navier-Stokes equation is employed to calculate the force due to the fluid in the pipe. Mori-Tanaka approach is used to estimate the equivalent material properties of the nanocomposite and to consider the effect of the CNTs agglomeration on the scismic response of the structure. Moreover, the dynamic displacement of the structure is extracted using harmonic differential quadrature method (HDQM) and Newmark method. The main goal of this research is the analysis of the seismic response using piezoelectric layer and nanotechnology. The results indicate that reinforcing the pipeline by CNTs leads to a reduction in the displacement of the structure during an earthquake. Also the negative voltage applied to the piezoelectric layer reduces the dynamic displacement.

• Journal of the Korean Society of Manufacturing Process Engineers
• /
• v.17 no.6
• /
• pp.151-157
• /
• 2018

In this study, we have developed a composite pressure vessel that is compact and can store refrigerant at high pressure to increase the refrigerant volume. The composite pressure vessel is made of aluminum-based duralumin, which has high rigidity and excellent elongation in the inner liner, considering the characteristics of products in the aerospace and defense industry, where the safety of the applied product is considered as a priority. High strength carbon fiber was applied to the outside. In order to evaluate the performance of the developed product, burst test and cycling test were carried out. In burst test, an excellent safety margin equivalent to 2.7 times the operating pressure was obtained. In cycling test, a stable failure mode in which 'pre-burst leak' occurs is proved and the soundness of the product is proved.

• Steel and Composite Structures
• /
• v.31 no.5
• /
• pp.517-527
• /
• 2019

To move forward in large steps rather than in small increments, the community would benefit from a systematic and comprehensive database of multi-scale composites and measured properties, driven by comprehensive studies with a full range of types of fiber-reinforced polymers. The multi-scale hierarchy is a promising chemical approach that provides superior performance in synergistically integrated microstructured fibers and nanostructured materials in composite applications. Achieving high-efficiency thermal conductivity and mechanical properties with a simple surface treatment on single-walled carbon nanotubes (SWCNTs) is important for multi-scale composites. The main purpose of the project is to introduce ozone-treated SWCNTs between an epoxy matrix and basalt fibers to improve mechanical properties and thermal conductivity by enhancing dispersion and interfacial adhesion. The obvious advantage of this approach is that it is much more effective than the conventional approach at improving the thermal conductivity and mechanical properties of materials under an equivalent load, and shows particularly significant improvement for high loads. Such an effort could accelerate the conversion of multi-scale composites into high performance materials and provide more rational guidance and fundamental understanding towards realizing the theoretical limits of thermal and mechanical properties.

• Earthquakes and Structures
• /
• v.20 no.1
• /
• pp.123-132
• /
• 2021

Deficient beam-column joints of reinforced concrete (RC) structures designed to older practices and codes often lead to destructive local or global failures. A strengthening technique for these joints based on the use of the new and innovative Carbon-FRP (C-FRP) ropes is presented and investigated. The C-FRP ropes are diagonally placed in superficial notches on the two sides of the joint. Two full scale external substandard joint subassemblages with the same characteristics, one unstrengthened and one strengthened with diagonally applied C-FRP ropes, are constructed and tested in cyclic loading. Special attention has been given to the elaboration of the acquired test measurements. The extracted conclusions are based on the comparative study of the hysteretic responses of the specimens, the observed maximum load envelopes, the comparisons of the joint body shear deformations as measured using diagonally mounted LVTDs, the calculated nominal principal stresses developed in the joint regions, the assessed joint damage as expressed by the damage index by Park and Ang and finally the calculated values of the equivalent damping ratio. From these comparisons it is concluded that application of diagonally mounted C-FRP ropes on the two sides of the joint body of exterior connections is an efficient easy-to-apply technique for the strengthening of substandard RC joints.

• International Journal of Korean Welding Society
• /
• v.2 no.2
• /
• pp.7-13
• /
• 2002

A comparison of the welding performance of ship hull structural steels has been made. The weldability of steels especially designed for laser processing was compared to that of conventional hull and structural steels with plate thicknesses up to 12 mm. Autogenous laser beam welding was used to weld butt joints as well as skid and stake welded T-joints. The welds were assessed in accordance with the document "The Classification Societies" Requirements for Approval of $CO_2$ Laser Welding Procedures" Small imperfections in the weld only grew slightly in root bend tests and they only had a minor influence on the fatigue properties of laser fillet welded joints. In Charpy impact tests, the 27 J transition temperature of the weld metal and HAZ ranged from below -60 to $-50^{\circ}C$. The amount of martensite in the weld metal depended on the carbon equivalent of the steel with the highest amounts and highest hardness levels in conventional EH 36 (389 HV 5). Thermomechanically rolled steels contained less martensite and showed a correspondingly lower maximum hardness.ximum hardness.