• 청정기술
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• 제24권4호
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• pp.287-292
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• 2018

효율적으로 이산화탄소를 처리할 수 있는 활성탄을 제조하기 위하여 활성탄의 물리적 특성이 이산화탄소 흡착에 미치는 영향을 조사하였다. 소나무 톱밥과 석탄이 활성탄의 원료로 사용되었고, 제조된 활성탄의 비표면적, 미세기공 부피, 중기공 부피를 분석하였다. 제조된 활성탄은 열중량 분석기를 이용하여 이산화탄소 흡착량을 결정하였다. 그리고 이산화탄소 흡착량 결과를 활성탄의 비표면적, 미세기공 부피, 중기공 부피에 따라 분석하였다. 실험 결과, 소나무 톱밥 활성탄과 석탄 활성탄의 비표면적과 미세기공 부피는 이산화탄소 흡착량과 높은 연관성을 보인 반면에 중기공 부피는 이산화탄소 흡착에 거의 영향을 미치지 않았다. 따라서 활성탄의 비표면적과 미세기공 부피를 극대화하는 것이 효율적인 이산화탄소 처리를 위해 매우 중요한 요소로 나타났다.

• 한국자동차공학회논문집
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• 제16권5호
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• pp.171-178
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• 2008

The combustion and exhaust emission characteristics were investigated in an DME fueled HCCI engine. Carbon dioxide, nitrogen and mixed gas, which was composed of carbon dioxide and nitrogen, were used as control parameters of combustion and exhaust emission. As the oxygen concentration in induction air, which was occurred by carbon dioxide, nitrogen and mixed gas, was reduced, the start of auto-ignition was retarded and the burn duration was extended due to obstruction of combustion and reduction of combustion temperature. Due to these fact, indicated mean effective pressure was increased and indicated combustion efficiency was decreased by carbon dioxide, nitrogen and mixed gas. In case of exhaust emission, hydrocarbon and carbon monoxide was increased by reduction of oxygen concentration in induction air. Especially, partial burning was appeared at lower than about 18% of oxygen concentration by supplying carbon dioxide. However it was overcome by intake air heating.

• Advances in environmental research
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• 제12권2호
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• pp.123-148
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• 2023

The first part of the study involved calculating emission factors from electricity production. The second part of the study aimed to analyze perceptions of the concept of carbon dioxide utilization and was conducted through a questionnaire survey with participants from Almaty and Astana. The results showed that there were no significant improvements in the decrease of carbon dioxide emissions between 2017 and 2020. Almost no change occurred in the rate of carbon dioxide emission throughout the course of the four years. According to the results of the survey, a number of respondents had reservations about the feasibility of using carbon dioxide utilization as a solution to tackle climate change. They felt that this technology would only offer a temporary solution to carbon emissions, without addressing the underlying causes of the problem. Despite these concerns, the participants acknowledged that carbon dioxide utilization had certain advantages in promoting sustainability.

• 한국지반환경공학회 논문집
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• 제23권12호
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• pp.55-61
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• 2022

대기 중 온난화 가스의 하나인 이산화탄소 감소를 위해 많은 연구들이 수행 중이다. 이 중 이산화탄소 지중저장은 지구온난화 방지를 위한 중요한 공법 중 하나로 주목받고 있다. 하지만, 제한된 공간의 최대한 많은 양의 이산화탄소 저장을 위한 기술의 개발이 필요한 실정이다. 계면활성제의 활용은 이산화탄소 지중저장 효율의 향상에 기여할 것으로 여겨지고 있으나, 이에 대한 연구는 부족한 실정이다. 본 연구에서는 이산화탄소 지중저장 효율 증진을 위해 계면활성제 종류(sodium dodecyl sulfate 및 sodium dodecylbenzene sulfonate) 및 농도, 이산화탄소 주입속도에 따른 2차원 마이크로모델 실험을 수행하였다. 그 결과, 계면활성제의 농도 및 이산화탄소 주입속도가 증가할수록, 이산화탄소 지중저장 효율이 증가함을 확인하였다. 하지만, 한계 농도 및 속도 이상에서는 더 이상 효율 증진이 발생하지 않는 것으로 나타났다.

• Bulletin of the Korean Chemical Society
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• 제26권11호
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• pp.1743-1748
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• 2005

This work presents that carbon dioxide, which is a main contributor to the global warming effect, could be utilized as a selective oxidant in the oxidative dehydrogenation of ethylbenzene. The dehydrogenation of ethylbenzene over alumina-supported vanadium-antimony oxide catalyst has been studied under different atmospheres such as inert nitrogen, steam, oxygen or carbon dioxide as diluent or oxidant. Among them, the addition of carbon dioxide gave the highest styrene yield (up to 82%) and styrene selectivity (up to 97%) along with stable activity. Carbon dioxide could play a beneficial role of a selective oxidant in the improvement of the catalytic behavior through the oxidative pathway.

• 동아시아경상학회지
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• 제2권4호
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• pp.1-8
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• 2014

This study examines the relationship between population growth and carbon dioxide emissions in the context of Africa perspective. Population growth and carbon dioxide emissions helped identify the key driving forces of environmental impacts by including other predictors in all the different income levels of all sampled countries in Africa. To explore the role of population growth in the emissions of carbon dioxide, this research employed a panel data set of 52 Africa countries from 1960 to 2012 using fixed effects, random effects and GLS/FGLS estimators to estimate the modified STIRPAT model. The results found that a 1% increase in population growth suggests an increase in carbon dioxide emission loads by about 0.33%, 1.08%, 0.57% and 2.32% on the average, controlling for all other anthropogenic driving forces, for LICA, LMICA, UICA and HICA respectively. There is a significant relationship between population growth and carbon dioxide emissions in all the national income levels in Africa.

• 한국신재생에너지학회:학술대회논문집
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• 한국신재생에너지학회 2011년도 춘계학술대회 초록집
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• pp.221.2-221.2
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• 2011

In this study, we prepared the magnesium oxide decorated ordered mesoporous carbons processed by the reduction of magnesium oxide precursor on the CMK-3 surfaces in order to investigate the characterization and the effect on their carbon dioxide adsorption behaviors. The magnesium contents of the prepared samples were characterized using XPS. The textural properties of the prepared samples were investigated by $N_2$/77 K adsorption isotherms by BET equation. The carbon dioxide adsorption capacities of the prepared samples were investigated by the amounts of carbon dioxide adsorptions at 298 K and 1.0 atm. The results showed that the magnesium oxide on the CMK-3 surface enhanced interaction between carbon dioxide and adsorbents. Consequently, it was found that the magnesium oxide led to an increase in the carbon dioxide adsorption capacity of the CMK-3.

• 한국컴퓨터산업학회논문지
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• 제9권4호
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• pp.143-148
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• 2008

콘크리트의 탄산화를 진행시키는 가장 주요한 영향인자는 대기 중의 농도이다. 본 연구에서는 대기 중의 이산화탄소 농도에 따른 탄산화 진행 정도를 개발한 프로그램을 통하여 해석적으로 접근하였다. 또한 해석 프로그램을 통하여 이산화탄소 농도에 따른 내구수명을 산정하였다. 이산화탄소 표면농도가 0.1%인 경우도 탄산화 깊이가 50mm 정도로 나타났다. 콘크리트의 피복두께를 40mm를 유지한다면 이산화탄소 표면농도가 0.1%일 때 콘크리트의 내구수명은 67년으로 검토되었다.

• 설비공학논문집
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• 제15권4호
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• pp.274-286
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• 2003

Numerical simulations are performed to investigate the turbulent convective heat transfer of the supercritical carbon dioxide flows in vertical and horizontal square ducts. The gas cooling process at the supercritical state experiences a sudden change in thermodynamic and transport properties. This results in the extraordinary variations of the heat transfer coefficients in the supercritical state, which are much different from those of single or two phase flows. Algebraic second moment closure which can include the effects of large thermophysical property variations of carbon dioxide and of buoyancy is employed to model the Reynolds stresses and turbulent heat fluxes in the governing equations. The previous correlations for the turbulent heat transfer coefficient for the supercritical carbon dioxide flows couldn't reflect the buoyancy effect. The present results are used to establish a new heat transfer coefficient correlation including the effects of large thermophysical property variation and buoyancy on in-duct cooling process of supercritical carbon dioxide.

• Korean Chemical Engineering Research
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• 제54권2호
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• pp.206-212
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• 2016

Experimental data are reported on the phase equilibrium of propoxylated neopentyl glycol diacrylate in supercritical carbon dioxide. Phase equilibria data were measured in static method at a temperature of (313.2, 333.2, 353.2, 373.2 and 393.2) K and at pressures up to 27.82 MPa. At a constant pressure, the solubility of propoxylated neopentyl glycol diacrylate for the (carbon dioxide + propoxylated neopentyl glycol diacrylate) system increases as temperature increases. The (carbon dioxide + propoxylated neopentyl glycol diacrylate) system exhibits type-I phase behavior. The experimental result for the (carbon dioxide + propoxylated neopentyl glycol diacrylate) system is correlated with Peng-Robinson equation of state using mixing rule. The critical property of propoxylated neopentyl glycol diacrylate is predicted with Joback and Lyderson method.