Bulletin of the Korean Chemical Society

Korean Chemical Society (대한화학회)
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Dehydrogenation of Ethylbenzene with Carbon Dioxide as Soft Oxidant over Supported Vanadium-Antimony Oxide Catalyst

  • Hong, Do-Young (Catalysis Center for Molecular Engineering, Korea Research Institute of Chemical Technology (KRICT)) ;
  • Vislovskiy, Vladislav P. (Catalysis Center for Molecular Engineering, Korea Research Institute of Chemical Technology (KRICT)) ;
  • Park, Sang-Eon (Department of Chemistry, Inha University) ;
  • Park, Min-Seok (Department of Biotechnology & Food Science, Mongolia International University) ;
  • Yoo, Jin-S. (Catalysis Center for Molecular Engineering, Korea Research Institute of Chemical Technology (KRICT)) ;
  • Chang, Jong-San (Catalysis Center for Molecular Engineering, Korea Research Institute of Chemical Technology (KRICT))
  • Published : 2005.11.20
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Abstract

This work presents that carbon dioxide, which is a main contributor to the global warming effect, could be utilized as a selective oxidant in the oxidative dehydrogenation of ethylbenzene. The dehydrogenation of ethylbenzene over alumina-supported vanadium-antimony oxide catalyst has been studied under different atmospheres such as inert nitrogen, steam, oxygen or carbon dioxide as diluent or oxidant. Among them, the addition of carbon dioxide gave the highest styrene yield (up to 82%) and styrene selectivity (up to 97%) along with stable activity. Carbon dioxide could play a beneficial role of a selective oxidant in the improvement of the catalytic behavior through the oxidative pathway.

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