• Title/Summary/Keyword: Carbon diffusion

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Porous Electrode manufacture by catalyst powdering method for PAFC (촉매분말법에 의한 PAFC용 다공성 전극제작)

  • 김영우;이주성
    • Journal of Energy Engineering
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    • v.2 no.2
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    • pp.194-199
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    • 1993
  • Gas diffusion passes are introduced to catalyst layer so as to enlarge reaction region in cathode and anode and then improve electrode performances. The catalyst layer was manufactured with PTFE/carbon (none catalyst loaded) for gas diffusion and Pt/carbon (10 w/o Pt catalyst loaded) by varing the mixing ratio of (PTFE/carbon) to (Pt/carbon) by catalyst powdering method. The electrodes made by mixing Pt(10 w/o)/carbon powders and PTFE/carbon powders containing 60 w/o PTFE at the ratio of 7 : 3 showed the best electrode performances. It was known that by comparing the porosities to electrode performances the electrode performances were increased as both macro pore for gas diffusion and micro pore for electrolyte intrusion were formed much more. The platinum catalyst content in electrode was 0.2 mg/$\textrm{cm}^2$ and the PTFE content was 42 w/o. The electrode performance in unit cell was 220 ㎃/$\textrm{cm}^2$/0.7 V at operating temperature of 150$^{\circ}C$.

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The Characteristics Evaluation of the Gas Diffusion Layer for a PEM Fuel Cell by Computational Fluid Dynamics (CFD 해석을 이용한 PEMFC 용 기체확산층의 특성평가)

  • Kim B.H.;Choi J.P.;Jeon B.H.
    • Proceedings of the Korean Society of Precision Engineering Conference
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    • 2005.06a
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    • pp.207-210
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    • 2005
  • In this paper, a two-dimensional cross-channel model was applied to investigate influence of the gas diffusion layer(GDL) property and flow field geometry in the anode side for proton exchange membrane fuel cell(PEMFC). The GDL is made of a porous material such as carbon cloth, carbon paper, or metal wire mesh. To the simplicity, the GDL is represented as a block of material containing numerous pathways through which gaseous reactants and liquid water can pass. The purpose of present work was to study the effect of the GDL thickness and the porosity, and flow field geometry by computational fluid dynamics(CFD)

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Electrochemical Reduction of High Pressure Carbon Dioxide on Metal Electrodes and Gas Diffusion Electrodes

  • Hara, Kohjiro;Sakata, Tadayoshi
    • Analytical Science and Technology
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    • v.8 no.4
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    • pp.683-689
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    • 1995
  • Electrochemical reduction of carbon dioxide under high pressure on Fe electrodes and a gas diffusion electrode containing Pt catalyst (Pt-GDE) had been investigated. Formic acid was formed on Fe electrode with a faradaic efficiency of 60% at a current density of $120mA\;cm^{-2}$ under 30 atm of $CO_2$. Hydrocarbons such as $CH_4$, $C_2H_6$, $C_3H_6$, $1-C_4H_8$, and $n-C_5H_{12}$ are also formed. The distribution of hydrocarbons followed well the Schultz-Flory distribution. $CH_4$ was formed efficiently as the main reduction product on Pt-GDE.

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The Characteristics of Soot at the Post-Flame Region in Jet Diffusion Flames Added Carbon Dioxide (이산화탄소가 첨가된 제트확산화염 후류에서의 매연 특성)

  • Ji, Jung-Hoon;Lee, Eui-Ju
    • Journal of the Korean Society of Safety
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    • v.25 no.6
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    • pp.9-13
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    • 2010
  • An experimental study for characteristics of soot were conducted at the post-flame region in jet diffusion flames, where carbon dioxide was used as additives in oxidizer stream. Light-extinction method was performed using He-Ne laser with wave length at 632.8nm for the measurement of relative soot density and soot volume fraction with dimensionless extinction coefficient, $K_e$ and mass specific extinction coefficient, ${\sigma}_s$. To increase of resolution, laser light was modified for sheet-form using concave, convex lenses and slit. C/H ratio was introduced for quantitative analysis of soot growth which is expressed by carbonization and dehydrogen. Also transmission electron microscopy(TEM) was used for observation of morphological shape. The results show that the relative soot density in the post-flame region was lower when carbon dioxide was added in oxidizer stream because of reduction of flame temperature.

Delayed Anoxic Encephalopathy after Carbon Monoxide Poisoning: Evaluation of Therapeutic Effect by Serial Diffusion-Tensor Magnetic Resonance Imaging and Neurocognitive Test (일산화탄소중독 이후 발생한 지연무산소뇌병증: 확산텐서영상 및 신경인지기능검사를 이용한 치료 효과의 평가)

  • Ryu, Ho-Sung;Kim, Youngwook;Jung, Boo-Kyoung;Kim, Yong-Won
    • Journal of the Korean neurological association
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    • v.36 no.4
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    • pp.358-362
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    • 2018
  • Delayed anoxic encephalopathy after carbon monoxide (CO) poisoning is characterized by neurological deterioration that occurs after recovery from acute CO intoxication. There has been no established therapy. We report a patient recovered from acute CO intoxication developed various neurological symptoms. After the administration of high dose prednisolone and anticholinesterase inhibitor, the therapeutic effect was remarkable and confirmed by quantitative analysis of diffusion-tensor imaging (DTI). DTI could be used to evaluate the therapeutic effect for delayed anoxic encephalopathy after CO poisoning.

Diffusion of Si Vapor Infiltrating into Porous Graphite (다공성 흑연의 기공내부로 침투하는 Si 증발입자의 확산)

  • Park, Jang-Sick;Hwang, Jungtae
    • Journal of the Korean institute of surface engineering
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    • v.49 no.1
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    • pp.104-109
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    • 2016
  • Graphite's thermal stability facilitates its widespread use as crucibles and molds in high temperatures processes. However, carbon atoms can be rather easily detached from pores and outer surfaces of the graphite due to the weak molecular force of the c axis of graphites. Detached carbon atoms are known to become a source of dust during fabrication processes, eventually lowering the effective yield of products. As an effort to reduce these problems of dust scattering, we have fabricated SiC composites by employing Si vapor infiltration method into the pores of graphites. In order to understand the diffusion process of the Si vapor infiltration, Si and C atomic percentages of fabricated SiC composites are carefully measured and the diffusion law is used to estimate the diffusion coefficient of Si vapor. A quadratic equation is obtained from the experimental results using the least square method. Diffusion coefficient of Si vapor is estimated using this quadratic equation. The result shows that the diffusion length obtained through the Si vapor infiltration method is about 10.7 times longer than that obtained using liquid Si and clearly demonstrates the usefulness of the present method.

Physical and Mechanical Properties of Low Carbon Green Concrete (저탄소 그린콘크리트의 물리·역학적 특성)

  • Cho, Il Ho;Sung, Chan Yong
    • Journal of The Korean Society of Agricultural Engineers
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    • v.55 no.3
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    • pp.123-128
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    • 2013
  • This study was performed to evaluate the slump flow, air content, setting time, compressive strength, adiabatic temperature rise and diffusion coefficient of chloride used ordinary portland cement, crushed coarse aggregate, crushed sand, river sand, fly ash, limestone powder, blast furnace slag powder and superplasticizer to find optimum mix design of low carbon green concrete for structures. The performances of low carbon green concrete used fly ash, limestone powder and blast furnace slag powder were remarkably improved. This fact is expected to have economical effects in the manufacture of low carbon green concrete for structures. Accordingly, the fly ash, limestone powder and blast furnace slag powder can be used for low carbon green concrete material.

Effect of Ni Content and Atmosphere Gas Pressure on the Carburizability Low-Carbon Alloy Steels During Fluidized-bed Carburizing (유동상 침탄시 저탄소 합금강의 침탄능에 미치는 Ni 함량 및 분위기 가스압력의 영향)

  • Roh, Y.S.;Kim, Y.H.;Lee, S.Y.
    • Journal of the Korean Society for Heat Treatment
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    • v.3 no.3
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    • pp.5-12
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    • 1990
  • This study has been conducted to establish the carburizing characteristics of low carbon alloy steels with varying amount of Ni element gas-carburized for 2 hours at $930^{\circ}C$ in an atmosphere of 94% $N_2$-6% $C_3H_8$ gas mixture with some changes in gas pressure passing through the diffusion plate in the fluidized-bed furnace. The results obtained from the experiment are as follows : (1) Optical micrograph has shown that the carburized layer consists of retained austenite and plate martensite and that retained austenite increases as the pressure of gas mixture passing through the diffusion plate as well as Ni content increase. (2) Chemical analysis has shown that carbon potential increases and carburizability is also improved due to a less degree of fluidization as the pressures of gas mixtures passing through the diffusion plate increase, resulting in, however, a severe formation of soot, and the gas pressure is necessarily regulated. (3) It has been revealed that carbon concentration hardness values at a given distance measured from the surface within the carburized case. Increase with increasing the pressure of gas mixtures passing through the diffusion plate and decrease with increasing Ni content. (4) The effective case depth has been shown to almost linearly increase as the pressure of gas mixtures passing through the diffusion plate is increased and to decrease with increasing Ni content.

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The Change in Diffusion Coefficient and Wear Characteristic in Carbonitriding Layer of SCM415 Steel (침탄질화 처리된 SCM415강의 깊이에 따른 확산 및 마모특성 변화)

  • Lee, Su-Yeon;Youn, Kuk-Tea;Huh, Seok-Hwan;Lee, Chan-Gyu
    • Journal of the Korean institute of surface engineering
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    • v.44 no.5
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    • pp.207-212
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    • 2011
  • In this study, the change in diffusion coefficient and wear characteristic with depth in the carbonitriding layer of SCM415 steel was discussed. To determine the diffusion coefficient, depth profile of carbon was measured from the surface using the Glow Discharge Spectrometer. In otherwise, measurements of carbide fraction, micro vickers hardness of surface and observation of microstructure have been implemented through the SEM image. $Fe_3$(C,N) layer and effective depth were increased as the time for carbonitriding takes longer. According to wear experiment, the results showed that wear resistance was improved by $Fe_3$(C,N) layer and effective depth.

Effects of n-Alkanols on the Lateral Diffusion of Total Phospholipid Fraction Extracted from Brain Membranes

  • Chung, In-Kyo;Kang, Jung-Sook;Yun, Il
    • Archives of Pharmacal Research
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    • v.16 no.3
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    • pp.191-195
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    • 1993
  • We investigated the effects of n-alkanols on the range and rate of the lateral diffusion of 1, 3-di(1-pyrenyl)propane in the model membranes of total phospholipid fraction extracted from synaptosomal plasma membrane vesicles. n-Akanols increased the range and rate of the lateral diffusion of 1, 3-di(1-pyrenyl)propane in the bulk model membrane structures (inner + outer monolayers) and the potencies of n-alknols up to 1-nonanol increased by 1 order of magnitude as the carbon chain length increases by two carbon atoms. The cut-off phenomenon was reached at 1-decanol, where further icnrease in hydrocarbon length resulted in a decrease in the lateral diffusion. However, significant changes in the 1'/1 value were not observed by methanol (from 100 to 2500 mM), ethanol (from 25 to 800 mM), and 1-propanol (from 10 to 250 mM) over entire concentration.

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